Field measurements of hygroscopic properties and state of mixing of nucleation mode particles

International audienceAn Ultrafine Tandem Differential Mobility Analyser (UF-TDMA) has been used in several field campaigns over the last few years. The investigations were focused on the origin and properties of nucleation event aerosols, which are observed frequently in various environments. This paper gives a summary of the results of 10 nm and 20 nm particle hygroscopic properties from different measurement sites: an urban site, an urban background site and a forest site in Finland and a coastal site in western Ireland. The data can be classified in four hygroscopic growth classes: hydrofobic, less-hygroscopic, more-hygroscopic and sea-salt. Similar classification has been earlier presented for Aitken and accumulation mode particles. In urban air, the summertime 10 nm particles showed varying less-hygroscopic growth behaviour, while winter time 10 nm and 20 nm particles were externally mixed with two different hygroscopic growth modes. The forest measurements revealed diurnal behaviour of hygroscopic growth, with high growth factors at day time and lower during night. The urban background particles had growth behaviour similar to the urban and forest measurement sites depending on the origin of the observed particles. The coastal measurements were strongly affected by air mass history. Both 10 nm and 20 nm particles were hygroscopic in marine background air. The 10 nm particles produced during clean nucleation burst periods were hydrofobic. Diurnal variation and higher growth factors of 10 nm particles were observed in air affected by other source regions. External mixing was occasionally observed at all the sites, but incidents with more than two growth modes were extremely rare

Field measurements of hygroscopic properties and state of mixing of nucleation mode particles

An Ultrafine Tandem Differential Mobility Analyser (UF-TDMA) has been used in several field campaigns over the last few years. The investigations were focused on the origin and properties of nucleation event aerosols, which are observed frequently in various environments. This paper gives a summary of the results of 10 nm and 20 nm particle hygroscopic properties from different measurement sites: an urban site, an urban background site and a forest site in Finland and a coastal site in western Ireland. The data can be classified in four hygroscopic growth classes: hydrofobic, less-hygroscopic, more-hygroscopic and sea-salt. Similar classification has been earlier presented for Aitken and accumulation mode particles. In urban air, the summertime 10 nm particles showed varying less-hygroscopic growth behaviour, while winter time 10 nm and 20 nm particles were externally mixed with two different hygroscopic growth modes. The forest measurements revealed diurnal behaviour of hygroscopic growth, with high growth factors at day time and lower during night. The urban background particles had growth behaviour similar to the urban and forest measurement sites depending on the origin of the observed particles. The coastal measurements were strongly affected by air mass history. Both 10 nm and 20 nm particles were hygroscopic in marine background air. The 10 nm particles produced during clean nucleation burst periods were hydrofobic. Diurnal variation and higher growth factors of 10 nm particles were observed in air affected by other source regions. External mixing was occasionally observed at all the sites, but incidents with more than two growth modes were extremely rare

The Effect of ArF-Excimer Laser Irradiation of the Human Enamel Surface on the Bond Strength of Orthodontic Appliances

This study investigated enamel laser conditioning as an alternative to acid etching in bracket therapy. In preliminary experiments optimal laser parameters for achieving a bond strength of 6-10 N/mm2 were defined. Enamel surface morphology was assessed and the ablation depth was measured on serial enamel sections. Thirty human molars were exposed to 193 nm ArF-excimer laser radiation (energy density: 260 mJ/cm2) by single pulse application of 23 nanoseconds. Thirty molars were etched with phosphoric acid (37%) for 60 seconds. The brackets from the treated molars and 30 untreated molars were debonded vertically for tensile bond strength measurement. Roughened enamel surfaces were attained by 450 and 900 laser pulses with a mean ablation depth of 10.13 ± 4. 84 μm. After 1-10 laser pulses, the enamel surface appeared intact. The tensile bond strength was 6.63 ± 2 .18 N/mm2 in the laser-treated group (1 pulse), 8.75 ± 3.61 N/mm2 in the acid-etched group, and 4 .61 ± 3.15 N/mm2 in the untreated group. We conclude a laser-selective ablation of the membranous enamel pellicle. Since the irradiated area can be adapted to bracket base and the enamel surface remains morphologically intact, pulsed ArF-excimer laser treatment seems to be superior to the acid etching technique

Intrinsic parton motion soft mechanisms and the longitudinal spin asymmetry A_LL in high energy pp -> pi X

The longitudinal double spin asymmetry A_LL in the reaction pp --> pi X has been measured at RHIC with extremely interesting consequences. If the gluon polarization in a proton were as big as needed to resolve the famous "spin crisis" then A_LL would be large and positive. Latest RHIC results indicate that A_LL is small and disfavour large positive values of the gluon polarization. We examine whether the soft mechanisms (Collins, Sivers, Boer-Mulders), essential for generating transverse single spin asymmetries, have any significant influence on A_LL, and whether they could alter the conclusion that the gluon polarization is necessarily small. It turns out that the contribution from these effects is essentially negligible.Comment: RevTeX, 9 pages, 3 eps figures. Revised and shortened version; title slightly modified; figs. 3,4 removed; a new figure for the unpol. cross section added; no changes in results and conclusions; matches the published versio

Virtual photon structure functions and positivity constraints

We study the three positivity constraints among the eight virtual photon structure functions, derived from the Cauchy-Schwarz inequality and which are hence model-independent. The photon structure functions obtained from the simple parton model show quite different behaviors in a massive quark or a massless quark case, but they satisfy, in both cases, the three positivity constraints. We then discuss an inequality which holds among the unpolarized and polarized photon structure functions $F_1^\gamma$, $g_1^\gamma$ and $W_{TT}^\tau$, in the kinematic region $\Lambda^2\ll P^2 \ll Q^2$, where $-Q^2 (-P^2)$ is the mass squared of the probe (target) photon, and we examine whether this inequality is satisfied by the perturbative QCD results.Comment: 24 pages, 13 eps figure

