206 research outputs found
A magnetic phase-transition graphene transistor with tunable spin polarization
Graphene nanoribbons (GNRs) have been proposed as potential building blocks
for field effect transistor (FET) devices due to their quantum confinement
bandgap. Here, we propose a novel GNR device concept, enabling the control of
both charge and spin signals, integrated within the simplest three-terminal
device configuration. In a conventional FET device, a gate electrode is
employed to tune the Fermi level of the system in and out of a static bandgap.
By contrast, in the switching mechanism proposed here, the applied gate voltage
can dynamically open and close an interaction gap, with only a minor shift of
the Fermi level. Furthermore, the strong interplay of the band structure and
edge spin configuration in zigzag ribbons enables such transistors to carry
spin polarized current without employing an external magnetic field or
ferromagnetic contacts. Using an experimentally validated theoretical model, we
show that such transistors can switch at low voltages and high speed, and the
spin polarization of the current can be tuned from 0% to 50% by using the same
back gate electrode. Furthermore, such devices are expected to be robust
against edge irregularities and can operate at room temperature. Controlling
both charge and spin signal within the simplest FET device configuration could
open up new routes in data processing with graphene based devices.Comment: 16 pages, 5 figures, accepted for publication in 2D Material
Screening and interlayer coupling in multilayer graphene field-effect transistors
With the motivation of improving the performance and reliability of
aggressively scaled nano-patterned graphene field-effect transistors, we
present the first systematic experimental study on charge and current
distribution in multilayer graphene field-effect transistors. We find a very
particular thickness dependence for Ion, Ioff, and the Ion/Ioff ratio, and
propose a resistor network model including screening and interlayer coupling to
explain the experimental findings. In particular, our model does not invoke
modification of the linear energy-band structure of graphene for the multilayer
case. Noise reduction in nano-scale few-layer graphene transistors is
experimentally demonstrated and can be understood within this model as well.Comment: 13 pages, 4 figures, 20 reference
Exfoliation of single layer BiTeI flakes
Spin orbit interaction is strongly enhanced in structures where a heavy element is embedded in an inversion asymmetric crystal field. A simple way for realizing such a setup is to take a single atomic layer of a heavy element and encapsulate it between two atomic layers of different elemental composition. BiTeI is a promising candidate for such a 2D crystal. In its bulk form BiTeI consists of loosely coupled three atom thick layers where a layer of high atomic number Bi are sandwiched between Te and I sheets. Despite considerable recent attention to bulk BiTeI due to its giant Rashba spin splitting, the isolation of a single layer remained elusive. In this work we report the first successful isolation and characterization of a single layer of BiTeI using a novel exfoliation technique on stripped gold. Our scanning probe studies and first principles calculations show that the fabricated 100 mu m sized BiTeI flakes are stable at ambient conditions. Giant Rashba splitting and spin-momentum locking of this new 2D crystal opens the way towards novel spintronic applications and synthetic topological heterostructures
Electronic transport through ordered and disordered graphene grain boundaries
The evolution of electronic wave packets (WPs) through grain boundaries (GBs) of various structures in graphene was investigated by the numerical solution of the time-dependent Schrödinger equation. WPs were injected from a simulated STM tip placed above one of the grains. Electronic structure of the GBs was calculated by ab-initio and tight-binding methods. Two main factors governing the energy dependence of the transport have been identified: the misorientation angle of the two adjacent graphene grains and the atomic structure of the GB. In case of an ordered GB made of a periodic repetition of pentagon-heptagon pairs, it was found that the transport at high and low energies is mainly determined by the misorientation angle, but the transport around the Fermi energy is correlated with the electronic structure of the GB. A particular line defect with zero misorientation angle Lahiri et al., behaves as a metallic nanowire and shows electron-hole asymmetry for hot electrons or holes. To generate disordered GBs, found experimentally in CVD graphene samples, a Monte-Carlo-like procedure has been developed. Results show a reduced transport for the disordered GBs, primarily attributed to electronic localized states caused by C atoms with only two covalent bonds. © 2013 Elsevier Ltd. All rights reserved
From One Electron to One Hole: Quasiparticle Counting in Graphene Quantum Dots Determined by Electrochemical and Plasma Etching
Graphene is considered to be a promising material for future electronics. The
envisaged transistor applications often rely on precision cutting of graphene
sheets with nanometer accuracy. In this letter we demonstrate graphene-based
quantum dots created by using atomic force microscopy (AFM) with tip-assisted
electrochemical etching. This lithography technique provides resolution of
about 20 nm, which can probably be further improved by employing sharper tips
and better humidity control. The behavior of our smallest dots in magnetic
