The space density of Compton-thick AGN at z~0.8 in the zCOSMOS-Bright Survey

The obscured accretion phase in BH growth is a key ingredient in many models linking the AGN activity with the evolution of their host galaxy. At present, a complete census of obscured AGN is still missing. The purpose of this work is to assess the reliability of the [NeV] emission line at 3426 A to pick up obscured AGN up to z~1 by assuming that [NeV] is a reliable proxy of the intrinsic AGN luminosity and using moderately deep X-ray data to characterize the amount of obscuration. A sample of 69 narrow-line (Type 2) AGN at z=0.65-1.20 were selected from the 20k-zCOSMOS Bright galaxy sample on the basis of the presence of the [NeV] emission. The X-ray properties of these galaxies were then derived using the Chandra-COSMOS coverage of the field; the X-ray-to-[NeV] flux ratio, coupled with X-ray spectral and stacking analyses, was then used to infer whether Compton-thin or Compton-thick absorption were present in these sources. Then the [NeV] luminosity function was computed to estimate the space density of Compton-thick (CT) AGN at z~0.8. Twenty-three sources were detected by Chandra, and their properties are consistent with moderate obscuration (on average, ~a few 10^{22} cm^-2). The X-ray properties of the remaining 46 X-ray undetected Type 2 AGN were derived using X-ray stacking analysis. Current data indicate that a fraction as high as ~40% of the present sample is likely to be CT. The space density of CT AGN with logL_2-10keV>43.5 at z=0.83 is (9.1+/-2.1) 10^{-6} Mpc^{-3}, in good agreement with both XRB model expectations and the previously measured space density for objects in a similar redshift and luminosity range. We regard our selection technique for CT AGN as clean but not complete, since even a mild extinction in the NLR can suppress [NeV] emission. Therefore, our estimate of their space density should be considered as a lower limit.Comment: 10 pages, 7 figures, 2 tables, A&A, in pres

Bio-phenols determination in olive oils: Recent mass spectrometry approaches

Extra virgin olive oil (EVOO) is largely used in Mediterranean diet, and it is also worldwide apprised not only for its organoleptic properties but also for its healthy effects mainly attributed to the presence of several naturally occurring phenolic and polyphenolic compounds (bio-phenols). These compounds are characterized by the presence of multiple phenolic groups in more or less complex structures. Their content is fundamental in defining the healthy qualities of EVOO and consequently the analytical methods for their characterization and quantification are of current interest. Traditionally their determination has been conducted using a colorimetric assay based on the reaction of Folin-Ciocalteu (FC) reagent with the functional hydroxy groups of phenolic compounds. Identification and quantification of the bio-phenols in olive oils requires certainly more performing analytical methods. Chromatographic separation is now commonly achieved by HPLC, coupled with spectrometric devices as UV, FID, and MS. This last approach constitutes an actual cutting-edge application for bio-phenol determination in complex matrices as olive oils, mostly on the light of the development of mass analyzers and the achievement of high resolution and accurate mass measurement in more affordable instrument configurations. After a short survey of some rugged techniques used for bio-phenols determination, in this review have been described the most recent mass spectrometry-based methods, adopted for the analysis of the bio-phenols in EVOOs. In particular, the sample handling and the results of HPLC coupled with low- and high-resolution MS and MS/MS analyzers, of ion mobility mass spectrometry and ambient mass spectrometry have been reported and discussed

Do electrospray mass spectra of surfactants mirror their aggregation state in solution?

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The cosmic growth of the active black hole population at 1<z<2 in zCOSMOS, VVDS and SDSS

We present a census of the active black hole population at 1<z<2, by constructing the bivariate distribution function of black hole mass and Eddington ratio, employing a maximum likelihood fitting technique. The study of the active black hole mass function (BHMF) and the Eddington ratio distribution function (ERDF) allows us to clearly disentangle the active galactic nuclei (AGN) downsizing phenomenon, present in the AGN luminosity function, into its physical processes of black hole mass downsizing and accretion rate evolution. We are utilizing type-1 AGN samples from three optical surveys (VVDS, zCOSMOS and SDSS), that cover a wide range of 3 dex in luminosity over our redshift interval of interest. We investigate the cosmic evolution of the AGN population as a function of AGN luminosity, black hole mass and accretion rate. Compared to z = 0, we find a distinct change in the shape of the BHMF and the ERDF, consistent with downsizing in black hole mass. The active fraction or duty cycle of type-1 AGN at z~1.5 is almost flat as a function of black hole mass, while it shows a strong decrease with increasing mass at z=0. We are witnessing a phase of intense black hole growth, which is largely driven by the onset of AGN activity in massive black holes towards z=2. We finally compare our results to numerical simulations and semi-empirical models and while we find reasonable agreement over certain parameter ranges, we highlight the need to refine these models in order to match our observations.Comment: 31 pages, 28 figures, accepted for publication in MNRA

The dense molecular gas in the z∼6\rm z\sim6 QSO SDSS J231038.88+185519.7 resolved by ALMA

