Is the Sun Lighter than the Earth? Isotopic CO in the Photosphere, Viewed through the Lens of 3D Spectrum Synthesis

We consider the formation of solar infrared (2-6 micron) rovibrational bands of carbon monoxide (CO) in CO5BOLD 3D convection models, with the aim to refine abundances of the heavy isotopes of carbon (13C) and oxygen (18O,17O), to compare with direct capture measurements of solar wind light ions by the Genesis Discovery Mission. We find that previous, mainly 1D, analyses were systematically biased toward lower isotopic ratios (e.g., R23= 12C/13C), suggesting an isotopically "heavy" Sun contrary to accepted fractionation processes thought to have operated in the primitive solar nebula. The new 3D ratios for 13C and 18O are: R23= 91.4 +/- 1.3 (Rsun= 89.2); and R68= 511 +/- 10 (Rsun= 499), where the uncertainties are 1 sigma and "optimistic." We also obtained R67= 2738 +/- 118 (Rsun= 2632), but we caution that the observed 12C17O features are extremely weak. The new solar ratios for the oxygen isotopes fall between the terrestrial values and those reported by Genesis (R68= 530, R6= 2798), although including both within 2 sigma error flags, and go in the direction favoring recent theories for the oxygen isotope composition of Ca-Al inclusions (CAI) in primitive meteorites. While not a major focus of this work, we derive an oxygen abundance of 603 +/- 9 ppm (relative to hydrogen; 8.78 on the logarithmic H= 12 scale). That the Sun likely is lighter than the Earth, isotopically speaking, removes the necessity to invoke exotic fractionation processes during the early construction of the inner solar system

Electric-Field Enhancement of Dielectronic Recombination from a Continuum of Finite Bandwidth

A small electric field is shown to increase the dielectronic recombination, via autoionizing Rydberg states, of an electron from a continuum of finite bandwidth. The continuum of finite bandwidth is a broad autoionizing state which is part of a series converging to a higher limit, and the field enhancement of the rate occurs because the field converts the nl Rydberg states to nk Stark states, increasing the number of contributing recombination paths. The experimental results are in excellent agreement with the predictions of an isolated resonance approximation treatment and show clearly both the positive effect of Stark mixing and the negative effect of field ionization on dielectronic recombination

Evaluation of Metabolic Stress between Jumping at Different Cadences on the Digi-Jump Machine

The American College of Sports Medicine (ACSM) recommends that healthy adults achieve a minimum of thirty minutes of moderate intensity aerobic exercise five days per week. While cycling, walking, and jogging are commonly observed methods of achieving these recommendations, another option may be repetitive jumping. The purpose of this study was to examine the metabolic responses between repetitive jumping at a cadence of 120 jumps per minute (JPMs) vs. 100 JPMs when utilizing the Digi-Jump machine. Twenty-eight subjects completed two jumping trials, one at 120 JPMs and one at 100 JPMs. Subjects jumped until volitional exhaustion, or for a maximum of fifteen minutes. Oxygen uptake (VO2), heart rate (HR), respiratory exchange ratio (RER), and rating of perceived exertion (RPE) were assessed each minute of each exercise trial. RPE was differentiated, in that subjects reported perceived exertion of their total body, their upper-leg, and their lower leg. Results of this study indicated that there was no significant difference between the two trials for VO2, HR, or total body RPE. Differences were reported between trials for peak and average RER, with the 120 JPM trial eliciting a lower RER for both (peak: 1.08 + .087 vs. 1.17 + .1 p=.000; average: .99 + .076 vs. 1.04 + .098 p=.002), peak upper leg RPE (120: 15.29 + 3.89 vs. 100: 16.75 + 2.52 p=.022), and average lower leg RPE (120: 15.04 + 2.55 vs. 100: 13.94 + 2.02 p=.019). Also, there was a significant difference in exercise duration between the trials, with subjects able to exercise longer during the 120 JPM trial (12.4 + 3.42 mins vs. 9.68 + 4.31 mins p=.000). These data indicate that while the physiological stress may not be different between the two trials as indicated by VO2 and HR, the 120 JPM trial appears less strenuous as evidenced by RER values and by subjects’ ability to exercise longer at that cadence

Method and Apparatus for Non-Destructive Evaluation of Materials

Methods and apparatus for characterizing composite materials for manufacturing quality assurance (QA), periodic inspection during the useful life, or for forensic analysis/material testing. System are provided that relate eddy-current sensor responses to the fiber layup of a composite structure, the presence of impact damage on a composite structure with or without a metal liner, volumetric stress within the composite, fiber tow density, and other NDE inspection requirements. Also provided are systems that determine electromagnetic material properties and material dimensions of composite materials from capacitive sensor inspection measurements. These properties are related to the presence of buried defects in non-conductive composite materials, moisture ingress, aging of the material due to service or environmental/thermal exposure, or changes in manufacturing quality

Concerted reductive coupling of an alkyl chloride at Pt(IV)

Oxidation of a doubly cyclometallated platinum(II) complex results in two isomeric platinum(IV) complexes. Whereas the trans isomer is robust, being manipulable in air at room temperature, the cis isomer decomposes at −20 °C and above. Reductive coupling of an alkyl chloride at the cis isomer gives a new species which can be reoxidised. The independence of this coupling on additional halide rules out the reverse of an SN2 reaction, leaving a concerted process as the only sensible reaction pathway

Method and Apparatus for Non-Destructive Evaluation of Materials

Methods and apparatus for characterizing composite materials for manufacturing quality assurance (QA), periodic inspection during the useful life, or for forensic analysis/material testing. System are provided that relate eddy-current sensor responses to the fiber layup of a composite structure, the presence of impact damage on a composite structure with or without a metal liner, volumetric stress within the composite, fiber tow density, and other NDE inspection requirements. Also provided are systems that determine electromagnetic material properties and material dimensions of composite materials from capacitive sensor inspection measurements. These properties are related to the presence of buried defects in non-conductive composite materials, moisture ingress, aging of the material due to service or environmental/thermal exposure, or changes in manufacturing quality