Non-LTE Abundances and Consequences for the Evolution of the alpha elements in the Galaxy

Abundances of alpha-elements such as Ca and Mg in disk and halo stars are usually derived from equivalent widths lines measured on high resolution spectra, and assuming Local Thermodynamic Equilibrium (LTE) . In this paper, we present non-LTE differential abundances derived by computing the statistical equilibrium of CaI and MgI atoms, using high resolution equivalent widths available in the literature for 252 dwarf to subgiant stars. These non-LTE abundances combined with recent determination of non-LTE abundances of iron, seem to remove the dispersion of the [Ca/Fe] and [Mg/Fe] ratios in the galactic halo and disk phases, revealing new and surprising structures. These results have important consequences for chemical evolution models of the Galaxy. In addition, non-LTE abundance ratios for stars belonging to the M92 cluster apparently have the same behavior. More high resolution observations, mainly of globular clusters, are urgently needed to confirm our results.Comment: 15 pages, 3 tables, 7 figure

VINCI / VLTI observations of Main Sequence stars

Main Sequence (MS) stars are by far the most numerous class in the Universe. They are often somewhat neglected as they are relatively quiet objects (but exceptions exist), though they bear testimony of the past and future of our Sun. An important characteristic of the MS stars, particularly the solar-type ones, is that they host the large majority of the known extrasolar planets. Moreover, at the bottom of the MS, the red M dwarfs pave the way to understanding the physics of brown dwarfs and giant planets. We have measured very precise angular diameters from recent VINCI/VLTI interferometric observations of a number of MS stars in the K band, with spectral types between A1V and M5.5V. They already cover a wide range of effective temperatures and radii. Combined with precise Hipparcos parallaxes, photometry, spectroscopy as well as the asteroseismic information available for some of these stars, the angular diameters put strong constraints on the detailed models of these stars, and therefore on the physical processes at play.Comment: 5 pages, 3 figures. To appear in the Proceedings of IAU Symposium 219, "Stars as Suns", Editors A. Benz & A. Dupree, Astronomical Society of the Pacifi

Stellar Iron Abundances: non-LTE Effects

We report new statistical equilibrium calculations for Fe I and Fe II in the atmosphere of Late-Type stars. We used atomic models for Fe I and Fe II having respectively 256 and 190 levels, as well as 2117 and 3443 radiative transitions. Photoionization cross-sections are from the Iron Project. These atomic models were used to investigate non-LTE effects in iron abundances of Late-Type stars with different atmospheric parameters. We found that most Fe I lines in metal-poor stars are formed in conditions far from LTE. We derived metallicity corrections of about 0.3 dex with respect to LTE values, for the case of stars with [Fe/H] ~ -3.0. Fe II is found not to be affected by significant non-LTE effects. The main non-LTE effect invoked in the case of Fe I is overionization by ultraviolet radiation, thus classical ionization equilibrium is far to be satisfied. An important consequence is that surface gravities derived by LTE analysis are in error and should be corrected before final abundances corrections. This apparently solves the observed discrepancy between spectroscopic surface gravities derived by LTE analyses and those derived from Hipparcos parallaxes. A table of non-LTE [Fe/H] and log g values for a sample of metal-poor late-type stars is given.Comment: 22 pages, 9 figures, 1 table, ApJ style, accepte

