Hierarchical nanophase-separated structures created by precisely-designed polymers with complexity

AbstractThis review paper summarizes recent advances in self-assembly of complex polymers, focusing on three characteristic polymeric systems. The first is star-branched polymers of the ABC type, the second one consists of multiblock terpolymers with different chain lengths, while the third comprises supramacromolecular assembly systems with hydrogen and ionic bonding interactions between different polymer species. A quasicrystalline tiling structure with mesoscopic length scale has been found for the first star polymer system as well as the periodic Archimedean tiling structures, and moreover three-dimensional Zincblende network structure has been discovered. Furthermore the hierarchical structures having two length scales have been also found for the ABC star molecules whose chain length ratios, that is, A/B and/or A/C are larger than approximately five. Hierarchical structures with double periodicity have been observed for the hexablock and undecablock terpolymers and it has been revealed that their morphology changes systematically depending on composition of polymeric species. Poly(4-hydroxystyrene) (H) homopolymer was found to be dissolved into microdomain of poly(2-vinylpyridine) formed by poly(styrene-b-2-vinylpyridine) due to hydrogen bonding interaction, resulting in the origin of morphological transitions depending on the composition of H homopolymer added. Hierarchical structures possessing double periodicity have been found for poly(isoprene-b-2-vinylpyridine)/poly(styrene-b-4-hydroxystyrene) blends depending on both volume fractions of component polymers and blend ratio. Blends of different homopolymers with several complementary nucleotides or acid/base moieties on chain ends have been confirmed to show nanophase-separated structures as a result of successful formation of “supramacromolecules”

Buckling Experiment on Anisotropic Long and Short Cylinders

A buckling experiment was performed on anisotropic, long and short cylinders with various radius-to-thickness ratios. The 13 cylinders had symmetric and anti-symmetric layups, were between 2 and 6 in terms of the length-to-radius ratio, between 154 and 647 in radius-to-thickness ratio, and made of two kinds of carbon fiber reinforced plastic (CFRP) prepreg with high or low fiber modulus. The theoretical buckling loads for the cylinders were calculated from the previously published solution by using linear bifurcation theory considering layup anisotropy and transverse shear deformation and by using deep shell theory to account for the effect of length and compared with the test results. The theoretical buckling loads for the cylinders were calculated from the previously published solution by using linear bifurcation theory considering layup anisotropy and transverse shear deformation and by using deep shell theory to account for the effect of length. The knockdown factor, defined as the ratio of the experimental value to the theoretical value, was found to be between 0.451 and 0.877. The test results indicated that a large length-to-radius ratio reduces the knockdown factor, but the radius-to-thickness ratio and other factors do not affect it

Wood in sustainable construction - a material perspective: Learning from vernacular architecture

Traditionally, vernacular buildings were constructed based upon a deep understanding of the surroundings and the features of locally sourced materials. This wisdom led to a rational building composition and appropriate material selection, which ensured adequate living conditions and proper building life cycle, without any advanced technologies. In the discussion about reducing the environmental impacts of a building, there should be useful ideas to be taken from traditional solutions for the further development of modern buildings. A life cycle perspective is nowadays becoming more significant for comprehensive building analysis as the distribution of the environmental impacts over a building life cycle change. In such a context, building material selection is an important factor. Wood products have lately attracted attention as promising construction materials due to their unique environmental properties. This study investigated the optimal use and development of wood products in sustainable construction in comparison to other building materials, based on life cycle assessment method. With regard to learning from vernacular buildings, a holistic analysis of wood in construction was carried out. In this dissertation, first the methodological issues relating to the fair assessment of wood products and wood construction based on the current normative standards and assessment data were discussed. Secondly, wood in sustainable construction was discussed according to ten principles in terms of appropriate building material selection over the building life cycle. This study demonstrated that there are both strengths and weakness to the use of wood in sustainable construction. In this sense, the importance of diverse perspectives to building materials has been highlighted. It was also discussed that wood may contribute to the environment more positively when it is used more. A reduction in consumption (e.g. energy) and emissions (e.g. CO2) has thus far been the principle behind mitigating environmental impacts. In this context, for instance, a CLT (Cross laminated timber) framed building would not be preferable since it requires a large amount of wood, resulting in high embodied energy. However, on the other hand, that gives significant environmental benefits (e.g. energy recovery) to the building. In this case, by optimising the weaknesses (high embodied energy) and maximising the strengths (environmental benefits), the greater use of wood may improve the environmental profile of a building. This would be a paradigm shift from the current approach to the environmental problems. In that sense, wood seems to have significant potential. It would be important to consider a specific approach and use for wood in construction based upon the proper understanding of their characteristics as practiced in traditional buildings

Radial and vertical distributions of radiocesium in tree stems of Pinus densiflora and Quercus serrata 1.5 y after the Fukushima nuclear disaster.

