Análisis de calidad de aguas y promoción de la salud en quintas del cinturón hortíflorícola platense

El presente trabajo constituye una de las líneas de acción del proyecto de extensión de la Facultad de Ciencias Exactas (UNLP) “Taller de potabilidad de aguas subterráneas”. El objetivo general del proyecto es contribuir a la construcción de conocimiento, intercambiado saberes con la comunidad, que nos permita generar herramientas para defender el acceso al agua potable como un derecho humano fundamental

Full-Configuration-Interaction Study of the Metal-Insulator Transition in Model Systems: Li_N Linear Chains (N=2,4,6,8)

International audienceThe precursor of the metal-insulator transition is studied at ab initio level in linear chains of equally spaced lithium atoms. In particular, full configuration interaction calculations (up to 1×109 determinants) are performed, in order to take into account the different nature of the wave function at different internuclear distances. Several indicators of the Metal-Insulator transition (minimum of the energy gap, maximum of the localization tensor or of the polarizability) are considered and discussed. It is shown that the different indicators give concordant results, showing a rapid change in the nature of the wave function at an internuclear distance of about 7bohrs

Viscosity of andesite melts and its implication for magma mixing prior to Unzen 1991-1995 eruption

The viscosity of an iron-bearing melt with composition similar to Unzen andesite was determined experimentally in the high (109-1010.5 Pa·s) and low (5-1000 Pa·s) viscosity range using a parallel plate viscometer and the falling sphere method, respectively. Falling sphere experiments were carried out in an internally heated argon pressure vessel and in a piston cylinder apparatus at 1323 to 1573 K and 200 to 2000 MPa. Creep experiments were performed in the temperature range of 747 - 845 K at 300 MPa. The water content of the melt varies from nominally dry to 6.2 wt% H2O. The Fe2+/Fetot ratio was determined for each sample in the quenched glass using a colorimetric method. Pressure has minor influence on the viscosity compared with the effect of temperature, water content (main compositional parameter controlling the viscosity) or with the Fe2+/Fetot ratio (especially important at low water content of the melt). Based on our new viscosity data and literature data with measured Fe2+/Fetot ratio we propose a new empirical equation to estimate the viscosity η (in Pa·s) of andesitic melts as a function of temperature T (in K), water content w (in wt%) and Fe2+/Fetot ratio. The derived relationship reproduces the experimental data (87 in total) in the viscosity range from 100.5 to 1013 Pa·s with a 1σ standard deviation of 0.17 log units. However, application of this calculation model is limited to Fe2+/Fetot>0.3 and to temperatures above Tg. Moreover, in the high viscosity range the variation of viscosity with water content is constrained only by few experimental data and needs verification by additional measurements. The viscosity data are used to interpret mixing processes in the Unzen magma chamber prior to 1991-1995 eruption. We demonstrate that the viscosities of the rhyolite and andesite melts from the two end-member magmas are nearly identical prior and during mixing, enabling efficient magma mixing

The viscosity of shoshonitic melts (Vulcanello Peninsula, Aeolian Islands, Italy): insight on the magma ascent in dikes

The viscosity of shoshonitic melts from Vulcanello Peninsula (Vulcano Island, Italy) is experimentally determined at temperatures between 733 K and 1673 K. The water content of the melts varies from 0.03 to 4.75 wt% H2O. The micropenetration technique is employed at ambient pressure in the high viscosity range (109-1012 Pa·s). Falling sphere(s) experiments are performed at 500 and 2000 MPa in the low viscosity range (100.5-103 Pa·s). Results show a decrease of about 2 orders of magnitude in viscosity if ~ 3 wt% of water is added to the dry melt at 1300 K. At high temperature the viscosity of Vulcanello melts is intermediate between that of andesitic and basaltic melts. In contrast, at low temperatures (≤1050 K), the shoshonitic melt is characterized by a lower viscosity with respect to the two previous melts. Based on our new data set, a calculation model is proposed to predict the viscosity of the shoshonitic melts as a function of temperature and water content. The viscosity data are used to constrain the ascent velocity of shoshonitic magmas from Vulcanello within dikes. Using petrological data (temperature and crystal content of the magma) and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate the time scale for the ascent of magma from the main reservoir to the surface. Results show time scales in the order of hours to few days. We conclude that the rapid ascent of poorly evolved melts from Moho depths should be taken into account for the hazard assessment of Vulcano Island