Polythiophenes and oligothiophenes in zeolite hosts

The polymerization of different thiophenes in the channels of molecular sieve zeolite hosts is described. Thiophene, 3-methyIthiophene, 2,2'-bithiophene, and terthiophene were introduced into dehydrated proton-, Cu(II)- or Fe(III)-containing zeolites (NaY and Na-mordenite) from organic solvents or vapor-phase. In the large-pore hosts, green-black products are formed from the monomers within several minutes. Spectroscopic characterization (IR, UV-NIR) confirms the formation of oxidized polymer chains in the zeolite channels. UV-Near IR reflectance spectra of the zeolite/polythiophene samples exhibit a broad absorption from 500 to about 2500 nm as the bulk and not the resolved spectra of short oligomers, thus fairly long polymer chains are formed in the zeolites. Conducting polymers can be recovered after dissolution of the zeolite host in HF. 2, 2'-bithiophene and a-terthiophene in acidic H2Y and U^Y zeolites (2 and 6 protons per super cage/ß-cage) yield yellow-green and purple products, respectively. UV-NIR reflectance data indicate that the acidic zeolite hosts oxidize the thiophene oligomers to yield stable radical cations and dications in their channel systems

s-Process Nucleosynthesis in Carbon Stars

We present the first detailed and homogeneous analysis of the s-element content in Galactic carbon stars of N-type. Abundances of Sr,Y, Zr (low-mass s-elements, or ls) and of Ba, La, Nd, Sm and Ce (high-mass s-elements, hs) are derived using the spectral synthesis technique from high-resolution spectra. The N-stars analyzed are of nearly solar metallicity and show moderate s-element enhancements, similar to those found in S stars, but smaller than those found in the only previous similar study (Utsumi 1985), and also smaller than those found in supergiant post-AGB stars. This is in agreement with the present understanding of the envelope s-element enrichment in giant stars, which is increasing along the spectral sequence M-->MS-->S-->SC-->C during the AGB phase. We compare the observational data with recent $s$-process nucleosynthesis models for different metallicities and stellar masses. Good agreement is obtained between low mass AGB star models (M < 3 M_o) and s-elements observations. In low mass AGB stars, the 13C(alpha, n)16O reaction is the main source of neutrons for the s-process; a moderate spread, however, must exist in the abundance of 13C that is burnt in different stars. By combining information deriving from the detection of Tc, the infrared colours and the theoretical relations between stellar mass, metallicity and the final C/O ratio, we conclude that most (or maybe all) of the N-stars studied in this work are intrinsic, thermally-pulsing AGB stars; their abundances are the consequence of the operation of third dredge-up and are not to be ascribed to mass transfer in binary systems.Comment: 31 pages, 10 figures, 6 tables. Accepted in Ap

Comparative Modelling of the Spectra of Cool Giants

Our ability to extract information from the spectra of stars depends on reliable models of stellar atmospheres and appropriate techniques for spectral synthesis. Various model codes and strategies for the analysis of stellar spectra are available today. We aim to compare the results of deriving stellar parameters using different atmosphere models and different analysis strategies. The focus is set on high-resolution spectroscopy of cool giant stars. Spectra representing four cool giant stars were made available to various groups and individuals working in the area of spectral synthesis, asking them to derive stellar parameters from the data provided. The results were discussed at a workshop in Vienna in 2010. Most of the major codes currently used in the astronomical community for analyses of stellar spectra were included in this experiment. We present the results from the different groups, as well as an additional experiment comparing the synthetic spectra produced by various codes for a given set of stellar parameters. Similarities and differences of the results are discussed. Several valid approaches to analyze a given spectrum of a star result in quite a wide range of solutions. The main causes for the differences in parameters derived by different groups seem to lie in the physical input data and in the details of the analysis method. This clearly shows how far from a definitive abundance analysis we still are.Comment: accepted for publication in A&A. This version includes also the online tables. Reference spectra will later be available via the CD

