6,957 research outputs found
The Formation of Morpholine Thiosulfate From Morpholine and Sulfur
In recent years the use of morpholine and sulfur in the Willgerodt reaction has received considerable attention. There have been several mechanisms proposed for the Willgerodt reaction, but the most generally accepted mechanism today is that outlined by King and McMillan1. These authors have attempted to show that an independent reaction between sulfur and the amine is essential to this reaction. They have postulated an amine sulfide intermediate similar to the already known amine oxides. These sulfides have not been isolated as by-products of the reaction nor have they been prepared in any other way. The only previous evidence of a reaction between sulfur and morpholine is the formation of dithiooxalodi-morpholide reported by Horton and Van den Berghe2
Development of mathematical techniques for the analysis of remote sensing data
There are no author-identified significant results in this report
Four Bed Molecular Sieve - Exploration (4BMS-X) Virtual Heater Design and Optimization
A 4BMS-X (Four Bed Molecular Sieve - Exploration) design and heater optimization study for CO2 sorbent beds in proposed exploration system architectures is presented. The primary objectives of the study are to reduce heater power and thermal gradients within the CO2 sorbent beds while minimizing channeling effects. Some of the notable changes from the ISS (International Space Station) CDRA (Carbon Dioxide Removal Assembly) to the proposed exploration system architecture include cylindrical beds, alternate sorbents and an improved heater core. Results from both 2D and 3D sorbent bed thermal models with integrated heaters are presented. The 2D sorbent bed models are used to optimize heater power and fin geometry while the 3D models address end effects in the beds for more realistic thermal gradient and heater power predictions
A new photon recoil experiment: towards a determination of the fine structure constant
We report on progress towards a measurement of the fine structure constant to
an accuracy of or better by measuring the ratio of the
Planck constant to the mass of the cesium atom. Compared to similar
experiments, ours is improved in three significant ways: (i) simultaneous
conjugate interferometers, (ii) multi-photon Bragg diffraction between same
internal states, and (iii) an about 1000 fold reduction of laser phase noise to
-138 dBc/Hz. Combining that with a new method to simultaneously stabilize the
phases of four frequencies, we achieve 0.2 mrad effective phase noise at the
location of the atoms. In addition, we use active stabilization to suppress
systematic effects due to beam misalignment.Comment: 12 pages, 9 figure
Rapid reduction versus abrupt quitting for smokers who want to stop soon: a randomised controlled non-inferiority trial
Background: The standard way to stop smoking is to stop abruptly on a quit day with no prior reduction in consumption of cigarettes. Many smokers feel that reduction is natural and if reduction programmes were offered, many more might take up treatment. Few trials of reduction versus abrupt cessation have been completed. Most are small, do not use pharmacotherapy, and do not meet the standards necessary to obtain a marketing authorisation for a pharmacotherapy.\ud
Design/Methods: We will conduct a non-inferiority andomised trial of rapid reduction versus standard abrupt cessation among smokers who want to stop smoking. In the reduction arm,participants will be advised to reduce smoking consumption by half in the first week and to 25% of baseline in the second, leading up to a quit day at which participants will stop smoking completely.This will be assisted by nicotine patches and an acute form of nicotine replacement therapy. In the abrupt arm participants will use nicotine patches only, whilst smoking as normal, for two weeks prior to a quit day, at which they will also stop smoking completely. Smokers in either arm will have standard withdrawal orientated behavioural support programme with a combination of nicotine patches and acute nicotine replacement therapy post-cessation.\ud
Outcomes/Follow-up: The primary outcome of interest will be prolonged abstinence from smoking, with secondary trial outcomes of point prevalence, urges to smoke and withdrawal\ud
symptoms. Follow up will take place at 4 weeks, 8 weeks and 6 months post-quit day
New Five Dimensional Black Holes Classified by Horizon Geometry, and a Bianchi VI Braneworld
We introduce two new families of solutions to the vacuum Einstein equations
