Out-of-plane auxeticity in sintered fibre network mats

Fibre network mats composed of stainless steel exhibit an unusually large out-of-plane auxeticity (i.e. high negative Poisson’s ratio ν) when subjected to in-plane tensile loading. In situ observations in a scanning electron microscope suggest that this is attributable to fibre segment straightening. An investigation was carried out on the effects of fibre volume fraction and network thickness on the auxetic response. Weak inter-layer bonding, high fibre content and low network thickness were found to amplify the auxetic effect.This research was supported by the European Research Council (ERC) (Grant No. 240446). We wish to thank Dr. Kalin Dragnevski at The Laboratory for In situ Microscopy and Analysis (LIMA) in the Department of Engineering Science, Oxford University for the help in setting up the in situ DEBEN experiments.This is the accepted manuscript of a paper published in Scripta Materialia (Neelakantan S, Tan J-C, Markaki AE, Scripta Materialia, 2015, doi:10.1016/j.scriptamat.2015.04.028). The final version is available at http://dx.doi.org/10.1016/j.scriptamat.2015.04.02

Kiloparsec-Scale Simulations of star formations in disk galaxies. III. Structure and dynamics of filaments and clumps in giant molecular clouds

We present hydrodynamic simulations of self-gravitating dense gas in a galactic disk, exploring scales ranging from 1 kpc down to ~0.1 pc. Our primary goal is to understand how dense filaments form in giant molecular clouds (GMCs). These structures, often observed as infrared dark clouds (IRDCs) in the Galactic plane, are thought to be the precursors to massive stars and star clusters, so their formation may be the rate-limiting step controlling global star formation rates in galactic systems as described by the Kennicutt–Schmidt relation. Our study follows on from Van Loo et al., which carried out simulations to 0.5 pc resolution and examined global aspects of the formation of dense gas clumps and the resulting star formation rate. Here, using our higher resolution, we examine the detailed structural, kinematic, and dynamical properties of dense filaments and clumps, including mass surface density (Σ) probability distribution functions, filament mass per unit length and its dispersion, lateral Σ profiles, filament fragmentation, filament velocity gradients and infall, and degree of filament and clump virialization. Where possible, these properties are compared to observations of IRDCs. By many metrics, especially too large mass fractions of high ${\Sigma }\gt 1\;{\rm g}\;{\rm c}{{{\rm m}}^{-2}}$ material, too high mass per unit length dispersion due to dense clump formation, too high velocity gradients, and too high velocity dispersion for a given mass per unit length, the simulated filaments differ from observed IRDCs. We thus conclude that IRDCs do not form from global fast collapse of GMCs. Rather, we expect that IRDC formation and collapse are slowed significantly by the influence of dynamically important magnetic fields, which may thus play a crucial role in regulating galactic star formation rates

Mechanical properties of zeolitic metal-organic frameworks: Mechanically flexible topologies and stabilization against structural collapse

We report the low elastic modulus of a zeolitic MOF, along with stabilization against structural collapse by filling with solvent.This is the author-accepted manuscript. It is under embargo for 12 months after publication. The final version of this article is published by RSC in CrystEngComm and can be found here: http://dx.doi.org/10.1039/c4ce02145

GMC Collisions as Triggers of Star Formation. I. Parameter Space Exploration with 2D Simulations

We utilize magnetohydrodynamic (MHD) simulations to develop a numerical model for GMC-GMC collisions between nearly magnetically critical clouds. The goal is to determine if, and under what circumstances, cloud collisions can cause pre-existing magnetically subcritical clumps to become supercritical and undergo gravitational collapse. We first develop and implement new photodissociation region (PDR) based heating and cooling functions that span the atomic to molecular transition, creating a multiphase ISM and allowing modeling of non-equilibrium temperature structures. Then in 2D and with ideal MHD, we explore a wide parameter space of magnetic field strength, magnetic field geometry, collision velocity, and impact parameter, and compare isolated versus colliding clouds. We find factors of ~2-3 increase in mean clump density from typical collisions, with strong dependence on collision velocity and magnetic field strength, but ultimately limited by flux-freezing in 2D geometries. For geometries enabling flow along magnetic field lines, greater degrees of collapse are seen. We discuss observational diagnostics of cloud collisions, focussing on 13CO(J=2-1), 13CO(J=3-2), and 12CO(J=8-7) integrated intensity maps and spectra, which we synthesize from our simulation outputs. We find the ratio of J=8-7 to lower-J emission is a powerful diagnostic probe of GMC collisions