A general viscosity model of Campi Flegrei (Italy) melts

Viscosities of shoshonitic and latitic melts, relevant to the Campi Flegrei caldera magmas, have been experimentally determined at atmospheric pressure and 0.5 GPa, temperatures between 840 K and 1870 K, and H2O contents from 0.02 to 3.30 wt%. The concentric cylinder technique was employed at atmospheric pressure to determine viscosity of nominally anhydrous melts in the viscosity range of 101.5 - 103 Pa·s. The micropenetration technique was used to determine the viscosity of hydrous and anhydrous melts at atmospheric pressure in the high viscosity range (1010 Pa·s). Falling sphere experiments were performed at 0.5 GPa in the low viscosity range (from 100.35 to 102.79 Pa·s) in order to obtain viscosity data of anhydrous and hydrous melts. The combination of data obtained from the three different techniques adopted permits a general description of viscosity as a function of temperature and water content using the following modified VFT equation: where η is the viscosity in Pa·s, T the temperature in K, w the H2O content in wt%, and a, b, c, d, e, g are the VFT parameters. This model reproduces the experimental data (95 measurements) with a 1σ standard deviation of 0.19 and 0.22 log units for shoshonite and latite, respectively. The proposed model has been applied also to a more evolved composition (trachyte) from the same area in order to create a general model applicable to the whole compositional range of Campi Flegrei products. Moreover, speed data have been used to constrain the ascent velocity of latitic, shoshonitic, and trachytic melts within dikes. Using petrological data and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate a time scale for the ascent of melt from 9 km to 4 km depth (where deep and shallow reservoirs, respectively, are located) in the order of few minutes. Such a rapid ascent should be taken into account for the hazard assessment in the Campi Flegrei area

Intrinsic solidification behaviour of basaltic to rhyolitic melts: a cooling rate experimental study

Dynamic cooling-induced solidification experiments were run using six silicate glasses along the basalt - rhyolite join (B100= 100 wt % of basalt, R100= 100 wt % of rhyolite), i.e. B100, B80R20, B60R40, B40R60, B20R80 and R100; the glasses directly quenched from 1300 °C after a dwell of 120 minutes (experiment E0) contain 50-400 ppm H2O, << 1 area% μm-sized bubble, and Fe2+/Fetot between 0.34 and 0.46. Experiments were performed in Pt capsules at room pressure and fO2 of air, between 1300 and 800 °C using three different cooling rates of 0.0167, 3 and 30 °C/min; these cooling rates were run two times: E1-E2 experiments at 0.0167°C/min, S1-E3 at 3 °C/min, and E4-E5 at 30 °C/min. In experiments E1 to E5, samples were annealed for 120 minutes at 1300 °C, whereas in the experiment S1 the samples were firstly heated for 30 minutes at 1400 °C followed by a dwell time of 2400 minutes at 1300°C before cooling. In the experiments a preferential crystallization was not observed at the melt/gas interface. B100, B80R20 and B60R40 run-products have a low tendency to preferentially crystallize on Pt walls, while B40R60, B20R80 and R100 are not affected by the presence of Pt substrata. All run-products show very homogeneous textures, except for B60R40 and B40R60 at 0.0167°C/min in the E1 experiment. The duplicates of B40R60 and B60R40 at 0.0167°C/min and B100 at 30 °C/min show relatively large differences in crystal content (> 4 and < 14 area%). B40R60 and B60R40 duplicated run-products have the same amount of earlycrystallized clinopyroxene and spinel, but different contents in lately-formed plagioclase. The run-products with the same starting composition from E3-S1 (3 °C/min) show a high reproducibility in terms of crystal shape, size, and amount (< 4 area%). This demonstrates that the crystallization path is not affected by the different heat treatment above the liquidus temperature, i.e. the time scale of structural re-equilibration (relaxation) and chemical rehomogenization are shorter than our experimental time scale. Possible chemicalheterogeneities on a length scale of several micrometers for R100 and several hundreds of micrometers for B100 can be removed at 1300 °C within 120 minutes. A heat treatment at 1300 °C for 120 minutes significantly reduces the amount of μm-sized bubbles, potentially responsible for the onset of nucleation and unreveals the intrinsic solidification of silicate melts. The experimental reproducibility is low when the cooling path intersects the tip of the time-temperature-transformation (TTT) curves, i.e. when the nucleation rate is near its maximum (Imax). In that case, even small thermal variations in cooling rate and local composition can have large effects on phase abundance and crystal size. Dynamic crystallization experiments can be properly interpreted and compared only if they are texturally homogeneous and the physico-chemical state of the superheated silicate liquid is known. The solidification conditions used in this study mirror those of aphyric lavas and dikes emplaced at shallower crustal levels

