3,077 research outputs found
Electrostatic Patch Effect in Cylindrical Geometry. I. Potential and Energy between Slightly Non-Coaxial Cylinders
We study the effect of any uneven voltage distribution on two close
cylindrical conductors with parallel axes that are slightly shifted in the
radial and by any length in the axial direction. The investigation is
especially motivated by certain precision measurements, such as the Satellite
Test of the Equivalence Principle (STEP). By energy conservation, the force can
be found as the energy gradient in the vector of the shift, which requires
determining potential distribution and energy in the gap. The boundary value
problem for the potential is solved, and energy is thus found to the second
order in the small transverse shift, and to lowest order in the gap to cylinder
radius ratio. The energy consists of three parts: the usual capacitor part due
to the uniform potential difference, the one coming from the interaction
between the voltage patches and the uniform voltage difference, and the energy
of patch interaction, entirely independent of the uniform voltage. Patch effect
forces and torques in the cylindrical configuration are derived and analyzed in
the next two parts of this work.Comment: 26 pages, 1 Figure. Submitted to Classical and Quantum Gravit
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Parallel performance tuning using moments of utilization data
Many performance tuning tools for parallel software use visual representations of trace data to guide a developer towards code improvements. Most widely used visualization schemes, however, either omit useful information about time dependence of processor use, or include that information but do not scale well to long run times or massively parallel architectures. I propose a new visual representation of parallel program trace data that both scales well, and preserves time-dependent information. My approach is to partially transform profiled utilization data by computing its first few statistical moments. This preserves the most important timeÂ-dependent features of the underlying Gantt chart, while storing and displaying a set of parameters linear in number of processors and constant in execution time. By introducing task resolution into the analysis, the "moment" display can both alert a user to performance problems and direct that user to specific corresponding areas of code. I compare moment displays to conventional utilization Gantt chart displays by using published profile data. In a series of examples, I show how task-resolved moment displays would be used to detect and remove performance flaws from a parallel matrix multiplication computation. I also briefly review the mathematical theory behind transformations and statistical moments
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Surface structure, bonding, and dynamics: The universality of zincblende (110) potential energy surfaces
Using a tight-binding, total energy (TBTE) model we examine the hypothesis that the potential energy surfaces (PES) describing the (110) cleavage faces of the tetrahedrally coordinated, zincblende-structure compound semiconductors exhibit a common universal'' form if expressed in terms of suitably scaled parameters. TBTE calculations on both III-V and II-VI compounds reveal a linear scaling with bulk lattice constant of the geometric parameters of the reconstructed surfaces. This scaling is analogous to that found using low-energy, electron-diffraction surface-structure determination. The surface atomic force constants (found from a TBTE calculation) also scale monotonically with the lattice constant. Using TBTE models proposed previously for GaP, GaAs, GaSb, InP, and ZnSe, we find that the force constants scale as the inverse square of the bulk lattice constant. These results suggest that if distances are measured in units of the bulk lattice constant, the PES may be a universal function for the cleavage surface of zincblende-structure compound semiconductors, on average, with small fluctuations from this average occurring in individual materials. 22 refs., 5 figs., 1 tab
Poly(4-vinyl pyridine) radiografted PVDF track etched membranes as sensors for monitoring trace mercury in water
International audiencePoly-4-vinyl pyridine chains were radiografted inside the etched-tracks of PVDF nanoporous membrane. P4VP grafting was found to be localized on the solid PVDF surface. Coating of these PVDF-g-P4VP membranes with a very thin layer of gold results in an ASV electrochemical sensor. Functionalized ion track-etched PVDF-g-P4VP sensors were found very selective and highly sensitive for mercury LOD 5 ng/L. a b s t r a c t By a radiation-induced grafting technique, we have functionalized track-etched nanoporous polymer membranes with mercury sensitive poly-4-vinyl pyridine (P4VP). Coating of these membranes with a very thin layer of gold results in an electrochemical sensor that is very selective and highly sensitive for mercury LOD 5 ng/L â well below the norms for water (0.015 mg/L potable water and 0.5 mg/L residual waters-French water norms of 27 October 2011). E-beam irradiation permitted optimization of the radiografting synthesis on PVDF thin films prior to ion-track grafting. Synthesis and characterization by EPR, FESEM and FTIR are described in detail. A comparison between FTIR in ATR and transmission modes enabled us to localize the grafting on the surface of the e-beam irradiated PVDF films allowing us to extrapolate what happens on the etched tracks. Using Square Wave Anodic Stripping Voltammetry (SW-ASV), mercury concentrations of 1 mg/L are detected in 2 h and low ng/L concentrations are detected after 24 h of adsorption. The adsorption is passive so sensors do not require instrumentation and the analysis takes only 3â4 min. Also, the P4VP functionalized sensor appears insensitive to pH variations (pHs 3â9), high salt concentrations (up to 1 g/ L) and the presence of other heavy metals in the same solution.
The Effect of the Environment on alpha-Al_2O_3 (0001) Surface Structures
We report that calculating the Gibbs free energy of the alpha-Al_2O_3 (0001)
surfaces in equilibrium with a realistic environment containing both oxygen and
hydrogen species is essential for obtaining theoretical predictions consistent
with experimental observations. Using density-functional theory we find that
even under conditions of high oxygen partial pressure, the metal terminated
surface is surprisingly stable. An oxygen terminated alpha-Al_2O_3 (0001)
surface becomes stable only if hydrogen is present on the surface. In addition,
including hydrogen on the surface resolves discrepancies between previous
theoretical work and experimental results with respect to the magnitude and
direction of surface relaxations.Comment: 4 pages including 2 figures. Submitted to Phys. Rev. Lett. Related
publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm
Non-Destructive Evaluation of Damage and Failure of Fibre Reinforced Polymer Composites Using Ultrasonic Waves and Acoustic Emission
Real time noise and wavelength correlations in octave-spanning supercontinuum generation
We use dispersive Fourier transformation to measure shot-to-shot spectral
instabilities in femtosecond supercontinuum generation. We study both the onset
phase of supercontinuum generation with distinct dispersive wave generation, as
well as a highly-unstable supercontinuum regime spanning an octave in
bandwidth. Wavelength correlation maps allow interactions between separated
spectral components to be identified, even when such interactions are not
apparent in shot-to-shot or average measurements. Experimental results are
interpreted using numerical simulations. Our results show the clear advantages
of dispersive Fourier transformation for studying spectral noise during
supercontinuum generation.Comment: 14 pages, 5 figure
Extended states in 1D lattices: application to quasiperiodic copper-mean chain
The question of the conditions under which 1D systems support extended
electronic eigenstates is addressed in a very general context. Using real space
renormalisation group arguments we discuss the precise criteria for determining
the entire spertrum of extended eigenstates and the corresponding
eigenfunctions in disordered as well as quasiperiodic systems. For purposes of
illustration we calculate a few selected eigenvalues and the corresponding
extended eigenfunctions for the quasiperiodic copper-mean chain. So far, for
the infinite copper-mean chain, only a single energy has been numerically shown
to support an extended eigenstate [ You et al. (1991)] : we show analytically
that there is in fact an infinite number of extended eigenstates in this
lattice which form fragmented minibands.Comment: 10 pages + 2 figures available on request; LaTeX version 2.0
Effective Feedback to Improve Primary Care Prescribing Safety (EFIPPS) a pragmatic three-arm cluster randomised trial:designing the intervention (ClinicalTrials.gov registration NCT01602705)
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