The behavior of radiogenic particles at solidification fronts

© 2016. This version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/The thermal behavior of insoluble radiogenic particles at the solid-liquid interface of an advancing solidification front and its significance with regard to environmental impact are discussed. It is shown that, unlike classical particles, where the most probable behavior is engulfing by the solidification front, radiogenic particles are more likely to be rejected by the solidification front. Utilizing a simplified physical model, an adaptation of classical theoretical models is performed, where it is shown that, unlike classical particles, for radiogenic particles the mechanism is thermally driven. An analytical expression for the critical velocity of the solidification front for engulfing/rejection to occur is derived. The study could be potentially important to several fields, e.g. in engineering applications where technological processes for the physical removal of radionuclide particles dispersed throughout another substance by inducing solidification could be envisaged, in planetary science where the occurrence of radiogenic concentration could result in the possibility of the eruption of primordial comet/planetoids, or, if specific conditions are suitable, particle ejection may result in an increase in concentration as the front moves, which can translate into the formation of hot spots.Peer ReviewedPostprint (author's final draft

Heat removal system for shutdown in nuclear thermal rockets and advanced concepts

© 2016 by the American Institute of Aeronautics and Astronautics, Inc.It is well-known that a nuclear thermal rocket (NTR) cannot be abruptly shut down. After a power manoeuver, the reactor has contaminated itself with fission products and the decay heat released must be removed by maintaining an adequate flow of hydrogen through its passages. The objective of this work was to derive a first estimate of how much hydrogen will be needed to prevent the core from overheating after shutdown, and, from this, be able to assess the advantages of using a dedicated decay heat removal system to reduce or eliminate the amount of hydrogen needed to prevent the core from overheating after shutdown. Furthermore, the use of such a heat removal system could be needed by certain special nuclear thermal propulsion concepts, such as the fission fragment rocket or the more recently proposed pulsed nuclear thermal rocket, where significant amplification of specific impulse, Isp, as well as thrust can be obtained by the direct use of fission fragments or by pulsing the nuclear core, respectively.Peer ReviewedPostprint (author's final draft

A neutron diode for subcritical multistage multipliers with special reference in tritium breeding

This is a copy of the author 's final draft version of an article published in the Journal of fusion energy. The final publication is available at Springer via http://dx.doi.org/10.1007/s10894-015-0049-7In this paper the interaction between a magnetic field and the neutron spin magnetic moment is explored for use in the design of a neutron diode or valve that allows a neutron flux to pass in one direction, while preventing a neutron flux in the opposite direction. A neutron diode that ensures the unidirectional movement of neutrons could be used in the design of a subcritical multistage neutron multiplier, a device that has thus far not been realised. With a subcritical multistage neutron multiplier, an initial source of neutrons could be multiplied substantially in a very small area. Such a device could have potential applications in tritium breeding in a fusion reactor, in medicine, in space exploration, etc. Utilizing a simplified geometrical model, a first preliminary study is performed to assess the feasibility of this concept.Peer ReviewedPostprint (author's final draft

A linear mass spectrometer by induced Hall potential for electromagnetic isotopic separation working at high pressures

© 2016. This version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/In this paper a novel alternative for bulk electromagnetic separation working at high pressures is proposed. It is shown that if a self-induced Hall potential is stimulated in the boundaries, the system will be able to take advantage of the collisions process, boosting the isotopic separation and resulting in a linear-spectrometer with a higher spatial separation per unit length than a traditional calutron. Although originally the concept was devised for the production of medical isotopes where the minority isotope to be separated is produced by neutron capture and is the heavier isotope, if the Hall potential is replaced by an external electrical field, the concept is equally applicable for situations where the minority isotope is the lighter one, as for example in the enrichment of uranium. Additional R&D is required to explore further the possibilities of this concept and to identify optimal values for several of the system design variables.Peer ReviewedPostprint (author's final draft

Second harmonic Hamiltonian: Algebraic and Schrödinger approaches

We study in detail the behavior of the energy spectrum for the second harmonic generation (SHG) and a family of corresponding quasi-exactly solvable Schrödinger potentials labeled by a real parameter b. The eigenvalues of this system are obtained by the polynomial deformation of the Lie algebra representation space. We have found the bi-confluent Heun equation (BHE) corresponding to this system in a differential realization approach, by making use of the symmetries. By means of a b-transformation from this second-order equation to a Schrödinger one, we have found a family of quasi-exactly solvable potentials. For each invariant n-dimensional subspace of the second harmonic generation, there are either n potentials, each with one known solution, or one potential with n-known solutions. Well-known potentials like a sextic oscillator or that of a quantum dot appear among them

Interaction of oxygen with TiN (001): N↔O exchange and oxidation process

This work presents a detailed experimental and theoretical study of the oxidation of TiN(001) using a combination of synchrotron-based photoemission and density functional theory (DFT). Experimentally, the adsorption of O2 on TiN(001) was investigated at temperatures between 250 and 450K. At the lowest temperature, there was chemisorption of oxygen (O2,gas→2Oads) without significant surface oxidation. In contrast, at 450K the amount of O2 adsorbed increased continuously, there was no evidence for an oxygen saturation coverage, a clear signal in the Ti 2p core level spectra denoted the presence of TiOx species, and desorption of both N2 and NO was detected. The DFT calculations show that the adsorption/dissociation of O2 is highly exothermic on a TiN(001) substrate and is carried out mainly by the Ti centers. A high oxygen coverage (larger than 0.5 ML) may induce some structural reconstructions of the surface. The exchange of a surface N atom by an O adatom is a highly endothermic process (ΔE=2.84eV). However, the overall oxidation of the surface layer is thermodynamically favored due to the energy released by the dissociative adsorption of O2 and the formation of N2 or NO. Both experimental and theoretical results lead to conclude that a TiN+mO2→TiOx+NO reaction is an important exit channel for nitrogen in the oxidation process.Ministerio de Educación y Ciencia de España, MEC. MAT2005-01872Junta de Andalucía. FQM-132División de Ciencias Químicas del Departamento de Energía de EE. UU. DE-AC02-98CH10086Fundación japonesa para la Ciencia de los Materiale

Extraordinary absorption of decorated undoped graphene

We theoretically study absorption by an undoped graphene layer decorated with arrays of small particles. We discuss periodic and random arrays within a common formalism, which predicts a maximum absorption of $50\%$ for suspended graphene in both cases. The limits of weak and strong scatterers are investigated and an unusual dependence on particle-graphene separation is found and explained in terms of the effective number of contributing evanescent diffraction orders of the array. Our results can be important to boost absorption by single layer graphene due to its simple setup with potential applications to light harvesting and photodetection based on energy (F\"orster) rather than charge transfer.Comment: 5 pages, 3 figure