1,852 research outputs found
Electromagnetic Polarizabilities of Nucleons bound in Ca, O and He
Differential cross sections for elastic scattering of photons have been
measured for Ca at energies of 58 and 74 MeV and for O and He
at 61 MeV, in the angular range from 45 to 150. Evidence is obtained
that there are no significant in-medium modifications of the electromagnetic
polarizabilities except for those originating from meson exchange currents.Comment: 20 pages including 5 Figure
Strong-Coupling Expansion for the Hubbard Model
A strong-coupling expansion for models of correlated electrons in any
dimension is presented. The method is applied to the Hubbard model in
dimensions and compared with numerical results in . Third order expansion
of the Green function suffices to exhibit both the Mott metal-insulator
transition and a low-temperature regime where antiferromagnetic correlations
are strong. It is predicted that some of the weak photoemission signals
observed in one-dimensional systems such as should become stronger as
temperature increases away from the spin-charge separated state.Comment: 4 pages, RevTex, 3 epsf figures include
Instantaneous Spin Correlations in La2CuO4
We have carried out a neutron scattering study of the instantaneous spin-spin
correlations in La2CuO4 (T_N = 325 K) over the temperature range 337 K to 824
K. Incident neutron energies varying from 14.7 meV to 115 meV have been
employed in order to guarantee that the energy integration is carried out
properly. The results so-obtained for the spin correlation length as a function
of temperature when expressed in reduced units agree quantitatively both with
previous results for the two dimensional (2D) tetragonal material Sr2CuO2Cl2
and with quantum Monte Carlo results for the nearest neighbor square lattice
S=1/2 Heisenberg model. All of the experimental and numerical results for the
correlation length are well described without any adjustable parameters by the
behavior predicted for the quantum non-linear sigma model in the low
temperature renormalized classical regime. The amplitude, on the other hand,
deviates subtly from the predicted low temperature behavior. These results are
discussed in the context of recent theory for the 2D quantum Heisenberg model.Comment: 9 pages, LaTeX, includes 8 figure
Dual Nature of the Electronic Structure of the Stripe Phase
High resolution angle-resolved photoemission measurements have been carried
out on (La_1.4-xNd_0.6Sr_x)CuO_4, a model system with static stripes, and
(La_1.85Sr_0.15)CuO_4, a high temperature superconductor (T_c=40K) with dynamic
stripes. In addition to the straight segments near (pi, 0) and (0, pi)
antinodal regions, we have identified the existence of nodal spectral weight
and its associated Fermi surface in the electronic structure of both systems.
The ARPES spectra in the nodal region show well-defined Fermi cut-off,
indicating a metallic character of this charge-ordered state. This observation
of nodal spectral weight, together with the straight segments near antinodal
regions, reveals dual nature of the electronic structure of the stripes due to
the competition of order and disorder
One particle spectral weight of the three dimensional single band Hubbard model
Dynamic properties of the three-dimensional single-band Hubbard model are
studied using Quantum Monte Carlo combined with the maximum entropy technique.
At half-filling, there is a clear gap in the density of states and well-defined
quasiparticle peaks at the top (bottom) of the lower (upper) Hubbard band. We
find an antiferromagnetically induced weight above the naive Fermi momentum.
Upon hole doping, the chemical potential moves to the top of the lower band
where a robust peak is observed. Results are compared with spin-density-wave
(SDW) mean-field and self consistent Born approximation results, and also with
the infinite dimensional Hubbard model, and experimental photoemission (PES)
for three dimensional transition-metal oxides.Comment: 11 pages, REVTeX, 16 figures included using psfig.sty. Ref.30
correcte
The Discovery Potential of a Super B Factory
The Proceedings of the 2003 SLAC Workshops on flavor physics with a high
luminosity asymmetric e+e- collider. The sensitivity of flavor physics to
physics beyond the Standard Model is addressed in detail, in the context of the
improvement of experimental measurements and theoretical calculations.Comment: 476 pages. Printed copies may be obtained by request to
[email protected] . arXiv admin note: v2 appears to be identical to v
Graz. Schloßberg.