We present ALMA observations of the CO(6-5) and [CII] emission lines and the sub-millimeter continuum of the $z\sim6$ quasi-stellar object (QSO) SDSS J231038.88+185519.7. Compared to previous studies, we have analyzed a synthetic beam that is ten times smaller in angular size, we have achieved ten times better sensitivity in the CO(6-5) line, and two and half times better sensitivity in the [CII] line, enabling us to resolve the molecular gas emission. We obtain a size of the dense molecular gas of $2.9\pm0.5$ kpc, and of $1.4\pm0.2$ kpc for the 91.5 GHz dust continuum. By assuming that CO(6-5) is thermalized, and by adopting a CO--to--$H_2$ conversion factor $\rm \alpha_{CO} = 0.8~ M_{\odot}~K^{-1}~ (km/s)^{-1} ~pc^{2}$, we infer a molecular gas mass of $\rm M(H_2)=(3.2 \pm0.2) \times 10^{10}\rm M_{\odot}$. Assuming that the observed CO velocity gradient is due to an inclined rotating disk, we derive a dynamical mass of $\rm M_{dyn}~sin^2(i) = (2.4\pm0.5) \times 10^{10}~ M_{\odot}$, which is a factor of approximately two smaller than the previously reported estimate based on [CII]. Regarding the central black hole, we provide a new estimate of the black hole mass based on the C~IV emission line detected in the X-SHOOTER/VLT spectrum: $\rm M_{BH}=(1.8\pm 0.5) \times 10^{9}~ M_{\odot}$. We find a molecular gas fraction of $\rm \mu=M(H_2)/M^*\sim4.4$, where $\rm M^*\approx M_{dyn} - M(H_2)-M(BH)$. We derive a ratio $v_{rot}/\sigma \approx 1-2$ suggesting high gas turbulence, outflows/inflows and/or complex kinematics due to a merger event. We estimate a global Toomre parameter $Q\sim 0.2-0.5$, indicating likely cloud fragmentation. We compare, at the same angular resolution, the CO(6-5) and [CII] distributions, finding that dense molecular gas is more centrally concentrated with respect to [CII]. We find that the current BH growth rate is similar to that of its host galaxy.Comment: A&A in pres

Blowin' in the wind: both `negative' and `positive' feedback in an obscured high-z Quasar

Quasar feedback in the form of powerful outflows is invoked as a key mechanism to quench star formation in galaxies, preventing massive galaxies to over-grow and producing the red colors of ellipticals. On the other hand, some models are also requiring `positive' AGN feedback, inducing star formation in the host galaxy through enhanced gas pressure in the interstellar medium. However, finding observational evidence of the effects of both types of feedback is still one of the main challenges of extragalactic astronomy, as few observations of energetic and extended radiatively-driven winds are available. Here we present SINFONI near infrared integral field spectroscopy of XID2028, an obscured, radio-quiet z=1.59 QSO detected in the XMM-COSMOS survey, in which we clearly resolve a fast (1500 km/s) and extended (up to 13 kpc from the black hole) outflow in the [OIII] lines emitting gas, whose large velocity and outflow rate are not sustainable by star formation only. The narrow component of Ha emission and the rest frame U band flux from HST-ACS imaging enable to map the current star formation in the host galaxy: both tracers independently show that the outflow position lies in the center of an empty cavity surrounded by star forming regions on its edge. The outflow is therefore removing the gas from the host galaxy (`negative feedback'), but also triggering star formation by outflow induced pressure at the edges (`positive feedback'). XID2028 represents the first example of a host galaxy showing both types of feedback simultaneously at work.Comment: 9 pages, 5 figures, accepted for publication in Ap

Fatty acids and triacylglycerols profiles from sicilian (Cold pressed vs. soxhlet) grape seed oils

Among the Sicilian economic productive sectors, that of wine production has today a considerable economic value. However, with the growth of this sector, notable was the increase in the production of waste, which to date is not only an economic damage for companies, but also a threat to the environment. It is known that waste from wine production has properties (e.g., antioxidants) which have potential reuse at cosmetic, pharmaceutical and nutritional levels to obtain economically sustainable applications. A new goal is given by the recovery of added value compounds from agri-food wastes and by-products. Grape seed oil is a promising vegetable fat and cold pressing does not involve the use of chemicals, which are harmful to health. It implies that cold-pressed seed oils may contain phytochemicals, as well as natural antioxidants, more than refined oils. In this context, this works aims at studying the chemical characterization (triglycerides profile and composition in fatty acids) of grape seed oils obtained from Soxhlet and cold pressed extraction from Sicilian red grape seeds and white grape seeds. The possibility of obtaining high yields of triglycerides and fatty acids from the waste of wine production through new extraction methods would open up new perspectives for the reuse of waste in a human and animal food context. The results of this work allow the opening up of new perspectives to reuse and then reduce these wastes, helping not only to reduce the damage to the environment and costs for companies but also to create a new product that is environmentally sustainable and with an important economic value