1,983 research outputs found
Ectomycorrhiza formation in Eucalyptus.. IV. Ectomycorrhizas in the sporocarps of the hypogeous fungi Mesophellia and Castorium in Eucalypt forests of Western Australia
Mesophellia and Castorium are common hypogeous macrofungi in the karri (Eucalyptus diversicolor F. Muell.) and jarrah (Eucalyptus marginata Donn ex Sm.) forests of south‐western Australia. Sporocarps of Mesophellia and Castorium develop 5‐20 cm below the soil surface in close association with eucalypt roots. During differentiation of the sporocarps, eucalypt roots become trapped within the peridium where they branch profusely and form a dense ectomycorrhizal layer. Mature sporocarps of M. trabalis nom. ined. contain approximately S m of roots of 45 cm2 surface area. Anatomical studies have shown that these roots have Hartig nets penetrating to the hypodermis and are similar to the superficial eucalypt ectomycorrhizas formed in soil and litter. The association of Mesophellia and Castorium sporocarps with tree roots suggests that these are important mycorrhizal fungi in forests of southern Australia
Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation
Liquid mixtures involving fluorinated alcohols:
The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol)
Experimental and Simulation
Pedro Duartea, Djêide Rodriguesa, Marcelo Silvaa, Pedro Morgadoa,
Luís Martinsa,b and Eduardo J. M. Filipea*
aCentro de Química Estrutural, Instituto Superior Técnico, 1049-001 Lisboa, Portugal
bCentro de Química de Évora, Universidade de Évora, 7000-671 Évora, Portugal
Fluorinated alcohols are substances with unique properties and high technological value in the pharmaceutical and chemical industries. Trifluoroethanol (TFE), in particular, displays a number of unusual properties as a solvent. For example, it dissolves nylon at room temperature and is effectively used as solvent in bioengineering. The presence of the three fluorines atoms gives the alcohol a high ionization constant, strong hydrogen bonding capability and stability at high temperatures.
In the pharmaceutical industry, TFE finds use as the major raw material for the production of inhalation anesthetics. Mixtures of TFE and water (known as Fluorinols®) are used as working fluids for Rankine cycle heat engines for terrestrial and space applications, as a result of a unique combination of physical and thermodynamic properties such as high thermal efficiency and excellent turbine expansion characteristics.
Environmentally, TFE is a CFC substitute with an acceptable short lifetime and with small ozone depletion potential. Additionally, TFE is known to induce conformational changes in proteins and it is used as a co-solvent to analyze structural features of partially folded states.
The (ethanol + TFE) system displays an interesting and peculiar behaviour, combining a negative azeotrope with high positive excess volumes.
In this work, liquid mixtures of (ethanol + TFE) were investigated. The densities of the mixtures were measured as a function of composition between 278K and 338K and at pressures up to 700 bar. The corresponding excess volumes as a function of temperature and pressure, the isothermal compressibilities and thermal expansivities were calculated from the experimental results. The mixtures are highly non-ideal with excess volumes ranging from 0.8 - 1.0 cm3mol-1.
Finally, molecular dynamic simulations were performed to model and interpret the experimental results. The Trappe force field was used to simulate the (TFE + ethanol) mixtures and calculate the corresponding excess volumes. The simulation results are able to reproduce the correct sign and order of magnitude of the experimental VE without fitting to the experimental data. Furthermore, the simulations suggest the presence of a particular type of hydrogen bridge between ethanol and TFE, that can help to rationalize the experimental results
Circular frame fixation for calcaneal fractures risks injury to the medial neurovascular structures: a cadaveric description
Aim: There is a risk of iatrogenic injury to the soft tissues of the calcaneus and this study assesses the risk of injury to these structures in circular frame calcaneal fracture fixation.
Materials and Methods: After olive tip wires were inserted, an L-shaped incision on the lateral and medial aspects of 5 formalin fixed cadaveric feet was performed to expose the underlying soft tissues. The calcaneus was divided into zones corresponding to high, medium and low risk using a grading system.
Results: Structures at high risk included the posterior tibial artery, posterior tibial vein and posterior tibial nerve on the medial aspect. Soft tissue structures on the lateral side that were shown to be at lower risk of injury were the small saphenous vein and the sural nerve and the tendons of fibularis longus and fibularis brevis.
Conclusion: The lateral surface of the calcaneus provides a lower risk area for external fixation. The risk of injury to significant soft tissues using a circular frame fixation approach has been shown to be greater on the medial aspect.
