Dimerization and low-dimensional magnetism in nanocrystalline TiO2 semiconductors doped by Fe and Co

The report is devoted to an analysis of the structural and magnetic state of the nanocrystalline diluted magnetic semiconductors based on TiO2 doped with Fe and Co atoms. Structural and magnetic characterization of samples was carried out using X-ray diffraction (XRD) analysis, transmission electron microscopy (TEM), X-ray absorption spectroscopy (XAS), electron paramagnetic resonance (EPR) spectroscopy, SQUID magnetometry, and the density functional theory (DFT) calculations. Analysis of the experimental data suggests the presence of non-interacting paramagnetic Fe3+ and Co2+ ions in the high-spin state and negative exchange interactions between them. The important conclusions is that the distribution of dopants in the TiO2 matrix, even at low concentrations of 3d-metal dopant (less than one percent), is not random, but the 3d ions localization and dimerization is observed both on the surface and in the nanoparticles core. Thus, in the paper the quantum mechanical model for describing the magnetic properties of TiO2:(Fe, Co) was suggested. The model operates only with two parameters: paramagnetic contribution of non-interacting 3d-ions and dimers having different exchange interactions between 3d magnetic carriers. © Published under licence by IOP Publishing Ltd

Synthesis of cubic ferrite CoFe2O4 by spray pyrolysis

The phase composition, morphology, and structural parameters of cobalt ferrospinel powders synthesized by spray pyrolysis combined with drop sol-gel combustion are determined. The obtained data are compared with those of the powders synthesized by sol-gel combustion

Spectral and kinetic features of thermoluminescence in hexagonal boron nitride powder after UV-irradiation

Thermally stimulated luminescence (TL) from UV-irradiated h-BN powder synthesized using carbamide technique was studied. Three TL peaks at T max = 380, 500 and 600 K during linear heating with 2 K/s rate in RT - 773 K temperature range were observed. It was found that the 2.90 and 3.25 eV emission bands, which were related with recombination centers on the basis of VN and BO--complexes, dominate in TL spectra of h-BN. Experimental TL glow curves were analyzed in terms of general order kinetics and energy parameters of responsible capture levels were estimated. It was shown, considering the independent data on the luminescent properties of hexagonal boron nitride in different structural states, that TL peaks at 380 K and 600 K were due to traps based on the one-boron and the three-boron centers with thermal depth EA = 0.7 and 1.0 eV, respectively. The possible origin of the trap with EA = 1.6 eV, responsible for the TL peak at 500 K, is discussed. © 2013 Elsevier B.V. All rights reserved

Benchmark of Selected Digital Image Processing Algorithms Implemented in Python

Tato bakalářská práce se zabývá digitálním zpracováním obrazu v Pythonu, popisem vybraných algoritmů, jejich implementací a použitou technologií. Porovnává rychlosti běhu vybraných algoritmů na zpracování obrazu v C++ a Pythonu, potom Pyhonu s využitím speciální knihovny Numpy a mezi překladači PyPy a Cython.This Bachelor thesis deals with the digital image processing in Python, description of selected algorithms their implementation and used technology. Specifically, it is focused on comparison of speed among selected algorithms, implemented in languages C++ and Python, Python with NumPy library and compilers PyPy and Cython.460 - Katedra informatikydobř