The radial and vertical distributions of radiocesium in tree stems were investigated to understand radiocesium transfer to trees at an early stage of massive contamination from the Fukushima nuclear disaster. A conifer species (Japanese red pine) and a broad-leaved species (Japanese konara oak) were selected to determine whether the radiocesium contamination pattern differs between species. Stem disks were collected at several heights and separated into outer bark, inner bark, and wood. The radiocesium concentration was the highest in the outer bark, followed by that in the inner bark and wood. The vertical distribution of the radiocesium concentration at each stem part differed between the species. The difference between species in radiocesium concentration of the outer bark could be explained by presence or absence of leaves at the time of the disaster. However, the reasons for the differences between species in the radiocesium concentration of the inner bark and wood are unclear. The radial distribution in the wood of the studied species showed a common pattern across stem disk heights and species. However, the radiocesium concentration ratio between sapwood and inner bark was significantly different between species. Although the radial contamination pattern in the wood was similar in the studied species during the early stage of contamination, the radiocesium transport pathway and allocation would be different between the species, and the contamination pattern will likely be different between the species at later stages. Continued investigations are important for understanding the radiocesium cycle and the accumulation of radiocesium in the tree stems of each species

Frequency ratios of Sr, Yb and Hg based optical lattice clocks and their applications

This article describes the recent progress of optical lattice clocks with neutral strontium ($^{87}$Sr), ytterbium ($^{171}$Yb) and mercury ($^{199}$Hg) atoms. In particular, we present frequency comparison between the clocks locally via an optical frequency comb and between two Sr clocks at remote sites using a phase-stabilized fibre link. We first review cryogenic Sr optical lattice clocks that reduce the room-temperature blackbody radiation shift by two orders of magnitude and serve as a reference in the following clock comparisons. Similar physical properties of Sr and Yb atoms, such as transition wavelengths and vapour pressure, have allowed our development of a compatible clock for both species. A cryogenic Yb clock is evaluated by referencing a Sr clock. We also report on a Hg clock, which shows one order of magnitude less sensitivity to blackbody radiation, while its large nuclear charge makes the clock sensitive to the variation of fine-structure constant. Connecting all three types of clocks by an optical frequency comb, the ratios of the clock frequencies are determined with uncertainties smaller than possible through absolute frequency measurements. Finally, we describe a synchronous frequency comparison between two Sr-based remote clocks over a distance of 15 km between RIKEN and the University of Tokyo, as a step towards relativistic geodesy.Comment: 11 pages, 5 figures, invited review article in Comptes Rendus de Physique 201

Soft X-ray Absorption and Photoemission Studies of Ferromagnetic Mn-Implanted 3CC-SiC

We have performed x-ray photoemission spectroscopy (XPS), x-ray absorption spectroscopy (XAS), and resonant photoemission spectroscopy (RPES) measurements of Mn-implanted 3$C$-SiC (3$C$-SiC:Mn) and carbon-incorporated Mn$_{5}$Si$_{2}$ (Mn$_{5}$Si$_{2}$:C). The Mn 2$p$ core-level XPS and XAS spectra of 3$C$-SiC:Mn and Mn$_{5}$Si$_{2}$:C were similar to each other and showed "intermediate" behaviors between the localized and itinerant Mn 3$d$ states. The intensity at the Fermi level was found to be suppressed in 3$C$-SiC:Mn compared with Mn$_{5}$Si$_{2}$:C. These observations are consistent with the formation of Mn$_{5}$Si$_{2}$:C clusters in the 3$C$-SiC host, as observed in a recent transmission electron microscopy study.Comment: 4 pages, 3 figure

Marked motor function improvement in a 32-year-old woman with childhood-onset hypophosphatasia by asfotase alfa therapy: Evaluation based on standardized testing batteries used in Duchenne muscular dystrophy clinical trials

Hypophosphatasia (HPP) is a rare disorder resulting from biallelic loss-of-function variants or monoallelic dominant negative variants in the ALPL gene. We herein describe the clinical outcome of a 32-year-old woman with childhood-onset HPP caused by compound heterozygous variants in ALPL. Her chief complaints were severe musculoskeletal pain, muscle weakness, and impaired daily activities necessitating assistance in housework and child-rearing in addition to a history of early tooth loss and mildly short stature. Asfotase alfa therapy produced a remarkable increase in muscle strength and daily activities and markedly reduced musculoskeletal pain. Drug efficacy was clearly demonstrated through multiple test batteries (muscle strength test using microFET®2, six-minute walking test, Stair Climb Test, rising-from-floor-time test, and number-of-steps test using Actigraph®) currently adopted as standardized evaluations in Duchenne muscular dystrophy clinical trials since no test batteries for HPP have been established to date. These tests may also be promising for the assessment of HPP