Blick zum Schloßberg mit Hauptbrück
Transport of Pb and Zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100°C: the influence of pH and oxygen fugacity
It is well established through field observations, experiments, and chemical models that oxidation (redox) state and pH exert a strong influence on the speciation of dissolved components and the solubility of minerals in hydrothermal fluids. log [Image: see text] –pH diagrams were used to depict the influence of oxygen fugacity and pH on monocarboxylate- and dicarboxylate-transport of Pb and Zn in low-temperature (100°C) hydrothermal ore fluids that are related to diagenetic processes in deep sedimentary basins, and allow a first-order comparison of Pb and Zn transport among proposed model fluids for Mississippi Valley-type (MVT) and red-bed related base metal (RBRBM) deposits in terms of their approximate pH and [Image: see text] conditions. To construct these diagrams, total Pb and Zn concentrations and Pb and Zn speciation were calculated as a function of log [Image: see text] and pH for a composite ore-brine with concentrations of major elements, total sulfur, and total carbonate that approximate the composition of MVT and RBRBM model ore fluids and modern basinal brines. In addition to acetate and malonate complexation, complexes involving the ligands Cl(-), HS(-), H(2)S, and OH(- )were included in the model of calculated total metal concentration and metal speciation. Also, in the model, Zn and Pb are competing with the common-rock forming metals Ca, Mg, Na, Fe, and Al for the same ligands. Calculated total Pb concentration and calculated total Zn concentration are constrained by galena and sphalerite solubility, respectively. Isopleths, in log [Image: see text] –pH space, of the concentration of Pb and concentration of Zn in carboxylate (acetate + malonate) complexes illustrate that the oxidized model fluids of T. H. Giordano (in Organic Acids in Geological Processes, ed. E. D. Pittman and M. D. Lewan, Springer-Verlag, New York, 1994, pp. 319–354) and G. M. Anderson (Econ. Geol., 1975, 70, 937–942) are capable of transporting sufficient amounts of Pb (up to 10 ppm) and Zn (up to 100 ppm) in the form of carboxylate complexes to form economic deposits of these metals. On the other hand, the reduced ore fluid models of D. A. Sverjensky (Econ. Geol., 1984, 79, 23–37) and T. H. Giordano and H. L. Barnes (Econ. Geol., 1981, 76, 2200–2211) can at best transport amounts of Pb and Zn, as carboxylate complexes, that are many orders of magnitude below the 1 to 10 ppm minimum required to form economic deposits. Lead and zinc speciation (mol% of total Pb or Zn) in the model ore fluid was calculated at specific log [Image: see text] –pH conditions along the 100, 0.01, and 0.001 ppm total Pb and total Zn isopleths. Along the 100 ppm isopleth conditions are oxidized (∑SO(4 )>> ∑H(2)S) with Pb and Zn predominantly in the form of chloride complexes under acid to mildly alkaline conditions (pH from 3 to approximately 7.5), while hydroxide complexes dominate Pb and Zn speciation under more alkaline conditions. Sulfide complexes are insignificant under these oxidized conditions. For more reduced conditions along the 0.01 and 0.001 ppm isopleths chloride complexes dominate Pb and Zn speciation in the SO(4)(2- )field and near the SO(4)(2-)-reduced sulfur boundary from pH = 4 to approximately 7.5, while hydroxide complexes dominate Pb and Zn speciation under alkaline conditions above pH = 7.5 in the SO(4)(2- )field. In the most reduced fluids (∑H(2)S >> ∑SO(4)) along the 0.01 and 0.001 isopleths, sulfide complexes account for almost 100% of the Pb and Zn in the model fluid. Acetate (monocarboxylate) complexation is significant only under conditions of chloride and hydroxide complex dominance and its effect is maximized in the pH range 5 to 7, where it complexes 2 to 2.6% of the total Pb and 1 to 1.25% of the total Zn. Malonate (dicarboxylate) complexes are insignificant along all isopleths. The speciation results from this study show that deep formation waters characterized by temperatures near 100°C, high oxidation states and ∑H(2)S < 0.03 mg L(-1 )([Image: see text] < 10(-6)), high chlorinities (~ 100000 mg L(-1)), and high but reasonable concentrations of carboxylate anions can mobilize up to 3% of the total Pb and up to 1.3% of the total Zn as carboxylate complexes. Furthermore, these percentages, under the most favorable conditions, correspond to approximately 1 to 100 ppm of these metals in solution; concentrations that are adequate to form economic deposits of these metals. However, the field evidence suggests that all of these optimum conditions for carboxylate complexation are rarely met at the same time. A comparison of the composite ore fluid compositions from this study and modern brine data shows that the ore brines, corresponding to log [Image: see text] –pH conditions based on the Anderson (1975) and Giordano (1994) model fluids, are similar in many respects to modern, high trace-metal petroleum-field brines. The principal differences between modern high trace-metal brines and the composite ore fluids of Anderson (1975) and Giordano (1994) relate to their carboxylate anion content. The reported concentrations of monocarboxylate anions (∑monocbx) and dicarboxylate anions (Edicbx) in high trace-metal petroleum-field brines (< 1 to 300 mg L(-1 )and < 1 mg L(-1), respectively) are significantly lower than the concentrations assumed in the modelled brines of this study (∑monocbx = 7 700 mg L(-1 )and ∑dicbx = 300 mg L(-1)). There are also major differences in the corresponding total chloride to carboxylate ratio (∑m(Cl)/∑m(cbx)) and monocarboxylate to dicarboxylate ratio (∑m(monocbx)/∑m(dicbx)). Modern high trace-metal brines have much higher ∑m(Cl)/∑m(cbx )values and, therefore, the contribution of carboxylate complexes to the total Pb and Zn content in these modern brines is likely to be significantly less than the 1 to 3 percent for the composite ore fluids of Anderson (1975) and Giordano (1994). The composite ore-brine based on the Giordano and Barnes (1981) MVT ore fluid is comparable to the high salinity (> 170 000 mg L(-1 )TDS) subset of modern brines characterized by low trace-metal content and high total reduced sulfur (∑H(2)S). A comparison of the Sverjensky (1984) composite ore-brine with modern petroleum-field brines in terms of ∑H(2)S and Zn content, reveals that this ore fluid corresponds to a "border-type" brine, between modern high trace-metal brines and those with low trace-metal content and high ∑H(2)S. A brine of this type is characterized by values of ∑H(2)S, ∑Zn, and/or ∑Pb within or near the 1 to 10 mg L(-1 )range. Based on brine-composition data from numerous references cited in this paper, border-type brines do exist but are rare. The model results and field evidence presented in this study are consistent with other chemical simulation studies of carboxylate complexation in modern petroleum-field brines. Thus, it appears that carboxylate complexation plays a minor, if not insignificant, role as a transport mechanism for Pb and Zn in high salinity Na–Cl and Na–Ca–Cl basinal brines and related ore fluids
The Main Belt Comets and ice in the Solar System
We review the evidence for buried ice in the asteroid belt; specifically the questions around the so-called Main Belt Comets (MBCs). We summarise the evidence for water throughout the Solar System, and describe the various methods for detecting it, including remote sensing from ultraviolet to radio wavelengths. We review progress in the first decade of study of MBCs, including observations, modelling of ice survival, and discussion on their origins. We then look at which methods will likely be most effective for further progress, including the key challenge of direct detection of (escaping) water in these bodies
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