A laminar roughness boundary condition

A modified slip boundary condition is obtained to represent the effects of small roughness-like perturbations to an otherwise-plane fixed wall which is acting as a boundary to steady laminar flow of a viscous fluid. In its simplest form, for low local Reynolds number and small roughness slope, this boundary condition involves a constant apparent backflow at the mean surface or, equivalently, represents a shift of the apparent plane boundary toward the flow domain. Extensions of the theory are also made to include finite local Reynolds number and finite roughness slope.E. O. Tuck and A. Kouzoubo

Exact and semiclassical approach to a class of singular integral operators arising in fluid mechanics and quantum field theory

A class of singular integral operators, encompassing two physically relevant cases arising in perturbative QCD and in classical fluid dynamics, is presented and analyzed. It is shown that three special values of the parameters allow for an exact eigenfunction expansion; these can be associated to Riemannian symmetric spaces of rank one with positive, negative or vanishing curvature. For all other cases an accurate semiclassical approximation is derived, based on the identification of the operators with a peculiar Schroedinger-like operator.Comment: 12 pages, 1 figure, amslatex, bibtex (added missing label eq.11

On open venturis

Flow through an open converging-diverging channel, aimed at achieving maximum velocity at the throat.E. O. Tuc

Towards a systematic understanding of the influence of temperature on glycosylation reactions

Glycosidic bond formation is a continual challenge for practitioners. Aiming to enhance the reproducibility and efficiency of oligosaccharide synthesis, we studied the relationship between glycosyl donor activation and reaction temperature. A novel semi-automated assay revealed diverse responses of members of a panel of thioglycosides to activation at various temperatures. The patterns of protecting groups and the thiol aglycon combine to cause remarkable differences in temperature sensitivity among glycosylating agents. We introduce the concept of donor activation temperature to capture experimental insights, reasoning that glycosylations performed below this reference temperature evade deleterious side reactions. Activation temperatures enable a simplified temperature treatment and facilitate optimization of glycosylating agent (building block) usage. Isothermal glycosylation below the activation temperature halved the equivalents of building block required in comparison to the standard ‘ramp’ regime used in solution- and solid-phase oligosaccharide synthesis to-date

Free-surface pressure distributions with minimum wave resistance

The wave resistance of distributions of excess pressure over a rectangular region on the surface of a steady stream is minimised by choice of spatial variation in pressure. Both unconstrained and constrained (non-negative) pressures are studied. Results with impressive resistance reductions are provided, both via discretisation to a large number of step pressures, and via optimisation within a low-order continuous family

Steady two dimensional free-surface flow over semi-infinite and finite-length corrugations in an open channel

Free-surface flow past a semi-infinite or a finite length corrugation in an otherwise flat and horizontal open channel is considered. Numerical solutions for the steady flow problem are computed using both a weakly nonlinear and fully nonlinear model. The new solutions are classified in terms of a depth-based Froude number and the four classical flow types (supercritical, subcritical, generalised hydraulic rise and hydraulic rise) for flow over a small bump. While there is no hydraulic fall solution for semi-infinite topography, we provide strong numerical evidence that such a solution does exist in the case of a finite length corrugation. Numerical solutions are also found for the other flow types for either semi-infinite or finite length corrugation. For subcritical flow over a semi-infinite corrugation, the free-surface profile is found to be quasiperiodic in nature. A discussion of the new results is made with reference to the classical problem of flow over a bump

Conformal Mapping on Rough Boundaries II: Applications to bi-harmonic problems

We use a conformal mapping method introduced in a companion paper to study the properties of bi-harmonic fields in the vicinity of rough boundaries. We focus our analysis on two different situations where such bi-harmonic problems are encountered: a Stokes flow near a rough wall and the stress distribution on the rough interface of a material in uni-axial tension. We perform a complete numerical solution of these two-dimensional problems for any univalued rough surfaces. We present results for sinusoidal and self-affine surface whose slope can locally reach 2.5. Beyond the numerical solution we present perturbative solutions of these problems. We show in particular that at first order in roughness amplitude, the surface stress of a material in uni-axial tension can be directly obtained from the Hilbert transform of the local slope. In case of self-affine surfaces, we show that the stress distribution presents, for large stresses, a power law tail whose exponent continuously depends on the roughness amplitude

Structural relaxation in a system of dumbbell molecules

The interaction-site-density-fluctuation correlators, the dipole-relaxation functions, and the mean-squared displacements of a system of symmetric dumbbells of fused hard spheres are calculated for two representative elongations of the molecules within the mode-coupling theory for the evolution of glassy dynamics. For large elongations, universal relaxation laws for states near the glass transition are valid for parameters and time intervals similar to the ones found for the hard-sphere system. Rotation-translation coupling leads to an enlarged crossover interval for the mean-squared displacement of the constituent atoms between the end of the von Schweidler regime and the beginning of the diffusion process. For small elongations, the superposition principle for the reorientational $\alpha$-process is violated for parameters and time intervals of interest for data analysis, and there is a strong breaking of the coupling of the $\alpha$-relaxation scale for the diffusion process with that for representative density fluctuations and for dipole reorientations.Comment: 15 pages, 14 figures, Phys. Rev. E in pres

Steady free-surface flow at the stern of a ship

New solutions for steady two-dimensional free-surface flow past a curved plate are considered here. They can be interpreted as approximations to the flow locally at the stern of a ship. Weakly nonlinear solutions are derived analytically and nonlinear solutions are computed by boundary integral equation methods. Analysis in the phase plane provides a way to determine the geometries of hulls that give rise to wave-free stern flows. These waveless flows are desirable as they reduce ship-drag