Cloth catalysts in water denitrification: I. Pd on glass fibers

Fiber catalysts are easy to handle and free of mass-transfer resistance. This report is the first application of cloth catalysts to water denitrification. In this work, cloths woven from glass fibers (GF) of 7–10 mm in diameter, impregnated with Pd, were tested in a semi-batch reactor to evaluate their effectiveness in the catalytic liquid phase hydrogenation of nitrites and nitrates. The catalytic properties of Pd-GF cloths were evaluated as a function of Pd loading as well of chemical composition of the glass, specific surface area and weaving mode of the fibrous support. Investigated catalysts showed the same level of specific activity (per g Pd) as conventional powdered catalysts for liquid-phase hydrogenation of nitrites but their activity for nitrates was about one order of magnitude lower. The nitrite and nitrate removal activities were independent of the catalyst structure; the formation of ammonium ions was highly sensitive to reactant concentration. The stability of Pd-GF cloths is discussed

Current-induced magnetic superstructures in exchange-spring devices

We investigate the potential to use a magneto-thermo-electric instability that may be induced in a mesoscopic magnetic multi-layer (F/f/F) to create and control magnetic superstructures. In the studied multilayer two strongly ferromagnetic layers (F) are coupled through a weakly ferromagnetic spacer (f) by an "exchange spring" with a temperature dependent "spring constant" that can be varied by Joule heating caused by an electrical dc current. We show that in the current-in-plane (CIP) configuration a distribution of the magnetization, which is homogeneous in the direction of the current flow, is unstable in the presence of an external magnetic field if the length L of the sample in this direction exceeds some critical value Lc ~ 10 \mu m. This spatial instability results in the spontaneous formation of a moving domain of magnetization directions, the length of which can be controlled by the bias voltage in the limit L >> Lc. Furthermore, we show that in such a situation the current-voltage characteristics has a plateau with hysteresis loops at its ends and demonstrate that if biased in the plateau region the studied device functions as an exponentially precise current stabilizer.Comment: 8 pages, 6 figure

Cloth catalysts in water denitrification. II. Removal of nitrates using Pd-Cu supported on glass fibers

The use of glass fibers in the form of woven cloth (GFC), as a new type of catalytic support, was studied for the reduction of aqueous nitrate solutions using a Pd/Cu–GFC catalyst. The activity (per gram Pd) and selectivity to nitrogen were found to be comparable with those found for Pd–Cu catalysts supported on the other carriers. The maximal initial removal activity was found for a catalyst with a Pd/(Pd+Cu) ratio of 0.81. The corresponding activity was 0.7 mmol min-1 (gPd)-1, and the selectivity was 97 mol% at 25°C and pH 6.5 for initial nitrate concentration of 100 mg l-1. The selectivity to nitrogen declined at high conversions of nitrate and high pH

Breathing Current Domains in Globally Coupled Electrochemical Systems: A Comparison with a Semiconductor Model

Spatio-temporal bifurcations and complex dynamics in globally coupled intrinsically bistable electrochemical systems with an S-shaped current-voltage characteristic under galvanostatic control are studied theoretically on a one-dimensional domain. The results are compared with the dynamics and the bifurcation scenarios occurring in a closely related model which describes pattern formation in semiconductors. Under galvanostatic control both systems are unstable with respect to the formation of stationary large amplitude current domains. The current domains as well as the homogeneous steady state exhibit oscillatory instabilities for slow dynamics of the potential drop across the double layer, or across the semiconductor device, respectively. The interplay of the different instabilities leads to complex spatio-temporal behavior. We find breathing current domains and chaotic spatio-temporal dynamics in the electrochemical system. Comparing these findings with the results obtained earlier for the semiconductor system, we outline bifurcation scenarios leading to complex dynamics in globally coupled bistable systems with subcritical spatial bifurcations.Comment: 13 pages, 11 figures, 70 references, RevTex4 accepted by PRE http://pre.aps.or

Detonation type waves in phase (chemical) transformation processes in condensed matter

Fast self sustained waves (autowaves) associated with chemical or phase transformations are observed in many situations in condensed matter. They are governed neither by diffusion of matter or heat (as in combustion processes) nor by a travelling shock wave (as in gaseous detonation). Instead, they result from a coupling between phase transformation and the stress field, and may be classified as gasless detonation autowaves in solids. We propose a simple model to describe these regimes. The model rests on the classical equations of elastic deformations in a 1-dimensional solid bar, with the extra assumption that the phase (chemical) transformation induces a change of the sound velocity. The transformations are assumed to occur through a chain branched mechanism, which starts when the mechanical stress exceeds a given threshold. Our investigation shows that supersonic autowaves exist in this model. In the absence of diffusion (dissipation factor, losses), a continuum of travelling wave solutions is found. In the presence of diffusion, a steady state supersonic wave solution is found, along with a slower wave controlled by diffusion