Exploring the polarization of gluons in the nucleon

We give an overview of the current status of investigations of the polarization of gluons in the nucleon. We describe some of the physics of the spin-dependent gluon parton distribution and its phenomenology in high-energy polarized hadronic scattering. We also review the recent experimental results.Comment: 10 pages, 13 figures. Talk presented at the "Second Meeting of the APS Topical Group on Hadronic Physics", Nashville, Tennessee, October 22-24, 2006. Reference adde

Has phytodetritus processing by an abyssal soft-sediment community recovered 26 years after an experimental disturbance?

The potential harvest of polymetallic nodules will heavily impact the abyssal, soft sediment ecosystem by removing sediment, hard substrate, and associated fauna inside mined areas. It is therefore important to know whether the ecosystem can recover from this disturbance and if so at which rate. The first objective of this study was to measure recovery of phytodetritus processing by the benthic food web from a sediment disturbance experiment in 1989. The second objective was to determine the role of holothurians in the uptake of fresh phytodetritus by the benthic food web. To meet both objectives, large benthic incubation chambers (CUBEs; 50 × 50 × 50 cm) were deployed inside plow tracks (with and without holothurian presence) and at a reference site (holothurian presence, only) at 4100 m water depth. Shortly after deployment, ¹³C- and ¹⁵N-labeled phytodetritus was injected in the incubation chambers and during the subsequent 3-day incubation period, water samples were taken five times to measure the production of ¹³C-dissolved inorganic carbon over time. At the end of the incubation, holothurians and sediment samples were taken to determine biomass, densities and incorporation of ¹³C and ¹⁵N into bacteria, nematodes, macrofauna, and holothurians. For the first objective, the results showed that biomass of bacteria, nematodes and macrofauna did not differ between reference sites and plow track sites when holothurians were present. Additionally, meiofauna and macrofauna taxonomic composition was not significantly different between the sites. In contrast, total ¹³C uptake by bacteria, nematodes and holothurians was significantly lower at plow track sites compared to reference sites, though the number of replicates was low. This result suggests that important ecosystem functions such as organic matter processing have not fully recovered from the disturbance that occurred 26 years prior to our study. For the second objective, the analysis indicated that holothurians incorporated 2.16 × 10⁻³ mmol labile phytodetritus C m⁻² d⁻¹ into their biomass, which is one order of magnitude less as compared to bacteria, but 1.3 times higher than macrofauna and one order of magnitude higher than nematodes. Additionally, holothurians incorporated more phytodetritus carbon per unit biomass than macrofauna and meiofauna, suggesting a size-dependence in phytodetritus carbon uptake

Global Analysis of Helicity Parton Densities and Their Uncertainties

We present a new analysis of the helicity parton distributions of the nucleon. The analysis takes into account the available data from inclusive and semi-inclusive polarized deep inelastic scattering, as well as from polarized pp scattering at RHIC. For the first time, all theoretical calculations are performed fully at next-to-leading order (NLO) of perturbative QCD, using a method that allows to incorporate the NLO corrections in a very fast and efficient way in the analysis. We find evidence for a rather small gluon polarization in the nucleon, over a limited region of momentum fraction, and for interesting flavor patterns in the polarized sea.Comment: 4 pages, 3 figure

Polarized Photon Structure: g1γg_1^\gamma and g2γg_2^\gamma

We investigate the polarized photon structure functions $g_1^\gamma$ and $g_2^\gamma$ which can be studied in the future polarized version of ep or e$^+$e$^-$ colliders. The NLO QCD calculations of $g_1^\gamma$ and the possible twist-3 effects in $g_2^\gamma$ are discussed.Comment: 8 pages, LaTeX2e, 1 eps figure, cjpsuplf.cls file included, Talk given at the Advanced Study Institute on Symmetries and Spin, Praha-SPIN-2001, Prague, July 15-28, 2001, to appear in the Proceeding

The Interaction of Laser Energy with Ureter Tissues in a Long Term Investigation

This study investigates tissue responses after laser irradiation of the rabbit ureter, which serves as an experimental model for rectourogenital fistulae of children. Twenty-five rabbit ureters were irradiated intraluminally by a Nd:YAG laser 1320 nm (2 Watt, 20 seconds and 3 Watt, 8 seconds) via an applicator with radialsymmetrical light distribution. Immediately, 2 weeks, 4 weeks, 8 weeks, and 16 weeks after irradiation, the ureters were X-rayed with contrast solution and prepared for light and transmission electron microscopy. For the parameters employed, no apparent morphological differences could be observed. Immediately, the central laser zone showed a transmural therrnonecrosis prevailed by cellular destruction, condensed ground substance and occlusion of most vascular lumina. Peripheral laser zones displayed urothelial vacuolations. Between 2 and 16 weeks, urothelial regeneration and ingrowth of granulation tissue caused a luminal stenosis or occlusion followed by transformation into scar tissue. In some peripheral laser zones, a hydroureter with marked luminal dilatation developed. We conclude that the ureter is occluded if the expanding force of the growing scar tissue exceeds the hydrostatic pressure of the obstructed urine. A laser occlusion of rectourogenital fistulae will be easier to achieve since fistula occlusion does not entail an obstruction of the urine flow