Nanostructures originales obtenues par décomposition catalytique d'hydrocarbure

National audienceL'arc électrique et la décomposition catalytique d'hydrocarbures peuvent produire diverses nanostructures de carbone, telles que fullerènes, nanotubes, nanofibres et autres particules nanométriques de carbone. Une publication récente1 décrit la préparation et la séparation de nanobâtonnets de carbone dans la suie produite par arc électrique. Ici nous présentons la fabrication de nanobâtonnets de carbone par décomposition catalytique d'hydrocarbures, ainsi que des fibrilles de quelques nanomètres de diamètre et de quelques dizaines de nanomètres de longueur poussant perpendiculairement à la particule de catalyseur

Centrifuge rolling test for ore liquefaction analysis

To study the development of liquefaction in ore cargo, a new Rolling Test has been designed to support similar stresses than those observed in a vessel. It can be used in an 80×g macrogravity field in the 5.5m radius Ifsttar geo-centrifuge. Its main characteristics are presented

Analysis of tissue surrounding thyroid nodules by ultrasound digital images

Since US is not easily reproducible, the digital image analysis (IA) has been proposed so that the image evaluation is not subjective. In fact, IA meets the criteria of objectivity, accurateness, and reproducibility by a matrix of pixels whose value is displayed in a gray level. This study aims at evaluating via IA the tissue surrounding a thyroid nodule (backyard tissue, BT) from goitres with benign (b-BT) and malignant (m-BT) lesions. Sixty-nine US images of thyroid nodules surrounded by adequate thyroid tissue was classified as normoechoic and homogeneous were enrolled as study group. Forty-three US images from normal thyroid (NT) glands were included as controls. Digital images of 800 × 652 pixels were acquired at a resolution of eight bits with a 256 gray levels depth. By one-way ANOVA, the 43 NT glands were not statistically different (P = 0.91). Mean gray level of normal glands was significantly higher than b-BT (P = 0.026), and m-BT (P = 0.0001), while no difference was found between b-BT and m-BT (P = 0.321). NT tissue boundary external to the nodule was found at 6.0 ± 0.5 mm in cancers and 4.0 ± 0.5 mm in benignancies (P = 0.001). These data should indicate that the tissue surrounding a thyroid nodule may be damaged even when assessed as normal by US. This is of interest to investigate the extranodular effects of thyroid tumors

Electrochemical testing of an innovative dual membrane fuel cell design in reversible mode

Solid oxide fuel Cells (SOFC) are intrinsically reversible which makes them attractive for the development of reversible devices (rSOC). The main hurdles that have to be overcome are the higher degradation in electrolyzer (EL) mode and the slow and difficult switching form mode to mode. This work aims at the development and experimental validation of a concept for rSOC based on a new dual membrane fuel cell (dmFC) design which can overcome the existing problems of the classical SOFC. The kernel of the system is additional chamber - central membrane (CM) for water formation/evacuation in FC mode and injection in El mode. Its optimization in respect of microstructure and geometry in laboratory conditions is carried out on button cells. The electrochemical performance is evaluated based on volt-ampere characteristics (VACs) combined with impedance measurements in different working points. The influence of a catalyst in the water chamber is also examined. The VACs which give integral picture of the cell performance are in excellent agreement with the impedance studies which ensure deeper and quantitative information about the processes, including information about the rate limiting step. The results from the optimization of the water chamber show that the combination of design and material brings to important principle advantages in respect to the classical rSOC \u2013 better performance in electrolyzer mode combined with instantaneous switching

Impedance investigation of BaCe0.85Y0.15O3-delta properties for hydrogen conductor in fuel cells

International audienceThe influence of the sintering conditions on the electrochemical properties of the proton conducting electrolyte BaCe0.85Y0.15O3-delta (BCY15) and Ni - based BCY15 cermet anode for application in high temperature proton conducting fuel cell are investigated by electrochemical impedance spectroscopy. The results show that at lower sintering temperatures due to the formation of parasitic Y2O3 phase an increase of both the electrolyte and electrode resistances is observed. This effect is strongly reduced by enhancement of the sintering temperature. The obtained BCY15 conductivity (sigma = 2.5x10(-2) S/cm at 700 degrees C) is comparable with that of the best proton conducting materials, while the BCY15-Ni cermet (with ASR = 2.5 Omega cm(2) at 700 degrees C) needs further optimization. The results of impedance investigations of BCY15 as proton conducting electrolyte and cermet anode have been applied in development of innovative high temperature dual membrane fuel cell

Why pinning by surface irregularities can explain the peak effect in transport properties and neutron diffraction results in NbSe2 and Bi-2212 crystals?

