235 research outputs found
Internal Rotation of Disilane and Related Molecules:a Density Functional Study
DFT calculations performed on Si_2H_6, Si_2F_6, Si_2Cl_6, and Si_2Br_6 are
reported. The evolution of the energy, the chemical potential and the molecular
hardness, as a function of torsion angle, is studied. Results at the
DFT-B3LYP/6-311++G** level show that the molecules always favor the stable
staggered conformations, with low but significant energy barriers that hinder
internal rotation. The chemical potential and hardness of Si_2H_6 remains quite
constant as the sylil groups rotate around the Si-Si axis, whereas the other
systems exhibit different degrees of rearrangement of the electronic density as
a function of the torsion angle. A qualitative analysis of the frontier
orbitals shows that the effect of torsional motion on electrophilic attack is
negligible, whereas this internal rotation may generate different specific
mechanisms for nucleophilic attack.Comment: LATeX file, 7 figures, uses elsart.cls, natbib, graphic
Anomalies and Fermion Content of Grand Unified Theories in Extra Dimensions
The restrictions imposed by anomaly cancellation on the chiral fermion
content of nonsupersymmetric gauge theories based on various groups are studied
in spacetime dimension D=6, 8, and 10. In particular, we show that the only
mathematically consistent chiral SU(5) theory in D=6 contains three
nonidentical generations.Comment: 15 pages, revtex. v2: references added to match published versio
Measurement of Hydrogen Permeation of Stainless Steel by Electron Stimulated Desorption (ESD) Method
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Confucius computer: a philosophical digital agent for intergenerational philosophical play
Confucianism is commonly defined as â... a system of philosophical, ethical and political thought based on the teachings of Confucius,â which originated through the teachings of Confucius during the sixth-century BCE. It is a way of life or a philosophy of human nature that considers human relationships as the foundation of the society. Confucius teachings had highly influenced the development of several cultures in Asia, making Confucianism an intangible cultural heritage. In this paper, we are re-acquainting users with an intangible heritage that is part of their everyday, by developing a system that permits experiencing Confucius teachings virtually and interactively. The system can measure philosophical intent of the human and generate meaningful philosophical answers. It is also aimed for intergenerational sharing of Confucius heritage through a simple interactive process with the virtual sage making the experience enjoyable and entertaining. Previous research in natural language processing (NLP) mainly focused on the understanding and delivering of human natural language accurately. In this research, we explored how to apply NLP to model the knowledge and teachings of Confucius, through the natural conversation between human and computer. This virtual Confucius, a chat agent that generates outputs based on Confucius teachings, using a series of algorithms and techniques to improve the matching accuracy between user input and computer output, introduces a novel way of interacting with intangible cultures. Our user evaluation results revealed that there is a positive correlation between relevance and enjoyment, finding their experiences interacting with virtual Confucius very encouraging. Adults who participated in experiencing the virtual Confucius together with their children believed that this system has the potential to improve intergenerational interactions through shared play
Accelerating Universe from an Evolving Lambda in Higher Dimension
We find exact solutions in five dimensional inhomogeneous matter dominated
model with a varying cosmological constant. Adjusting arbitrary constants of
integration one can also achieve acceleration in our model. Aside from an
initial singularity our spacetime is regular everywhere including the centre of
the inhomogeneous distribution. We also study the analogous homogeneous
universe in (4+d) dimensions. Here an initially decelerating model is found to
give late acceleration in conformity with the current observational demands. We
also find that both anisotropy and number of dimensions have a role to play in
determining the time of flip, in fact the flip is delayed in multidimensional
models. Some astrophysical parameters like the age, luminosity distance etc are
also calculated and the influence of extra dimensions is briefly discussed.