Clinical Relevance: This study highlights the relevant anatomical relations in circular frame fixation for calcaneal fractures to minimize damage to these structures
DECREASED PAIN SCALE BASED ON CRITICAL PAIN OBSERVATION TOOL (CPOT) AND BEHAVIORAL PAIN SCALE NON-INTUBATED (BPS-NI) IN PATIENTS WITH REDUCED CONSCIOUSNESS BY CLASSICAL MUSIC INTERVENTION IN UNS HOSPITAL
Patient with reduced consciousness needs attention to their comfort as well as pain during treatment. Listening to classical music caused relaxation and pain reduction. This study aimed to determine the effect of classical music on the CPOT score, BPS-NI, and cortisol levels in patients with reduced consciousness. The research was conducted by using a pretest-posttest control group design. 18 patients were divided into the control group (C) and the classical music group (M). Classical music was played for 3 days respectively that consisted of 3 sessions per day. Furthermore, each patient was tested for cortisol levels on the third day. Comparative test of mean difference between pre-intervention and post-intervention obtained significant results in CPOT (p= 0.000) and BPS-NI (p= 0.001) measurements in all groups. Tukey's post-hoc test obtained significant results in which the M group had a lower mean score. The mean of cortisol level was higher in M group (14.7 μg/dL) compared to the C group (12.96 μg/dL), although not significant statistically (p= 0.67). Listening to classical music for patients with reduced consciousness decreased the pain scale. This was supported by the average of cortisol levels that were higher in the M group, considering that cortisol was a hormone that prevents pain
Mapping dynamical heterogeneity in structural glasses to correlated fluctuations of the time variables
Dynamical heterogeneities -- strong fluctuations near the glass transition --
are believed to be crucial to explain much of the glass transition
phenomenology. One possible hypothesis for their origin is that they emerge
from soft (Goldstone) modes associated with a broken continuous symmetry under
time reparametrizations. To test this hypothesis, we use numerical simulation
data from four glass-forming models to construct coarse grained observables
that probe the dynamical heterogeneity, and decompose the fluctuations of these
observables into two transverse components associated with the postulated
time-fluctuation soft modes and a longitudinal component unrelated to them. We
find that as temperature is lowered and timescales are increased, the time
reparametrization fluctuations become increasingly dominant, and that their
correlation volumes grow together with the correlation volumes of the dynamical
heterogeneities, while the correlation volumes for longitudinal fluctuations
remain small.Comment: v4: Detailed analysis of transverse and longitudinal parts. One
figure removed, two added. v3: Explicit decomposition into transverse and
longitudinal parts, discussion of correlation volumes. One more figure v2:
Modified introduction and forma
Temporal Changes in Astronauts Muscle and Cardiorespiratory Physiology Pre-, In-, and Post-Spaceflight
NASAs vision for future exploration missions depends on the ability to protect astronauts health and safety for performance of Extravehicular Activity (EVA), and to allow astronauts to safely egress from vehicles in a variety of landing scenarios (e.g. water landing upon return to Earth and undefined planetary/lunar landings). Prolonged exposure to spaceflight results in diminished tolerance to prolonged physical activity, decreased cardiac and sensorimotor function, and loss of bone mineral density, muscle mass, and muscle strength. For over 50 years exercise has been the primary countermeasure against these physiologic decrements during spaceflight, and while the resulting protection is adequate for ISS missions (i.e., Soyuz landing, microgravity EVAs), there is little information regarding time-course changes in muscle and aerobic performance. As spaceflight progresses towards longer exploration missions and vehicles with less robust exercise capabilities compared to ISS, countermeasures will need to be combined and optimized to protect crew health and performance across all organ systems over the course of exploration missions up to 3 years in duration. This will require a more detailed understanding of the dynamic effects of spaceflight on human performance. Thus, the focus of this study is quantifying decrements in physical performance over different mission durations, and to provide detailed information on the physiological rational for why and when observed changes in performance occur. The research proposed will temporally profile changes in astronauts cardiorespiratory fitness, muscle mass, strength, and endurance over spaceflight missions of 2 months, 6 months, and up to 1 year in duration. Additionally, an extrapolation model will provide predictions for changes associated with exploration missions 2-3 years in duration. To accomplish these objectives astronauts will be asked to participate in pre, in, post-flight measurement of muscle performance, muscle size, cardiorespiratory fitness and submaximal performance capabilities, as well as non-invasive assessment of cerebral and muscle oxygenation and perfusion (Table 1). Additionally, ambulatory and in-flight exercise, nutrition, and sleep will be monitored using a variety of commercial technologies and in-flight assessment tools. Significance: Our detailed testing protocol will provide valuable information for describing how and when spaceflight-induced muscle and aerobic based adaptations occur over the course of spaceflight missions up to and beyond 1 year. This information will be vital in the assessment as to whether humans can be physically ready for deep space exploration such as Mars missions with current technology, or if additional mitigation strategies are necessary
Swimming turn performance: the distinguishing factor in 1500 m world championship freestyle races?
Objective: Turn sections represent the second largest part of total race time in 1500 m freestyle races and may substantially affect race results. Therefore, the aim of the study was to investigate individual race strategies and compare the effect of start, swim, and turn performances between short-course and long-course races. Video footages were collected from all 16 male finalists at the 2018 short and 2019 long-course World swimming championships (age 23.06 ± 2.3 years, FINA points 941 ± 42) for subsequently analysis of start, turn, and swim performance.
Results: The larger number of turns in short-course races resulted in significantly faster race times (p = 0.004), but slower mean turn times compared to long-course races (p < 0.001). Total race velocity closely correlated with swim and turn but not start section velocity in short- (r ≥ 0.80, p ≤ 0.017) and long-course races (r ≥ 0.83, p ≤ 0.011). Analysis of individual race strategies showed that turn performance affected race results in 6 (75%) and 3 (37.5%) of the 8 world-best 1500 m swimmers in short-course and long-course races, respectively. Medal standing was improved for 1st, 3rd, and 4th ranked short- as well as 1st and 2nd ranked long-course finalist. Coaches, athletes, and performance analysts may carefully consider the importance of turn performance additionally to free-swimming skills
The historical newspaper, and their cooperation with the Jagellonian University of Krakow
IBM Digital Archive Seminar in Warschau 12.-13.06.0
Ethnobiological notes and volatile profiles of two rare Chinese desert truffles
The production of a distinct profile of volatile organic compounds plays a crucial role in the ecology of hypogeous Ascomycetes, and is also key to their gastronomic relevance. In this study, we explored the aroma components of two rarely investigated Chinese desert truffles, namely Mattirolomyces terfezioides and Choiromyces cerebriformis, using headspace solid-phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS). Our investigation revealed the significant presence of sulphur-containing volatiles in the aroma of M. terfezioides but not in C. cerebriformis. We discussed available information on the distribution of these interesting truffles in China and their use as choice food by local people
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