with negative cosmological constant in 5 dimensions. These solutions are static
black holes whose horizons are modelled on the 3-geometries nilgeometry and
solvegeometry. Thus the horizons (and the exterior spacetimes) can be foliated
by compact 3-manifolds that are neither spherical, toroidal, hyperbolic, nor
product manifolds, and therefore are of a topological type not previously
encountered in black hole solutions. As an application, we use the
solvegeometry solutions to construct Bianchi VI braneworld cosmologies.Comment: LaTeX, 20 pages, 2 figures Typographical errors corrected, and
references to printed matter added in favour of preprints where possibl
Near-Surface Interface Detection for Coal Mining Applications Using Bispectral Features and GPR
The use of ground penetrating radar (GPR) for detecting the presence of near-surface interfaces is a scenario of special interest to the underground coal mining industry. The problem is difficult to solve in practice because the radar echo from the near-surface interface is often dominated by unwanted components such as antenna crosstalk and ringing, ground-bounce effects, clutter, and severe attenuation. These nuisance components are also highly sensitive to subtle variations in ground conditions, rendering the application of standard signal pre-processing techniques such as background subtraction largely ineffective in the unsupervised case. As a solution to this detection problem, we develop a novel pattern recognition-based algorithm which utilizes a neural network to classify features derived from the bispectrum of 1D early time radar data. The binary classifier is used to decide between two key cases, namely whether an interface is within, for example, 5 cm of the surface or not. This go/no-go detection capability is highly valuable for underground coal mining operations, such as longwall mining, where the need to leave a remnant coal section is essential for geological stability. The classifier was trained and tested using real GPR data with ground truth measurements. The real data was acquired from a testbed with coal-clay, coal-shale and shale-clay interfaces, which represents a test mine site. We show that, unlike traditional second order correlation based methods such as matched filtering which can fail even in known conditions, the new method reliably allows the detection of interfaces using GPR to be applied in the near-surface region. In this work, we are not addressing the problem of depth estimation, rather confining ourselves to detecting an interface within a particular depth range
Reactions of a Be-10 beam on proton and deuteron targets
The extraction of detailed nuclear structure information from transfer
reactions requires reliable, well-normalized data as well as optical potentials
and a theoretical framework demonstrated to work well in the relevant mass and
beam energy ranges. It is rare that the theoretical ingredients can be tested
well for exotic nuclei owing to the paucity of data. The halo nucleus Be-11 has
been examined through the 10Be(d,p) reaction in inverse kinematics at
equivalent deuteron energies of 12,15,18, and 21.4 MeV. Elastic scattering of
Be-10 on protons was used to select optical potentials for the analysis of the
transfer data. Additionally, data from the elastic and inelastic scattering of
Be-10 on deuterons was used to fit optical potentials at the four measured
energies. Transfers to the two bound states and the first resonance in Be-11
were analyzed using the Finite Range ADiabatic Wave Approximation (FR-ADWA).
Consistent values of the spectroscopic factor of both the ground and first
excited states were extracted from the four measurements, with average values
of 0.71(5) and 0.62(4) respectively. The calculations for transfer to the first
resonance were found to be sensitive to the size of the energy bin used and
therefore could not be used to extract a spectroscopic factor.Comment: 16 Pages, 10 figure
Europium valence state distributions in equilibrated ordinary chondrites
It has been recognized for 30 years that the presence of Eu anomalies in REE patterns is due to the presence of divalent Eu, unique among the REE. However, it has not previously been possible to infer quantitative Eu^(+2)/Eu^(+3) ratios in natural samples. We have used ion probe data for lithophile trace elements for the phases in equilibrated ordinary chondrites [Guareiia (H6), Marion (L6) and St. Sevérin (LL6)] to perform mass-balance calculations that yield relatively precise Eu^(+2)/Eu^(+3) ratios
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