The mechanical and electrical properties of direct-spun carbon nanotube mat-epoxy composites

Composites of direct-spun carbon nanotube (CNT) mats and epoxy are manufactured and tested in order to determine their mechanical and electrical properties. The mats are spun directly from a floating catalyst, chemical vapour deposition reactor. The volume fraction of epoxy is varied widely by suitable dilution of the epoxy resin with acetone. Subsequent evaporation of the acetone, followed by a cure cycle, leads to composites of varying volume fraction of CNT, epoxy and air. The modulus, strength, electrical conductivity and piezoresistivity of the composites are measured. The CNT mats and their composites exhibit an elastic-plastic stress-strain response under uniaxial tensile loading, and the degree of anisotropy is assessed by testing specimens in 0{\deg}, 45{\deg} and 90{\deg} directions with respect to the draw direction of mat manufacture. The electrical conductivity scales linearly with CNT volume fraction, irrespective of epoxy volume fraction. In contrast, the modulus and strength depend upon both CNT and epoxy volume fractions in a non-linear manner. The macroscopic moduli of the CNT mat-epoxy composites are far below the Voigt bound based on the modulus of CNT walls and epoxy. A micromechanical model is proposed to relate the macroscopic modulus and yield strength of a CNT mat-epoxy composite to the microstructure

Kiloparsec-scale Simulations of Star Formation in Disk Galaxies. IV. Regulation of Galactic Star Formation Rates by Stellar Feedback

Star formation from the interstellar medium of galactic disks is a basic process controlling the evolution of galaxies. Understanding the star formation rate in a local patch of a disk with a given gas mass is thus an important challenge for theoretical models. Here we simulate a kiloparsec region of a disk, following the evolution of self-gravitating molecular clouds down to subparsec scales, as they form stars that then inject feedback energy by dissociating and ionizing UV photons and supernova explosions. We assess the relative importance of each feedback mechanism. We find that H2-dissociating feedback results in the largest absolute reduction in star formation compared to the run with no feedback. Subsequently adding photoionization feedback produces a more modest reduction. Our fiducial models that combine all three feedback mechanisms yield, without fine-tuning, star formation rates that are in excellent agreement with observations, with H2-dissociating photons playing a crucial role. Models that only include supernova feedback—a common method in galaxy evolution simulations—settle to similar star formation rates, but with very different temperature and chemical states of the gas, and with very different spatial distributions of young stars

The mechanical and electrical properties of direct-spun carbon nanotube mats

The mechanical and electrical properties of a direct-spun carbon nanotube mat are measured. The mat comprises an interlinked random network of nanotube bundles, with approximately 40 nanotubes in a bundle. A small degree of in-plane anisotropy is observed. The bundles occasionally branch, and the mesh topology resembles a 2D lattice of nodal connectivity slightly below 4. The macroscopic in-plane tensile response is elasto-plastic in nature, with significant orientation hardening. In-situ microscopy reveals that the nanotube bundles do not slide past each other at their junctions under macroscopic stain. A micromechanical model is developed to relate the macroscopic modulus and flow strength to the longitudinal shear response of the nanotube bundles. The mechanical and electrical properties of the mat are compared with those of other nanotube arrangements over a wide range of density

Identifying Improved Sites for Heterologous Gene Integration Using ATAC-seq

Constructing efficient cellular factories often requires integration of heterologous pathways for synthesis of novel compounds and improved cellular productivity. Few genomic sites are routinely used, however, for efficient integration and expression of heterologous genes, especially in nonmodel hosts. Here, a data-guided framework for informing suitable integration sites for heterologous genes based on ATAC-seq was developed in the nonmodel yeast Komagataella phaffii. Single-copy GFP constructs were integrated using CRISPR/Cas9 into 38 intergenic regions (IGRs) to evaluate the effects of IGR size, intensity of ATAC-seq peaks, and orientation and expression of adjacent genes. Only the intensity of accessibility peaks was observed to have a significant effect, with higher expression observed from IGRs with low- to moderate-intensity peaks than from high-intensity peaks. This effect diminished for tandem, multicopy integrations, suggesting that the additional copies of exogenous sequence buffered the transcriptional unit of the transgene against effects from endogenous sequence context. The approach developed from these results should provide a basis for nominating suitable IGRs in other eukaryotic hosts from an annotated genome and ATAC-seq data