field has allowed us to identify the charge neutrality point and distinguish
the states with one electron, no charge and one hole left inside the quantum
dot
Facile Synthesis of High Quality Graphene Nanoribbons
Graphene nanoribbons have attracted attention for their novel electronic and
spin transport properties1-6, and because nanoribbons less than 10 nm wide have
a band gap that can be used to make field effect transistors. However,
producing nanoribbons of very high quality, or in high volumes, remains a
challenge. Here, we show that pristine few-layer nanoribbons can be produced by
unzipping mildly gas-phase oxidized multiwalled carbon nanotube using
mechanical sonication in an organic solvent. The nanoribbons exhibit very high
quality, with smooth edges (as seen by high-resolution transmission electron
microscopy), low ratios of disorder to graphitic Raman bands, and the highest
electrical conductance and mobility reported to date (up to 5e2/h and 1500
cm2/Vs for ribbons 10-20 nm in width). Further, at low temperature, the
nanoribbons exhibit phase coherent transport and Fabry-Perot interference,
suggesting minimal defects and edge roughness. The yield of nanoribbons was ~2%
of the starting raw nanotube soot material, which was significantly higher than
previous methods capable of producing high quality narrow nanoribbons1. The
relatively high yield synthesis of pristine graphene nanoribbons will make
these materials easily accessible for a wide range of fundamental and practical
applications.Comment: Nature Nanotechnology in pres
Direct Imaging of Graphene Edges: Atomic Structure and Electronic Scattering
We report an atomically-resolved scanning tunneling microscopy (STM)
investigation of the edges of graphene grains synthesized on Cu foils by
chemical vapor deposition (CVD). Most of the edges are macroscopically parallel
to the zigzag directions of graphene lattice. These edges have microscopic
roughness that is found to also follow zigzag directions at atomic scale,
displaying many ~120 degree turns. A prominent standing wave pattern with
periodicity ~3a/4 (a being the graphene lattice constant) is observed near a
rare-occurring armchair-oriented edge. Observed features of this wave pattern
are consistent with the electronic intervalley backscattering predicted to
occur at armchair edges but not at zigzag edges
Rotation Symmetry Spontaneous Breaking of Edge States in Zigzag Carbon Nanotubes
Analytical solutions of the edge states were obtained for the (N, 0) type
carbon nanotubes with distorted ending bonds. It was found that the edge states
are mixed via the distortion. The total energies for N=5 and N>=7 are lower in
the asymmetric configurations of ending bonds than those having axial rotation
symmetry. Thereby the symmetry is breaking spontaneously. The results imply
that the symmetry of electronic states at the apex depends on the occupation;
the electron density pattern at the apex could change dramatically and could be
controlled by applying an external field.Comment: 19 pages, 3 figure
Fast route to obtain Al2O3-based nanocomposites employing graphene oxide: Synthesis and Sintering
A fast approach based on microwave technology was employed for the sintering of novel composites of alumina and using graphene oxide (GO) as susceptor. The thermal stability and structure of GO materials produced by chemical oxidation of graphite were characterized. The morphology, structure and mechanical properties of the composites sintered by microwave approach were reported to the counterparts sintered by conventional method. The results indicated the formation of an interconnecting graphene network promoted the electrical conductivity in the composite having only 2 wt.% GO. Hardness and elastic modulus decreased significantly in samples sintered by conventional method due to lower values of density while microwave technology allowed to achieve a positive effect on the densification and showed a smaller grain size when compared to the one achieved by conventional heating. (C) 2014 Elsevier Ltd. All rights reserved.Financial support from European Commission (project no. NMP3-SL-2010-246073), Universidad Politecnica de Valencia (project SP20120677) and Ministerio de Economia y Competitividad - MINECO (project TEC2012-37532-C02-01, co-funded by ERDF (European Regional Development Funds) is gratefully acknowledged. A.B. acknowledges the Spanish Ministry of Science and Innovation (contract JCI-2011-10498). A.P. acknowledges support from Romanian Authority for Scientific Research - UEFISCDI (project no. PN-II-RU-PD-2012-3-0124).Benavente MartÃnez, R.; Pruna, AI.; Borrell Tomás, MA.; Salvador Moya, MD.; Pullini, D.; Penaranda-Foix, FL.; Busquets Mataix, DJ. (2015). Fast route to obtain Al2O3-based nanocomposites employing graphene oxide: Synthesis and Sintering. Materials Research Bulletin. 64:245-251. https://doi.org/10.1016/j.materresbull.2014.12.075S2452516
Snap-through instability of graphene on substrates
We determine the graphene morphology regulated by substrates with herringbone
and checkerboard surface corrugations. As the graphene/substrate interfacial
bonding energy and the substrate surface roughness vary, the graphene
morphology snaps between two distinct states: 1) closely conforming to the
substrate and 2) remaining nearly flat on the substrate. Such a snapthrough
instability of graphene can potentially lead to desirable electronic properties
to enable graphene-based devices.Comment: 13 pages, 4 figures; Nanoscale Research Letters, in press, 200
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