A comparison of radiant and circulating space heaters in farm dwellings

This bulletin is based on a thesis submitted by Mr. Phillips to the Graduate Faculty of the University of Missouri in partial fulfillment of the requirements for the degree of Master of Science in Agricultural Engineering--P. [3].Digitized 2007 AES.Includes bibliographical references

Photophysics of azobenzene constrained in a UiO metal‐organic framework: effects of pressure, solvation and dynamic disorder

Photophysical studies of chromophoric linkers in metal–organic frameworks (MOFs) are undertaken commonly in the context of sensing applications, in search of readily observable changes of optical properties in response to external stimuli. The advantages of the MOF construct as a platform for investigating fundamental photophysical behaviour have been somewhat overlooked. The linker framework offers a unique environment in which the chromophore is geometrically constrained and its structure can be determined crystallographically, but it exists in spatial isolation, unperturbed by inter‐chromophore interactions. Furthermore, high‐pressure studies enable the photophysical consequences of controlled, incremental changes in local environment or conformation to be observed and correlated with structural data. This approach is demonstrated in the present study of the trans‐azobenzene chromophore, constrained in the form of the 4,4’‐azobenzenedicarboxylate (abdc) linker, in a UiO topology framework. Previously unobserved effects of pressure‐induced solvation and conformational distortion on the lowest energy, nπ* transition are reported, and interpreted the light of crystallographic data. It was found that trans‐azobenzene remains non‐fluorescent (with a quantum yield less than 10(−4)) despite the prevention of trans‐cis isomerization by the constraining MOF structure. We propose that efficient non‐radiative decay is mediated by the local, pedal‐like twisting of the azo group that is evident as dynamic disorder in the crystal structure

Heating rural homes with space heaters

Cover title.Includes bibliographical references

Spin correlations in Ca3Co2O6: A polarised-neutron diffraction and Monte Carlo study

We present polarised-neutron diffraction measurements of the Ising-like spin-chain compound Ca3Co2O6 above and below the magnetic ordering temperature TN. Below TN, a clear evolution from a single-phase spin-density wave (SDW) structure to a mixture of SDW and commensurate antiferromagnet (CAFM) structures is observed on cooling. For a rapidly-cooled sample, the majority phase at low temperature is the SDW, while if the cooling is performed sufficiently slowly, then the SDW and the CAFM structure coexist between 1.5 and 10 K. Above TN, we use Monte Carlo methods to analyse the magnetic diffuse scattering data. We show that both intra- and inter-chain correlations persist above TN, but are essentially decoupled. Intra-chain correlations resemble the ferromagnetic Ising model, while inter-chain correlations resemble the frustrated triangular-lattice antiferromagnet. Using previously-published bulk property measurements and our neutron diffraction data, we obtain values of the ferromagnetic and antiferromagnetic exchange interactions and the single-ion anisotropy.Comment: 10 pages, 7 figure

Wideband TV white space transceiver design and implementation

For transceivers operating in television white space (TVWS), frequency agility and strict spectral mask fulfilments are vital. In the UK, TVWS covers a 320 MHz wide frequency band in the UHF range, and the aim of this paper is to present a wideband digital up- and down converter for this scenario. Sampling at radio frequency (RF), a two stage digital conversion is presented, which consists of a polyphase filter for implicit upsampling and decimation, and a filter bank-based multicarrier approach to resolve the 8MHz channels within the TVWS band. We demonstrate that the up- and down-conversion of 40 such channels is hardly more costly than that of a single channel. Appropriate filter design can satisfy the mandated spectral mask and control the reconstruction error. An FPGA implementation is discussed, capable of running the wideband transceiver on a single Virtex-7 device with sufficient word length to preserve the spectral mask requirements of the system

D-term Inflation in Superstring Theories

An inflationary stage dominated by a $D$-term avoids the slow-roll problem of inflation in supergravity and may emerge in theories with a non-anomalous or anomalous U(1) gauge symmetry. The most intriguing and commonly invoked possibility is that the Fayet-Iliopoulos $D$-term triggering inflation is the one emerging in superstring theories. We discuss the complications one has to face when trying to build up a successful $D$-term inflationary scenario in superstring models. In particular, we show that the ``vacuum shifting'' phenomenon of string theories is usually very efficient even in the early Universe, thus preventing inflation from taking place. On the other hand, when $D$-term inflation is free to occur, the presence of a plethora of fields and several non-anomalous additional abelian symmetries in string theories may help in reconciling the value of the Fayet-Iliopoulos $D$-term required by the COBE normalization with the value predicted by string theories. We also show that in superstring $D$-term inflation gravitinos are likely to pose no cosmological problem.Comment: 19 pages, LaTeX fil