Shelf Seas Baroclinic Energy Loss: Pycnocline Mixing and Bottom Boundary Layer Dissipation

Observations of turbulent kinetic energy dissipation rate from a range of historical shelf seas data sets are viewed from the perspective of their forcing and dissipation mechanisms: barotropic to baroclinic tidal energy conversion, and pycnocline and bottom boundary layer (BBL) dissipation. The observations are placed in their geographical context using a high resolution numerical model (NEMO AMM60) in order to compute relevant maps of the forcing (conversion). We analyze, in total, 18 shear microstructure surveys undertaken over a 17 year period from 1996 to 2013 on the North West European shelf, consisting of 3,717 vertical profiles of shear microstructure: 2,013 from free falling profilers and 1,704 from underwater gliders. A robust positive relationship is found between model-derived barotropic to baroclinic conversion, and observed pycnocline integrated. A fitted power law relationship of approximately one-third is found, giving a simple new parameterization. We discuss reasons for this apparent power law and where the “missing” dissipation may be occurring. We conclude that internal wave related dissipation in the bottom boundary layer provides a robust explanation and is consistent with a commonly used fine-scale pycnocline dissipation parameterization

Impact and recovery of pH in marine sediments subject to a temporary carbon dioxide leak

© 2014 The Authors. Published by Elsevier Ltd. A possible effect of a carbon dioxide leak from an industrial sub-sea floor storage facility, utilised for Carbon Capture and Storage, is that escaping carbon dioxide gas will dissolve in sediment pore waters and reduce their pH. To quantify the scale and duration of such an impact, a novel, field scale experiment was conducted, whereby carbon dioxide gas was injected into unconsolidated sub-sea floor sediments for a sustained period of 37 days. During this time pore water pH in shallow sediment (5 mm depth) above the leak dropped \u3e0.8 unit, relative to a reference zone that was unaffected by the carbon dioxide. After the gas release was stopped, the pore water pH returned to normal background values within a three-week recovery period. Further, the total mass of carbon dioxide dissolved within the sediment pore fluids above the release zone was modelled by the difference in DIC between the reference and release zones. Results showed that between 14 and 63% of the carbon dioxide released during the experiment could remain in the dissolved phase within the sediment pore water

Vertical mixing alleviates autumnal oxygen deficiency in the central North Sea

There is an immediate need to better understand and monitor shelf sea dissolved oxygen (O2) concentrations. Here we use high-resolution glider observations of turbulence and O2 concentrations to directly estimate the vertical O2 flux into the bottom mixed layer (BML) immediately before the autumn breakdown of stratification in a seasonally stratified shelf sea. We present a novel method to resolve the oxycline across sharp gradients due to slow optode response time and optode positioning in a flow “shadow zone” on Slocum gliders. The vertical O2 flux to the low-O2 BML was found to be between 2.5 to 6.4 mmol m−2 d−1. Episodic intense mixing events were responsible for the majority (up to 90 %) of this oxygen supply despite making up 40 % of the observations. Without these intense mixing events, BML O2 concentrations would approach ecologically concerning levels by the end of the stratified period. Understanding the driving forces behind episodic mixing and how these may change under future climate scenarios and renewable energy infrastructure is key for monitoring shelf sea health

Vertical mixing alleviates autumnal oxygen deficiency in the central North Sea

There is an immediate need to better understand and monitor shelf sea dissolved oxygen (O2) concentrations. Here we use high-resolution glider observations of turbulence and O2 concentrations to directly estimate the vertical O2 flux into the bottom mixed layer (BML) immediately before the autumn breakdown of stratification in a seasonally stratified shelf sea. We present a novel method to resolve the oxycline across sharp gradients due to slow optode response time and optode positioning in a flow “shadow zone” on Slocum gliders. The vertical O2 flux to the low-O2 BML was found to be between 2.5 to 6.4 mmol m−2 d−1. Episodic intense mixing events were responsible for the majority (up to 90 %) of this oxygen supply despite making up 40 % of the observations. Without these intense mixing events, BML O2 concentrations would approach ecologically concerning levels by the end of the stratified period. Understanding the driving forces behind episodic mixing and how these may change under future climate scenarios and renewable energy infrastructure is key for monitoring shelf sea health

Challenging vertical turbulence mixing schemes in a tidally energetic environment: 1. 3‐D shelf‐sea model assessment

