93 research outputs found
Cod Liver Oil as a Source of Vitamin A
In the course of experiments having for their object the study of the properties of vitamin A with a view to its isolation, certain observations were made concerning the behavior of animals on various rations containing cod liver oil. It was noted that different samples of cod liver oil apparently vary markedly in vitamin A potency. Xerophthalmia has been produced in rats on diets containing as much as 3 per cent of cod liver oil. Synthetic rations containing cod liver oil evolve a penetrating odor resembling acrolein. When the cod liver oil is replaced with butter fat, this odor is not observed. It is possible that the failure of rats on diets containing certain samples of cod liver oil may be due to one or more of the following factors. 1. A decreased consumption of the diet clue to this decomposition product. 2. A destruction of vitamin A which runs parallel with the destruction of the cod liver oil. 3. Certain samples of cod liver oil are not as rich in vitamin A as supposed heretofore
Long Exciton Dephasing Time and Coherent Phonon Coupling in CsPbBrCl Perovskite Nanocrystals
Fully-inorganic cesium lead halide perovskite nanocrystals (NCs) have shown
to exhibit outstanding optical properties such as wide spectral tunability,
high quantum yield, high oscillator strength as well as blinking-free single
photon emission and low spectral diffusion. Here, we report measurements of the
coherent and incoherent exciton dynamics on the 100 fs to 10 ns timescale,
determining dephasing and density decay rates in these NCs. The experiments are
performed on CsPbBrCl NCs using transient resonant three-pulse four-wave
mixing (FWM) in heterodyne detection at temperatures ranging from 5 K to 50 K.
We found a low-temperature exciton dephasing time of 24.51.0 ps, inferred
from the decay of the photon-echo amplitude at 5 K, corresponding to a
homogeneous linewidth (FWHM) of 545 {\mu}eV. Furthermore, oscillations in
the photon-echo signal on a picosecond timescale are observed and attributed to
coherent coupling of the exciton to a quantized phonon mode with 3.45 meV
energy
Localized holes and delocalized electrons in photoexcited inorganic perovskites: Watching each atomic actor by picosecond X-ray absorption spectroscopy
We report on an element-selective study of the fate of charge carriers in
photoexcited inorganic CsPbBr3 and CsPb(ClBr)3 perovskite nanocrystals (NCs) in
toluene solutions using time-resolved X-ray absorption spectroscopy with 80 ps
time resolution. Probing the Br K-edge, the Pb L3-edge and the Cs L2-edge, we
find that holes in the valence band are localized at Br atoms, forming small
polarons, while electrons appear as delocalized in the conduction band. No
signature of either electronic or structural changes are observed at the Cs
L2-edge. The results at the Br and Pb edges suggest the existence of a weakly
localized exciton, while the absence of signatures at the Cs edge indicates
that the Cs+ cation plays no role in the charge transport, at least beyond 80
ps. These results can explain the rather modest charge carrier mobilities in
these materials.Comment: 19 pages, 3 figure
Bright triplet excitons in lead halide perovskites
Nanostructured semiconductors emit light from electronic states known as
excitons[1]. According to Hund's rules[2], the lowest energy exciton in organic
materials should be a poorly emitting triplet state. Analogously, the lowest
exciton level in all known inorganic semiconductors is believed to be optically
inactive. These 'dark' excitons (into which the system can relax) hinder
light-emitting devices based on semiconductor nanostructures. While strategies
to diminish their influence have been developed[3-5], no materials have been
identified in which the lowest exciton is bright. Here we show that the lowest
exciton in quasi-cubic lead halide perovskites is optically active. We first
use the effective-mass model and group theory to explore this possibility,
which can occur when the strong spin-orbit coupling in the perovskite
conduction band is combined with the Rashba effect [6-10]. We then apply our
model to CsPbX3 (X=Cl,Br,I) nanocrystals[11], for which we measure size- and
composition-dependent fluorescence at the single-nanocrystal level. The bright
character of the lowest exciton immediately explains the anomalous
photon-emission rates of these materials, which emit 20 and 1,000 times
faster[12] than any other semiconductor nanocrystal at room[13-16] and
cryogenic[17] temperatures, respectively. The bright exciton is further
confirmed by detailed analysis of the fine structure in low-temperature
fluorescence spectra. For semiconductor nanocrystals[18], which are already
used in lighting[19,20], lasers[21,22], and displays[23], these optically
active excitons can lead to materials with brighter emission and enhanced
absorption. More generally, our results provide criteria for identifying other
semiconductors exhibiting bright excitons with potentially broad implications
for optoelectronic devices.Comment: 14 pages and 3 figures in the main text, Methods and extended data 16
pages which include 11 figures, and supporting information 28 page
Bright triplet excitons in caesium lead halide perovskites
Nanostructured semiconductors emit light from electronic states known as excitons. For organic materials, Hund’s rules state that the lowest-energy exciton is a poorly emitting triplet state. For inorganic semiconductors, similar rules predict an analogue of this triplet state known as the ‘dark exciton’. Because dark excitons release photons slowly, hindering emission from inorganic nanostructures, materials that disobey these rules have been sought. However, despite considerable experimental and theoretical efforts, no inorganic semiconductors have been identified in which the lowest exciton is bright. Here we show that the lowest exciton in caesium lead halide perovskites (CsPbX_3, with X = Cl, Br or I) involves a highly emissive triplet state. We first use an effective-mass model and group theory to demonstrate the possibility of such a state existing, which can occur when the strong spin–orbit coupling in the conduction band of a perovskite is combined with the Rashba effect. We then apply our model to CsPbX_3 nanocrystals, and measure size- and composition-dependent fluorescence at the single-nanocrystal level. The bright triplet character of the lowest exciton explains the anomalous photon-emission rates of these materials, which emit about 20 and 1,000 times faster than any other semiconductor nanocrystal at room and cryogenic temperatures, respectively. The existence of this bright triplet exciton is further confirmed by analysis of the fine structure in low-temperature fluorescence spectra. For semiconductor nanocrystals, which are already used in lighting, lasers and displays, these excitons could lead to materials with brighter emission. More generally, our results provide criteria for identifying other semiconductors that exhibit bright excitons, with potential implications for optoelectronic devices
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