491 research outputs found
Structure and Thermodynamics of the Mixed Alkali Alanates
The thermodynamics and structural properties of the hexahydride alanates
(M2M'AlH6) with the elpasolite structure have been investigated. A series of
mixed alkali alanates (Na2LiAlH6, K2LiAlH6 and K2NaAlH6) were synthesized and
found to reversibly absorb and desorb hydrogen without the need for a catalyst.
Pressure-composition isotherms were measured to investigate the thermodynamics
of the absorption and desorption reactions with hydrogen. Isotherms for
catalyzed (4 mol% TiCl3) and uncatalyzed Na2LiAlH6 exhibited an increase in
kinetics, but no change in the bulk thermodynamics with the addition of a
dopant. A structural analysis using synchrotron x-ray diffraction showed that
these compounds favor the Fm-3m space group with the smaller ion (M') occupying
an octahedral site. These results demonstrate that appropriate cation
substitutions can be used to stabilize or destabilize the material and may
provide an avenue to improving the unfavorable thermodynamics of a number of
materials with promising gravimetric hydrogen densities.Comment: 6 pages, 7 figures,3 tables, submitted to PR
Chemical Composition, Antioxidant, and Antimicrobial Activities of Lichen Umbilicaria cylindrica (L.) Delise (Umbilicariaceae)
The phytochemical analysis of methanol and chloroform extracts of Umbilicaria cylindrica was determined by HPLC-UV method. The predominant phenolic compound in both extracts was depsidone, salazinic acid (1). Besides salazinic acid, the tested extracts of U. cylindrica contain norstictic acid (2), methyl-β-orcinol carboxylate (3), ethyl haematommate (4), atranorin (5), and usnic acid (6), in different amounts and relations. The lichen extracts showed comparable and strong antioxidant activity, exhibited higher DPPH and hydroxyl radical scavengings, chelating activity, and inhibitory activity towards lipid peroxidation. The lichen extracts demonstrated important antimicrobial activity against eight strains with MIC values from 15.62 to 62.50 μg/mL. This is the first report of the detail chemical composition and antioxidant activity of the lichen Umbilicaria cylindrica, and the results suggest that this lichen can be used as a new source of the natural antioxidants and the substances with antimicrobial features
Raman study of insulating and conductive ZnO: (Al, Mn) thin films
Raman spectroscopy results obtained for undoped and Al- and/or Mn-doped ZnO thin films produced by RF-sputtering are reported. The effect of the doping method (either co-sputtering or ion implantation), the dopant type and its concentration on the Raman-active vibrational modes in these films were studied in detail. The results are discussed with focus on the peak shifts and broadening, and on the doping-induced relaxation of the symmetry selection rules. A particular attention is paid to the 520-530 cm-1 Raman band observed in all Mn containing samples and a simple theoretical model and arguments are presented in support of its relation to the local (gap) phonon mode produced by Mn atoms substituting Zn in the cationic sublattice of the ZnO crystal.Karlsruhe Nano Micro Facility (KNMF), a Helmholtz Research Infrastructure at KI
Massive Black Hole Binary Inspirals: Results from the LISA Parameter Estimation Taskforce
The LISA Parameter Estimation (LISAPE) Taskforce was formed in September 2007
to provide the LISA Project with vetted codes, source distribution models, and
results related to parameter estimation. The Taskforce's goal is to be able to
quickly calculate the impact of any mission design changes on LISA's science
capabilities, based on reasonable estimates of the distribution of
astrophysical sources in the universe. This paper describes our Taskforce's
work on massive black-hole binaries (MBHBs). Given present uncertainties in the
formation history of MBHBs, we adopt four different population models, based on
(i) whether the initial black-hole seeds are small or large, and (ii) whether
accretion is efficient or inefficient at spinning up the holes. We compare four
largely independent codes for calculating LISA's parameter-estimation
capabilities. All codes are based on the Fisher-matrix approximation, but in
the past they used somewhat different signal models, source parametrizations
and noise curves. We show that once these differences are removed, the four
codes give results in extremely close agreement with each other. Using a code
that includes both spin precession and higher harmonics in the
gravitational-wave signal, we carry out Monte Carlo simulations and determine
the number of events that can be detected and accurately localized in our four
population models.Comment: 14 pages, 2 figures, 5 tables, minor changes to match version to be
published in the proceedings of the 7th LISA Symposium. For more information
see the Taskforce's wiki at http://www.tapir.caltech.edu/dokuwiki/lisape:hom
The Current Status of Binary Black Hole Simulations in Numerical Relativity
Since the breakthroughs in 2005 which have led to long term stable solutions
of the binary black hole problem in numerical relativity, much progress has
been made. I present here a short summary of the state of the field, including
the capabilities of numerical relativity codes, recent physical results
obtained from simulations, and improvements to the methods used to evolve and
analyse binary black hole spacetimes.Comment: 14 pages; minor changes and corrections in response to referee
Discovery of the Onset of Rapid Accretion by a Dormant Massive Black Hole
Massive black holes are believed to reside at the centres of most galaxies.