Mixing in the ocean and shelf seas is critical for the vertical distribution of dynamically active properties, such as density and biogeochemical tracers. Eight different decadal simulations are used to assess the skill of vertical turbulent mixing schemes (TMS) in a 3‐D regional model of tidally active shelf seas. The TMS differ in the type of stability functions used and in the Ozmidov/Deardorff/Galperin limiter of the turbulence length scales. We review the dependence of the critical Richardson and Prandtl numbers to define the “diffusiveness” of the TMS. The skill in representing bias and variability of stratification profiles is assessed with five different metrics: surface and bottom temperatures and pycnocline depth, thickness, and strength. The assessment is made against hydrography from three data sets (28,000 profiles in total). Bottom and surface temperatures are found to be as sensitive to TMS choice as to horizontal resolution or heat flux formulation, as reported in other studies. All TMS underrepresent the pycnocline depth and benthic temperatures. This suggests physical processes are missing from the model, and these are discussed. Different TMSs show the best results for different metrics, and there is no outright winner. Simulations coupled with an ecosystem model show the choice of TMS strongly affects the ecosystem behavior: shifting the timing of peak chlorophyll by 1 month, showing regional chlorophyll differences of order 100%, and redistributing the production of chorophyll between the pycnocline and mixed layer

A novel sub-seabed CO\u3csub\u3e2\u3c/sub\u3e release experiment informing monitoring and impact assessment for geological carbon storage

© 2014 The Authors. Carbon capture and storage is a mitigation strategy that can be used to aid the reduction of anthropogenic CO2 emissions. This process aims to capture CO2 from large point-source emitters and transport it to a long-term storage site. For much of Europe, these deep storage sites are anticipated to be sited below the sea bed on continental shelves. A key operational requirement is an understanding of best practice of monitoring for potential leakage and of the environmental impact that could result from a diffusive leak from a storage complex. Here we describe a controlled CO2 release experiment beneath the seabed, which overcomes the limitations of laboratory simulations and natural analogues. The complex processes involved in setting up the experimental facility and ensuring its successful operation are discussed, including site selection, permissions, communications and facility construction. The experimental design and observational strategy are reviewed with respect to scientific outcomes along with lessons learnt in order to facilitate any similar future

A novel sub-seabed CO₂ release experiment informing monitoring and impact assessment for geological carbon storage

Carbon capture and storage is a mitigation strategy that can be used to aid the reduction of anthropogenic CO2 emissions. This process aims to capture CO2 from large point-source emitters and transport it to a long-term storage site. For much of Europe, these deep storage sites are anticipated to be sited below the sea bed on continental shelves. A key operational requirement is an understanding of best practice of monitoring for potential leakage and of the environmental impact that could result from a diffusive leak from a storage complex. Here we describe a controlled CO2 release experiment beneath the seabed, which overcomes the limitations of laboratory simulations and natural analogues. The complex processes involved in setting up the experimental facility and ensuring its successful operation are discussed, including site selection, permissions, communications and facility construction. The experimental design and observational strategy are reviewed with respect to scientific outcomes along with lessons learnt in order to facilitate any similar future

Stratification in a shelf sea: response to different atmospheric forcings

Continental shelves comprise a small portion of the world ocean, yet they are a key contributor to ocean carbon uptake with their immense biological productivity. On-set of spring stratification is one of the physical factors that influence the productivity of the continental shelves. Atmospheric convective mixing determines the on-set of stratification. This is particularly important in seasonally stratified shelf seas, where stratification inhibits nutrient injection to the upper water column. Higher productivity during the stratified period relies on intermittent diapycnal mixing events. Thus, the on-set and intensity of stratification is important for the functioning of the shelf-sea ecosystem. In this study, we investigate the period of on-set of spring stratification and its relation with atmospheric conditions using high resolution in-situ measurements from 10 glider deployments, spanning over 18 months in the central North Sea. Focusing on two consecutive winter-to-spring periods we investigate year to year variability in the timing and intensity of stratification. We observe an early initiation of stratification in 2018/2019, which is more intense than the previous year of 2017/2018. We identify that reduced wind stress and net air-sea heat fluxes result in an early on-set of stratification in 2018/2019. In February 2019, intermittent increases in chlorophyll are observed, corresponding to a minimum in sea-to-air heat loss. Similarly, in 2019 an earlier spring bloom is observed. The two years are characterised by a shift in winter NAO index, which is positive in 2017/2018 and negative in 2018/2019. We subsequently investigate the connections between variability in seasonal stratification on a continental shelf sea and large-scale atmospheric circulation patterns using the outputs of the 7km NEMO-shelf model (AMM7)