The use of demineralisation and torrefaction to improve the properties of biomass intended as a feedstock for fast pyrolysis

Pre-treatments of biomass were investigated to reduce its undesirable properties which may affect the quality of fast pyrolysis bio-oil. A pre-treatment sequence was developed in this study to incorporate both biomass demineralisation and torrefaction. Demineralisation was performed by dilute acid leaching, primarily to reduce the inorganic concentration in raw biomass, whereas torrefaction targeted a reduction of the carboxyl, moisture and oxygen content. The liquid produced during torrefaction was recycled back as the leaching reagent for demineralisation. This solution contained dilute organic acids; therefore, the viability of leaching with organic acids (acetic and formic acid) compared to commonly used mineral acids (sulphuric, nitric and hydrochloric acid) was validated. Synthetic leaching solutions reduced the inorganic content in raw biomass from 0.41 wt% to 0.14 wt% when leached with 1% formic acid and to 0.16 wt% when leached with 1% acetic acid, which was comparable to leaching with the mineral acids. Recycled torrefaction liquid that contained other acidic compounds in small quantities reduced the inorganic content to 0.14 wt%, suggesting it is effective to use the recycled torrefaction liquid as the leaching solution. From the experimental results, the optimal conditions for biomass torrefaction were 260 °C for 20 min to minimise the char formation during pyrolysis, based on the increase in the acid-insoluble fraction of the biomass. However, the torrefaction temperature may be increased to 280 °C if further reductions in acetyl and oxygen content are required. Higher temperatures are associated with severe biomass loss and the initiation of hydrogen loss. It should be noted that even at 280 °C, the oxygen reduction is minimal. If oxygen reduction is the principal target when pre-treating biomass, it is suggested that torrefaction alone is not a suitable method to obtain bio-oil with a low oxygen content due to the low pyrolysis yields obtainable. This study demonstrated that the combined use of demineralisation and torrefaction as biomass pre-treatments has the ability to decrease the inorganic, acetyl and moisture content of biomass, which reduces undesirable catalytic reactions during fast pyrolysis to improve the quality of bio-oil produced

The infection biology of pig-associated Salmonella

Through the use of an establishe dline of porcine intestinal epithelial cells, known as IPEC-1, this in vitro work examines the initial adhesion, invasion and persistence abilities of different Salmonella serovars and phage types, including multiresistant and monophasic S. typhimurium DT193 isolates. The resultant innate immune response of the porcine cells to the isolates is assessed through determination of interleukin (IL)-6 and IL-8 concentrations present in cell culture supernatants

Crystallization and preliminary crystallographic analysis of the DNA gyrase B protein from B-stearothermophilus

DNA gyrase B (GyrB) from B. stearothermophilus has been crystallized in the presence of the non-hydrolyzable ATP analogue, 5'-adenylpl-beta-gamma-imidodiphosphate (ADPNP), by the dialysis method. A complete native data set to 3.7 Angstrom has been collected from crystals which belonged to the cubic space group I23 with unit-cell dimension a = 250.6 Angstrom. Self-rotation function analysis indicates the position of a molecular twofold axis. Low-resolution data sets of a thimerosal and a selenomethionine derivative have also been analysed. The heavy-atom positions are consistent with one dimer in the asymmetric unit

Landowner Reports of Deer Hunter Damage in Arkansas

Damage to property from deer hunters, though usually not discovered immediately, is a problem for many Arkansans. A questionnaire survey was mailed to 3,773 rural landowners in Arkansas to determine the type and cost of damage suffered from hunters. Thirty-five percent reported minor problems, and 15% reported severe damage from hunters. The most common problems caused by hunters were fence cutting (33%), severe littering (16%), road damage (13%), crop damage (10%), cattle shot (8%), gates left open (6%), and trespassing (6%). Eighty-three (5%) of the landowners reported damage costs of $500 or more; one sustained a$15,000 loss. Total state-wide losses are estimated at almost $15 million per year. Solutions lie in cultivating a stewardship position among landowners and a stronger ethic of respect among hunters. Mandatory hunter education programs can help instill hunter ethics, while posting laws can provide the administrative mechanism to control access and exposure

