T-government for benefit realisation

This paper proposes a model for t-Government and highlights the research agenda needed to increase understanding of transformational government and the processes involved in furthering the agenda of the t-Government. In particular, both an operational and a conceptual model for the effective involvement of citizens and businesses in government functioning have been proposed. This will help to define an agenda for t-Government research that emerges from national UK strategy and policy for e-Government. The main threads of t- Government encompass: (1) A citizen-centric delivery of public services or e-inclusion, (2) A shared services culture to maximize value added to clients, (3) The effective delivery and management of resources and skills within government or professionalism. All three threads should be addressed principally from the perspectives of delivery, evaluation and participation in view of benefit realisation as envisioned by Government strategic planning and policy directives (CabinetOffice, 2005). The management of change dimension of these phenomena have been included in the research agenda. In particular, research is needed to reshape the discourse towards emphasising a citizen centric approach that defines, develops, and benefits from public service. Decision makers in Government will need models of Governance that fulfil transformational objectives. They will also need models of benefits realisation within a strategic Governance framework. It has been argued that t-Government research should be addressing these relative voids

Spin-coated Tin-doped NiO thin films for third order nonlinear optical applications

A self-made spin-coater was employed to deposit pure and Sn doped nickel oxide thin films on glass substrates. The tin doping impact on the structural, linear and nonlinear optical properties of the spin-coated NiO thin films was studied. The XRD analysis showed that undoped and Sn doped NiO thin films have a cubic structure and are preferentially oriented along the (200) direction. The increase of doping concentration leads to a modification in the values of certain parameters such as the crystallite size and the structural strain as well as affecting the nonlinear optical properties of the doped nickel oxide thin films. The values of the third order nonlinear optical susceptibility, found to be between 2.25 × 10−21 m2/V2 and 3.13 × 10−21 m2/V2, were obtained and analyzed depending on the concentration of the doping

Comparison of structural, morphological, linear and nonlinear optical properties of NiO thin films elaborated by Spin-Coating and Spray Pyrolysis

The paper reports on a comparative study of nickel oxide thin films prepared via two different elaboration methods spin-coating and spray pyrolysis. The structure and the surface topography of the NiO thin films have been studied by X-ray diffraction and the atomic force microscope. The optical properties of the deposited films were characterized with the analysis of the experimentally recorded optical transmittance data in the spectral wavelength range of 300–850 nm, via a JENWAY6715 UV–vis spectrophotometer. To complete the comparison, the third order nonlinear optical susceptibility was determined from the third harmonic generation experiment, which in turn were explored by the rotational Maker fringe technique using the beam of Nd:YAG laser at 1064 nm in picoseconds regime. The present work is aimed to exhibit the influence of the elaboration method on the physical properties through analyzing the obtained experimental results

Effect of zinc/cadmium proportion in CdS layers deposited by CBD method

Cadmium poisoning and the cost of panel recovery which is very expensive and difficult in the buffer layers of CdS in solar cell, for these two drawbacks, we do a search on the effect of proportion of zinc/cadmium in the properties layers of CdS. For this, our studies study the properties of CdxZn1-xS layers deposited by chemical bath (CBD). CdZnS thin films were synthesized by chemical bath deposition (CBD) with different deposition protocols to optimize deposition parameters such as temperature, deposition time, ion concentrations and pH. The surface morphology, structural, optical and chemical properties of the CdZnS thin films were studied by SEM, XRD, Raman and UV-visible spectrophotometer. The transmittance is 80% in the visible region 300 nm - 800 nm; the crystalline structure is hexagonal and cubic, the grain size is between 9.95 to 25.82 nm. It is observed that the transmittance and the shape change with the concentration of zinc in the solution; this result favors the application of these films in solar cells application

Properties Study of ZnS Thin Films Prepared by Spray Pyrolysis Method

Zinc sulfide (ZnS) is important II-VI semiconductors material for the development of various modern technologies and photovoltaic applications. ZnS thin film was prepared by using chemical spray pyrolysis technique. The starting solution is a mixture of 0.1 M zinc chloride as source of Zn and 0.05 M thiourea as source of S. The glass substrate temperature was varied in the range of 300 °C-400 °C to investigate the influence of substrate temperature on the structure, chemical composition, morphological and optical properties of ZnS films. The DRX analyses indicated that ZnS films have polycrystalline cubic structure with (111) preferential orientation and grain size varied from 25 to 60 nm, increasing with substrate temperature. The optical properties of these films have been studied in the wavelength range 300-2500 nm using UV-VIS spectro-photometer. The ZnS films has a band gap of 3.89 eV-3.96 eV

Properties Study of ZnS Thin Films Prepared by Spray Pyrolysis Method

Zinc sulfide (ZnS) is important II-VI semiconductors material for the development of various modern technologies and photovoltaic applications. ZnS thin film was prepared by using chemical spray pyrolysis technique. The starting solution is a mixture of 0.1 M zinc chloride as source of Zn and 0.05 M thiourea as source of S. The glass substrate temperature was varied in the range of 300 °C-400 °C to investigate the influence of substrate temperature on the structure, chemical composition, morphological and optical properties of ZnS films. The DRX analyses indicated that ZnS films have polycrystalline cubic structure with (111) preferential orientation and grain size varied from 25 to 60 nm, increasing with substrate temperature. The optical properties of these films have been studied in the wavelength range 300-2500 nm using UV-VIS spectro-photometer. The ZnS films has a band gap of 3.89 eV-3.96 eV

Wave particle interactions in the high-altitude polar cusp: a Cluster case study

On 23 March 2002, the four Cluster spacecraft crossed in close configuration (~100 km separation) the high-altitude (10 <i>R<sub>E</sub></i>) cusp region. During a large part of the crossing, the STAFF and EFW instruments have detected strong electromagnetic wave activity at low frequencies, especially when intense field-aligned proton fluxes were detected by the CIS/HIA instrument. In all likelihood, such fluxes correspond to newly-reconnected field lines. A focus on one of these ion injection periods highlights the interaction between waves and protons. The wave activity has been investigated using the k-filtering technique. Experimental dispersion relations have been built in the plasma frame for the two most energetic wave modes. Results show that kinetic Alfvén waves dominate the electromagnetic wave spectrum up to 1 Hz (in the spacecraft frame). Above 0.8 Hz, intense Bernstein waves are also observed. The close simultaneity observed between the wave and particle events is discussed as an evidence for local wave generation. A mechanism based on current instabilities is consistent with the observations of the kinetic Alfvén waves. A weak ion heating along the recently-opened field lines is also suggested from the examination of the ion distribution functions. During an injection event, a large plasma convection motion, indicative of a reconnection site location, is shown to be consistent with the velocity perturbation induced by the large-scale Alfvén wave simultaneously detected

Special Issue of Opto-Electronics Review on Nanophotonics

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