Diamond Detectors for the TOTEM Timing Upgrade

This paper describes the design and the performance of the timing detector developed by the TOTEM Collaboration for the Roman Pots (RPs) to measure the Time-Of-Flight (TOF) of the protons produced in central diffractive interactions at the LHC. The measurement of the TOF of the protons allows the determination of the longitudinal position of the proton interaction vertex and its association with one of the vertices reconstructed by the CMS detectors. The TOF detector is based on single crystal Chemical Vapor Deposition (scCVD) diamond plates and is designed to measure the protons TOF with about 50 ps time precision. This upgrade to the TOTEM apparatus will be used in the LHC run 2 and will tag the central diffractive events up to an interaction pileup of about 1. A dedicated fast and low noise electronics for the signal amplification has been developed. The digitization of the diamond signal is performed by sampling the waveform. After introducing the physics studies that will most profit from the addition of these new detectors, we discuss in detail the optimization and the performance of the first TOF detector installed in the LHC in November 2015.Comment: 26 pages, 18 figures, 2 tables, submitted for publication to JINS

LHC Optics Measurement with Proton Tracks Detected by the Roman Pots of the TOTEM Experiment

Precise knowledge of the beam optics at the LHC is crucial to fulfil the physics goals of the TOTEM experiment, where the kinematics of the scattered protons is reconstructed with the near-beam telescopes -- so-called Roman Pots (RP). Before being detected, the protons' trajectories are influenced by the magnetic fields of the accelerator lattice. Thus precise understanding of the proton transport is of key importance for the experiment. A novel method of optics evaluation is proposed which exploits kinematical distributions of elastically scattered protons observed in the RPs. Theoretical predictions, as well as Monte Carlo studies, show that the residual uncertainty of this optics estimation method is smaller than 0.25 percent.Comment: 20 pages, 11 figures, 5 figures, to be submitted to New J. Phy

Evidence for non-exponential elastic proton-proton differential cross-section at low |t| and sqrt(s) = 8 TeV by TOTEM

The TOTEM experiment has made a precise measurement of the elastic proton-proton differential cross-section at the centre-of-mass energy sqrt(s) = 8 TeV based on a high-statistics data sample obtained with the beta* = 90 optics. Both the statistical and systematic uncertainties remain below 1%, except for the t-independent contribution from the overall normalisation. This unprecedented precision allows to exclude a purely exponential differential cross-section in the range of four-momentum transfer squared 0.027 < |t| < 0.2 GeV^2 with a significance greater than 7 sigma. Two extended parametrisations, with quadratic and cubic polynomials in the exponent, are shown to be well compatible with the data. Using them for the differential cross-section extrapolation to t = 0, and further applying the optical theorem, yields total cross-section estimates of (101.5 +- 2.1) mb and (101.9 +- 2.1) mb, respectively, in agreement with previous TOTEM measurements.Comment: Final version published in Nuclear Physics

First Results from the TOTEM Experiment

The first physics results from the TOTEM experiment are here reported, concerning the measurements of the total, differential elastic, elastic and inelastic pp cross-section at the LHC energy of $\sqrt{s}$ = 7 TeV, obtained using the luminosity measurement from CMS. A preliminary measurement of the forward charged particle $\eta$ distribution is also shown.Comment: Conference Proceeding. MPI@LHC 2010: 2nd International Workshop on Multiple Partonic Interactions at the LHC. Glasgow (UK), 29th of November to the 3rd of December 201