They can be- come detectable by accretion of matter, either continuously from a
large gas reservoir or impulsively from the tidal disruption of a passing star,
and conversion of the gravitational energy of the infalling matter to light.
Continuous accretion drives Active Galactic Nuclei (AGN), which are known to be
variable but have never been observed to turn on or off. Tidal disruption of
stars by dormant massive black holes has been inferred indirectly but the on-
set of a tidal disruption event has never been observed. Here we report the
first discovery of the onset of a relativistic accretion-powered jet in the new
extragalactic transient, Swift J164449.3+573451. The behaviour of this new
source differs from both theoretical models of tidal disruption events and
observations of the jet-dominated AGN known as blazars. These differences may
stem from transient effects associated with the onset of a powerful jet. Such
an event in the massive black hole at the centre of our Milky Way galaxy could
strongly ionize the upper atmosphere of the Earth, if beamed towards us.Comment: Submitted to Nature. 4 pages, 3 figures (main paper). 26 pages, 13
figures (supplementary information
Multiwavelength periodicity study of Markarian 501
Context: Active Galactic Nuclei are highly variable emitters of
electromagnetic waves from the radio to the gamma-ray regime. This variability
may be periodic, which in turn could be the signature of a binary black hole.
Systems of black holes are strong emitters of gravitational waves whose
amplitude depends on the binary orbital parameters as the component mass, the
orbital semi-major-axis and eccentricity.
Aims: It is our aim to prove the existence of periodicity of the AGN
Markarian 501 from several observations in different wavelengths. A
simultaneous periodicity in different wavelengths provides evidence for bound
binary black holes in the core of AGN.
Methods: Existing data sets from observations by Whipple, SWIFT, RXTE and
MAGIC have been analysed with the Lomb-Scargle method, the epoch folding
technique and the SigSpec software.
Results: Our analysis shows a 72-day period, which could not be seen in
previous works due to the limited length of observations. This does not
contradict a 23-day period which can be derived as a higher harmonic from the
72-day period.Comment: 9 pages, 15 figures, accepted at A&
Clusters of galaxies : observational properties of the diffuse radio emission
Clusters of galaxies, as the largest virialized systems in the Universe, are
ideal laboratories to study the formation and evolution of cosmic
structures...(abridged)... Most of the detailed knowledge of galaxy clusters
has been obtained in recent years from the study of ICM through X-ray
Astronomy. At the same time, radio observations have proved that the ICM is
mixed with non-thermal components, i.e. highly relativistic particles and
large-scale magnetic fields, detected through their synchrotron emission. The
knowledge of the properties of these non-thermal ICM components has increased
significantly, owing to sensitive radio images and to the development of
theoretical models. Diffuse synchrotron radio emission in the central and
peripheral cluster regions has been found in many clusters. Moreover
large-scale magnetic fields appear to be present in all galaxy clusters, as
derived from Rotation Measure (RM) studies. Non-thermal components are linked
to the cluster X-ray properties, and to the cluster evolutionary stage, and are
crucial for a comprehensive physical description of the intracluster medium.
They play an important role in the cluster formation and evolution. We review
here the observational properties of diffuse non-thermal sources detected in
galaxy clusters: halos, relics and mini-halos. We discuss their classification
and properties. We report published results up to date and obtain and discuss
statistical properties. We present the properties of large-scale magnetic
fields in clusters and in even larger structures: filaments connecting galaxy
clusters. We summarize the current models of the origin of these cluster
components, and outline the improvements that are expected in this area from
future developments thanks to the new generation of radio telescopes.Comment: Accepted for the publication in The Astronomy and Astrophysics
Review. 58 pages, 26 figure
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