The Kr85 s-process Branching and the Mass of Carbon Stars

We present new spectroscopic observations for a sample of C(N)-type red giants. These objects belong to the class of Asymptotic Giant Branch stars, experiencing thermal instabilities in the He-burning shell (thermal pulses). Mixing episodes called third dredge-up enrich the photosphere with newly synthesized C12 in the He-rich zone, and this is the source of the high observed ratio between carbon and oxygen (C/O > 1 by number). Our spectroscopic abundance estimates confirm that, in agreement with the general understanding of the late evolutionary stages of low and intermediate mass stars, carbon enrichment is accompanied by the appearance of s-process elements in the photosphere. We discuss the details of the observations and of the derived abundances, focusing in particular on rubidium, a neutron-density sensitive element, and on the s-elements Sr, Y and Zr belonging to the first s-peak. The critical reaction branching at Kr85, which determines the relative enrichment of the studied species, is discussed. Subsequently, we compare our data with recent models for s-processing in Thermally Pulsing Asymptotic Giant Branch stars, at metallicities relevant for our sample. A remarkable agreement between model predictions and observations is found. Thanks to the different neutron density prevailing in low and intermediate mass stars, comparison with the models allows us to conclude that most C(N) stars are of low mass (M < 3Mo). We also analyze the C12/C13 ratios measured, showing that most of them cannot be explained by canonical stellar models. We discuss how this fact would require the operation of an ad hoc additional mixing, currently called Cool Bottom Process, operating only in low mass stars during the first ascent of the red giant branch and, perhaps, also during the asymptotic giant branch.Comment: 54 pages + 6 figures + 6 tables. ApJ accepte

Properties of the Volume Operator in Loop Quantum Gravity II: Detailed Presentation

The properties of the Volume operator in Loop Quantum Gravity, as constructed by Ashtekar and Lewandowski, are analyzed for the first time at generic vertices of valence greater than four. The present analysis benefits from the general simplified formula for matrix elements of the Volume operator derived in gr-qc/0405060, making it feasible to implement it on a computer as a matrix which is then diagonalized numerically. The resulting eigenvalues serve as a database to investigate the spectral properties of the volume operator. Analytical results on the spectrum at 4-valent vertices are included. This is a companion paper to arXiv:0706.0469, providing details of the analysis presented there.Comment: Companion to arXiv:0706.0469. Version as published in CQG in 2008. More compact presentation. Sign factor combinatorics now much better understood in context of oriented matroids, see arXiv:1003.2348, where also important remarks given regarding sigma configurations. Subsequent computations revealed some minor errors, which do not change qualitative results but modify some numbers presented her

Oxygen Abundances in Two Metal-Poor Subgiants from the Analysis of the 6300 A Forbidden O I Line

Recent LTE analyses (Israelian et al. 1998 and Bosegaard et al. 1999) of the OH bands in the optical-ultraviolet spectra of nearby metal-poor subdwarfs indicate that oxygen abundances are generally higher than those previously determined. The difference increases with decreasing metallicity and reaches delta([O/Fe]) ~ +0.6 dex as [Fe/H] approaches -3.0. Employing high resolution (R = 50000), high S/N (~ 250) echelle spectra of the two stars found by Israelian et al. (1998) to have the highest [O/Fe]-ratios, viz, BD +23 3130 and BD +37 1458, we conducted abundance analyses based on about 60 Fe I and 7-9 Fe II lines. We determined from Kurucz LTE models the values of the stellar parameters, as well as abundances of Na, Ni, and the traditional alpha-elements, independent of the calibration of color vs $T_{eff}$ scales. We determined oxygen abundances from spectral synthesis of the stronger line (6300 A) of the [O I] doublet. The syntheses of the [O I] line lead to smaller values of [O/Fe], consistent with those found earlier among halo field and globular cluster giants. We obtain [O/Fe] = +0.35 +/- 0.2 for BD +23 3130 and +0.50 +/- 0.2 for BD +37 1458. In the former, the [O I] line is very weak (~ 1 mA), so that the quoted [O/Fe] value may in reality be an upper limit. Therefore in these two stars a discrepancy exists between the [O/Fe]- ratios derived from [O I] and the OH feature, and the origin of this difference remains unclear. Until the matter is clarified, we suggest it is premature to conclude that the ab initio oxygen abundances of old, metal-poor stars need to be revised drastically upward.Comment: 38 pages, 5 tables, 14 figures To appear in July 1999 AJ Updated April 16, 1999. Fixed typo