Interestingly our model yields a larger age of the universe compared to many
other quintessential models.Comment: 18 pages, 9 figure
Isolation and fine mapping of Rps6: An intermediate host resistance gene in barley to wheat stripe rust
A plant may be considered a nonhost of a pathogen if all known genotypes of a plant species are resistant to all known isolates of a pathogen species. However, if a small number of genotypes are susceptible to some known isolates of a pathogen species this plant maybe considered an intermediate host. Barley (Hordeum vulgare) is an intermediate host for Puccinia striiformis f. sp. tritici (Pst), the causal agent of wheat stripe rust. We wanted to understand the genetic architecture underlying resistance to Pst and to determine whether any overlap exists with resistance to the host pathogen, Puccinia striiformis f. sp. hordei (Psh). We mapped Pst resistance to chromosome 7H and show that host and intermediate host resistance is genetically uncoupled. Therefore, we designate this resistance locus Rps6. We used phenotypic and genotypic selection on F2:3 families to isolate Rps6 and fine mapped the locus to a 0.1 cM region. Anchoring of the Rps6 locus to the barley physical map placed the region on two adjacent fingerprinted contigs. Efforts are now underway to sequence the minimal tiling path and to delimit the physical region harbouring Rps6. This will facilitate additional marker development and permit identification of candidate genes in the region
The Sacred Geography of Dawei: Buddhism in peninsular Myanmar (Burma)
The paper opens by recounting the beginnings of Buddhism in Dawei as preserved in local chronicles and sustained in stupas marking the episodes of the chronicle narrative. The chronicles start with a visit of the Buddha whose arrival triggers a series of events bringing together pre-existing tutelary figures, weiza, a hermit and offspring born of a golden fish, culminating in the establishment of the first Buddhist kingdom circa the eighth to tenth century CE. The enshrinement of sacred hairs gifted by the Buddha also includes patronage by a king of the âSuvannbhumiâ lineage. Associated with the monks Sona and Uttara from Sri Lanka sent by King Asokaâs son Mahinda, âSuvannbhumiâ literally can refer to the archaeology of Thaton, a walled site in the present day Mon State, or, as is the case here, more widely to the missionary tradition associated with Asoka (Sao Saimong Mengrai 1976). The third story in the establishment of the Buddhist king at Thagara is the longest of the chronicle, the tale of a royal hunter who failed to capture a golden peacock for the queen. The hunter became a hermit living by a pond with a golden fish and as he urinated in the pond, two children were born from the fish. The boy becomes the first Buddhist king of Thagara, 11 km north of Dawei, where artefacts from survey and excavation confirm the chronology of the chronicle, with the closest archaeological parallels found not at the ancient sites of the Mon State but to the first millennium CE Buddhist âPyuâ heritage of Upper Myanmar which is notably absent in the chronicle compilation
Magnetic Reconnection Triggered by the Parker Instability in the Galaxy: Two-Dimensional Numerical Magnetohydrodynamic Simulations and Application to the Origin of X-Ray Gas in the Galactic Halo
We propose the Galactic flare model for the origin of the X-ray gas in the
Galactic halo. For this purpose, we examine the magnetic reconnection triggered
by Parker instability (magnetic buoyancy instability), by performing the
two-dimensional resistive numerical magnetohydrodynamic simulations. As a
result of numerical simulations, the system evolves as following phases: Parker
instability occurs in the Galactic disk. In the nonlinear phase of Parker
instability, the magnetic loop inflates from the Galactic disk into the
Galactic halo, and collides with the anti-parallel magnetic field, so that the
current sheets are created in the Galactic halo. The tearing instability
occurs, and creates the plasmoids (magnetic islands). Just after the plasmoid
ejection, further current-sheet thinning occurs in the sheet, and the anomalous
resistivity sets in. Petschek reconnection starts, and heats the gas quickly in
the Galactic halo. It also creates the slow and fast shock regions in the
Galactic halo. The magnetic field (G), for example, can heat the
gas ( cm) to temperature of K via the
reconnection in the Galactic halo. The gas is accelerated to Alfv\'en velocity
( km s). Such high velocity jets are the evidence of the
Galactic flare model we present in this paper, if the Doppler shift of the
bipolar jet is detected in the Galactic halo. Full size figures are available
at http://www.kwasan.kyoto-u.ac.jp/~tanuma/study/ApJ2002/ApJ2002.htmlComment: 13 pages, 12 figures, uses emulateapj.sty, accepted by Ap
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