The existence of a peak effect in transport properties (a maximum of the critical current as function of magnetic field) is a well-known but still intriguing feature of type II superconductors such as NbSe2 and Bi-2212. Using a model of pinning by surface irregularities in anisotropic superconductors, we have developed a calculation of the critical current which allows estimating quantitatively the critical current in both the high critical current phase and in the low critical current phase. The only adjustable parameter of this model is the angle of the vortices at the surface. The agreement between the measurements and the model is really very impressive. In this framework, the anomalous dynamical properties close to the peak effect is due to co-existence of two different vortex states with different critical currents. Recent neutron diffraction data in NbSe2 crystals in presence of transport current support this point of view

Structure of the flux lines lattice in NbSe2: Equilibrium state and influence of the magnetic history

We have performed small-angle neutron scattering (SANS) of the flux line lattice (FLL) in a Fe doped NbSe_2 sample which presents a large peak effect in the critical current. The scattered intensity and the width of the Bragg peaks of the equilibrium FLL indicate an ordered structure in the peak effect zone. The history dependence in the FLL structure has been studied using field cooled and zero field cooled procedures, and each state shows the same intensity of Bragg scattering and good orientational order. These results strongly suggest that the peak effect is unrelated to a bulk disordering transition, and confirm the role of a heterogeneous distribution of screening current.Comment: accepted in Phys. Rev.

Moving glass phase of driven lattices

We study periodic lattices, such as vortex lattices, driven by an external force in a random pinning potential. We show that effects of static disorder persist even at large velocity. It results in a novel moving glass state with topological order analogous to the static Bragg glass. The lattice flows through well-defined, elastically coupled, {\it % static} channels. We predict barriers to transverse motion resulting in finite transverse critical current. Experimental tests of the theory are proposed.Comment: Revised version, shortened, 8 pages, REVTeX, no figure

Toxicity and activity of docetaxel in anthracycline-pretreated breast cancer patients: a phase II study

: Docetaxel has proven effective in advanced breast cancer. Myelosuppression and cumulative fluid retention syndrome are troublesome, potentially avoidable toxicities. In this consecutive cohort study, docetaxel (100 mg/m2 by 1 hour i.v. infusion, q3 weeks) activity and toxicity was explored in 56 anthracycline-pretreated patients (eligible: 55: median age: 51 years [range: 28-68 years]; median performance status: 0 [range: 0-3]) with metastatic breast cancer, using two different granulocyte colony-stimulating factor and steroid pre- and postmedication schedules. Twenty-nine patients (group A) received a 5-day oral prednisone premedication, and 26 (group B) received 4-day low-dose i.m. dexamethasone; group B patients also received prophylactic granulocyte colony-stimulating factor. All patients were evaluable for toxicity and 53 for response. Prophylactic granulocyte colony-stimulating factor significantly lowered the incidence of grade III-IV neutropenia and neutropenic fever (p = 0.0001 and 0.01, respectively). The incidence of moderate-severe fluid retention syndrome was lower in patients receiving i.m. dexamethasone (p = 0.08). Overall response rate was 53% (4 complete responses/24 partial responses, 95% confidence interval 39.4-66.2%); 32% have stable disease and 15% progressive disease. In 21 anthracycline-refractory/resistant patients, as well as in 10 paclitaxel-pretreated patients, the overall response rate was 50%. Docetaxel is highly active in anthracycline- and paclitaxel-pretreated metastatic breast cancer, with manageable toxicity. Optimal use of both granulocyte colony-stimulating factor support and steroid premedication deserves further investigation

Physical modelling of piles under lateral loading in unsaturated soils

In this paper, selected aspects of an experimental study conducted in a geotechnical centrifuge are discussed. The tests aimed to explore the effects of partial saturation of soil on the response of a single pile subjected to a combination of lateral force and bending moment under drained conditions. The soil used in the experiments is a low plasticity silty soil, named B-grade kaolin, characterized by a relatively high permeability compared to the typical values for clayey soils. Two different elevations of the water table and its effects on the pile response under loading are studied. The data show a marked influence of soil partial saturation on the pile response, both under working loads and ultimate loads. In particular, under working loads, the displacement of the head of the pile is appreciably lower than that measured under saturated conditions