Absence of magnetically-induced fractional quantization in atomic contacts

Using the mechanically controlled break junction technique at low temperatures and under cryogenic vacuum conditions we have studied atomic contacts of several magnetic (Fe, Co and Ni) and non-magnetic (Pt) metals, which recently were claimed to show fractional conductance quantization. In the case of pure metals we see no quantization of the conductance nor half-quantization, even when high magnetic fields are applied. On the other hand, features in the conductance similar to (fractional) quantization are observed when the contact is exposed to gas molecules. Furthermore, the absence of fractional quantization when the contact is bridged by H_2 indicates the current is never fully polarized for the metals studied here. Our results are in agreement with recent model calculations.Comment: 4 pages, 3 figure

Mechanical properties of Pt monatomic chains

The mechanical properties of platinum monatomic chains were investigated by simultaneous measurement of an effective stiffness and the conductance using our newly developed mechanically controllable break junction (MCBJ) technique with a tuning fork as a force sensor. When stretching a monatomic contact (two-atom chain), the stiffness and conductance increases at the early stage of stretching and then decreases just before breaking, which is attributed to a transition of the chain configuration and bond weakening. A statistical analysis was made to investigate the mechanical properties of monatomic chains. The average stiffness shows minima at the peak positions of the length-histogram. From this result we conclude that the peaks in the length-histogram are a measure of the number of atoms in the chains, and that the chains break from a strained state. Additionally, we find that the smaller the initial stiffness of the chain is, the longer the chain becomes. This shows that softer chains can be stretched longer.Comment: 6 pages, 5 figure

Effect of bonding of a CO molecule on the conductance of atomic metal wires

We have measured the effect of bonding of a CO molecule on the conductance of Au, Cu, Pt, and Ni atomic contacts at 4.2 K. When CO gas is admitted to the metal nano contacts, a conductance feature appears in the conductance histogram near 0.5 of the quantum unit of conductance, for all metals. For Au, the intensity of this fractional conductance feature can be tuned with the bias voltage, and it disappears at high bias voltage (above $\sim$ 200 mV). The bonding of CO to Au appears to be weakest, and associated with monotomic Au wire formation.Comment: 6 figure

Bulk and Surface Nucleation Processes in Ag2S Conductance Switches

We studied metallic Ag formation inside and on the surface of Ag2S thin films, induced by the electric field created with a STM tip. Two clear regimes were observed: cluster formation on the surface at low bias voltages, and full conductance switching at higher bias voltages (V > 70mV). The bias voltage at which this transition is observed is in agreement with the known threshold voltage for conductance switching at room temperature. We propose a model for the cluster formation at low bias voltage. Scaling of the measured data with the proposed model indicates that the process takes place near steady state, but depends on the STM tip geometry. The growth of the clusters is confirmed by tip retraction measurements and topography scans. This study provides improved understanding of the physical mechanisms that drive conductance switching in solid electrolyte memristive devices.Comment: In press for PR

Examining habituation and sensitization across repetitive laboratory stress inductions using the MAST

Reliably eliciting acute stress repeatedly over time is of indispensable value for research into stress vulnerability and for developing interventions aimed at increasing stress resiliency. Here, we evaluated whether the Maastricht Acute Stress Test (MAST), a potent stress protocol that combines physical and psychosocial stress components, can be used to reliably elicit subjective and neuroendocrine stress responses multiple times. Sixty healthy undergraduate participants were exposed to the MAST on three occasions, with intervals of three-weeks and one-month in between sessions. Results showed no significant signs of habituation or sensitization to the MAST in terms of subjective or physiological (salivary alpha-amylase and cortisol) stress reactivity. Fifty-nine percent of the sample displayed a significant physiological stress response (i.e., cortisol) to two MAST exposures and 57% to every MAST exposure. This study demonstrates that the MAST can be used to repeatedly induce significant stress responses

Придністровський конфлікт: чинники існування напруги

Стаття присвячена аналізу та систематизації чинників, що обумовлюють збереження статус-кво у процесі придністровського врегулювання на глобальному, регіональному та локальному рівні.The article is devoted to the analysis and systematization of factors leading to the preservation of the status-quo in the Transnistrian settlement process on global, regional and local level

Resistivity, Hall effect and Shubnikov-de Haas oscillations in CeNiSn

The resistivity and Hall effect in CeNiSn are measured at temperatures down to 35 mK and in magnetic fields up to 20 T with the current applied along the {\it b} axis. The resistivity at zero field exhibits quadratic temperature dependence below $\sim$0.16 K with a huge coefficient of the $T^2$ term (54 $\mu$$\Omega$cm/K$^2$). The resistivity as a function of field shows an anomalous maximum and dip, the positions of which vary with field directions. Shubnikov-de Haas (SdH) oscillations with a frequency {\it F} of $\sim$100 T are observed for a wide range of field directions in the {\it ac} and {\it bc} planes, and the quasiparticle mass is determined to be $\sim$10-20 {\it m}$_e$. The carrier density is estimated to be $\sim10^{-3}$ electron/Ce. In a narrow range of field directions in the {\it ac} plane, where the magnetoresistance-dip anomaly manifests itself clearer than in other field directions, a higher-frequency ($F=300\sim400\text{T}$) SdH oscillation is found at high fields above the anomaly. This observation is discussed in terms of possible field-induced changes in the electronic structure.Comment: 15 pages, 5 figures, to appear in Phys. Rev. B (15 Sept. 2002 issue

Electronic and optical properties of electromigrated molecular junctions

Electromigrated nanoscale junctions have proven very useful for studying electronic transport at the single-molecule scale. However, confirming that conduction is through precisely the molecule of interest and not some contaminant or metal nanoparticle has remained a persistent challenge, typically requiring a statistical analysis of many devices. We review how transport mechanisms in both purely electronic and optical measurements can be used to infer information about the nanoscale junction configuration. The electronic response to optical excitation is particularly revealing. We briefly discuss surface-enhanced Raman spectroscopy on such junctions, and present new results showing that currents due to optical rectification can provide a means of estimating the local electric field at the junction due to illumination.Comment: 19 pages, 8 figures, invited paper for forthcoming special issue of Journal of Physics: Condensed Matter. For other related papers, see http://www.ruf.rice.edu/~natelson/publications.htm