Forest Habitat Use by White-tailed Deer in the Arkansas Coastal Plain

Forest habitat use by five radio-equipped white-tailed deer (Odocoileus virginianus) was monitored in the Arkansas Coastal Plain during 1982-84. The deer were located 821 times. Use of forest types was compared to expected use as calculated from availability. The study area was also divided into 491 two-hectare cells for which timber characteristics and number of deer locations were determined. Pine sawtimber was the most heavily used forest type in all seasons and was used more often than expected during spring. Also used more than expected were brushy areas (clearcut but not site prepared) during spring, summer and fall and openings (grass fields and a site-prepared clearcut) during summer. Hardwood stands were used less often than expected during every season. Also used less than expected were pine pulpwood stands in summer and pine-hardwood stands during spring and summer. A significant (P \u3c 0.001) discriminant function correctly classified 74% of the two-hectare cells as used (1+ locations) or not used (0 locations). Used cells often had less hardwood pulpwood and sawtimber and more pine sawtimber than nonused cells. Use by deer of cells containing stand edges did not differ from use of cells without edges

The Paris warming targets: emissions requirements and sea level consequences

The Paris Agreement states that, relative to pre-industrial times, the increase in global average temperature should be kept to well below 2 °C and efforts should be made to limit the temperature increase to 1.5 °C. Emissions scenarios consistent with these targets are derived. For an eventual 2 °C warming target, this could be achieved even if CO2 emissions remained positive. For a 1.5 °C target, CO2 emissions could remain positive, but only if a substantial and long-lasting temperature overshoot is accepted. In both cases, a warming overshoot of 0.2 to 0.4 °C appears unavoidable. If the allowable (or unavoidable) overshoot is small, then negative emissions are almost certainly required for the 1.5 °C target, peaking at negative 1.3 GtC/year. In this scenario, temperature stabilization occurs, but cumulative emissions continue to increase, contrary to a common belief regarding the relationship between temperature and cumulative emissions. Changes to the Paris Agreement to accommodate the overshoot possibility are suggested. For sea level rise, tipping points that might lead to inevitable collapse of Antarctic ice sheets or shelves might be avoided for the 2 °C target (for major ice shelves) or for the 1.5 °C target for the West Antarctic Ice Sheet. Even with the 1.5 °C target, however, sea level will continue to rise at a substantial rate for centuries.T.M.L. Wigle

Emulating IPCC AR4 atmosphere-ocean and carbon cycle models for projecting global-mean, hemispheric and land/ocean temperatures: MAGICC 6.0

International audienceCurrent scientific knowledge on the future response of the climate system to human-induced perturbations is comprehensively captured by various model intercomparison efforts. In the preparation of the Fourth Assessment Report (AR4) of the Intergovernmental Panel on Climate Change (IPCC), intercomparisons were organized for atmosphere-ocean general circulation models (AOGCMs) and carbon cycle models, named "CMIP3" and "C4MIP", respectively. Despite their tremendous value for the scientific community and policy makers alike, there are some difficulties in interpreting the results. For example, key radiative forcings have not been considered or standardized in the majority of AOGCMs integrations and carbon cycle runs. Furthermore, the AOGCM analysis of plausible emission pathways was restricted to only three SRES scenarios. This study attempts to address these issues. We present an updated version of MAGICC, the simple carbon cycle-climate model used in past IPCC Assessment Reports with enhanced representation of time-varying climate sensitivities, carbon cycle feedbacks, aerosol forcings and ocean heat uptake characteristics. This new version of MAGICC (6.0) is successfully calibrated against the higher complexity AOGCM and carbon cycle models. Parameterizations of MAGICC 6.0 are provided. Previous MAGICC versions and emulations shown in IPCC AR4 (WG1, Fig. 10.26, page 803) yielded, in average, a 10% larger global-mean temperature increase over the 21st century compared to the AOGCMs. The reasons for this difference are discussed. The emulations presented here using MAGICC 6.0 match the mean AOGCM responses to within 2.2% for the SRES scenarios. This enhanced emulation skill is due to: the comparison on a "like-with-like" basis using AOGCM-specific subsets of forcings, a new calibration procedure, as well as the fact that the updated simple climate model can now successfully emulate some of the climate-state dependent effective climate sensitivities of AOGCMs. The mean diagnosed effective climate sensitivities of the AOGCMs is 2.88°C, about 0.33°C cooler than the reported slab ocean climate sensitivities. Finally, we examine the combined climate system and carbon cycle emulations for the complete range of IPCC SRES emission scenarios and some lower mitigation pathways