801 research outputs found
The Flower-Like Hierarchical Architectures Assembled from Aniline Oligomers
The flower-like hierarchical architectures assembled from aniline oligomers by a template-free method
are reported. They are important because of their close relation to a conducting polymer, polyaniline. Their
formation process is ascribed to the self-assembly of oligoanilines under non-covalent interactions, such as
hydrogen bonding, hydrophobic forces, and π–π stacking. The model of directional growth is offered to explain the formation of petal-like objects and, subsequently, flowers. In order to investigate the chemical
structure of the oligomers, a series of characterizations have been carried out, such as UV–visible, Fourier-transform infrared and Raman spectroscopies. Based on the results of characterization methods, a formation mechanism of the aniline oligomers and their self-assembly are proposed.
When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3484
The Formation of Oligoaniline Microspheres in Alkaline Media
Aniline oligomers are generally believed to be responsible for the self-assembly that guides the growth
of polyaniline nanostructures. The oxidations of aniline with ammonium peroxydisulfate, which are started
and finished above pH 2.5, produce aniline oligomers only. Under alkaline conditions, oligoaniline microspheres spheres are formed as the dominating morphology. They will be potentially useful in applications that do
not require conductivity, such as in electrorheology, corrosion protection, as ionic conductors or catalyst
supports. Aniline oligomers prepared at alkaline conditions as microspheres have been studied by UV–Vis,
infrared and Raman spectroscopies in the combination with optical and electron microscopic techniques.
When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3483
Finsler geometry on higher order tensor fields and applications to high angular resolution diffusion imaging.
We study 3D-multidirectional images, using Finsler geometry. The application considered here is in medical image analysis, specifically in High Angular Resolution Diffusion Imaging (HARDI) (Tuch et al. in Magn. Reson. Med. 48(6):1358–1372, 2004) of the brain. The goal is to reveal the architecture of the neural fibers in brain white matter. To the variety of existing techniques, we wish to add novel approaches that exploit differential geometry and tensor calculus. In Diffusion Tensor Imaging (DTI), the diffusion of water is modeled by a symmetric positive definite second order tensor, leading naturally to a Riemannian geometric framework. A limitation is that it is based on the assumption that there exists a single dominant direction of fibers restricting the thermal motion of water molecules. Using HARDI data and higher order tensor models, we can extract multiple relevant directions, and Finsler geometry provides the natural geometric generalization appropriate for multi-fiber analysis. In this paper we provide an exact criterion to determine whether a spherical function satisfies the strong convexity criterion essential for a Finsler norm. We also show a novel fiber tracking method in Finsler setting. Our model incorporates a scale parameter, which can be beneficial in view of the noisy nature of the data. We demonstrate our methods on analytic as well as simulated and real HARDI data
NMR Time Reversal Experiments in Highly Polarised Liquid 3He-4He Mixtures
Long-range magnetic interactions in highly magnetised liquids
(laser-polarised 3He-4He dilute mixtures at 1 K in our experiment) introduce a
significant non-linear and non-local contribution to the evolution of nuclear
magnetisation that leads to instabilities during free precession. We recently
demonstrated that a multi-echo NMR sequence, based on the magic sandwich pulse
scheme developed for solid-state NMR, can be used to stabilise the
magnetisation against the effect of distant dipolar fields. Here, we report
investigations of echo attenuation in an applied field gradient that show the
potential of this NMR sequence for spin diffusion measurements at high
magnetisation densities.Comment: Accepted for publication in the Journal of Low Temperature Physic
Measuring surface-area-to-volume ratios in soft porous materials using laser-polarized xenon interphase exchange NMR
We demonstrate a minimally invasive nuclear magnetic resonance (NMR)
technique that enables determination of the surface-area-to-volume ratio (S/V)
of soft porous materials from measurements of the diffusive exchange of
laser-polarized 129Xe between gas in the pore space and 129Xe dissolved in the
solid phase. We apply this NMR technique to porous polymer samples and find
approximate agreement with destructive stereological measurements of S/V
obtained with optical confocal microscopy. Potential applications of
laser-polarized xenon interphase exchange NMR include measurements of in vivo
lung function in humans and characterization of gas chromatography columns.Comment: 14 pages of text, 4 figure
Classical Limit of Demagnetization in a Field Gradient
We calculate the rate of decrease of the expectation value of the transverse
component of spin for spin-1/2 particles in a magnetic field with a spatial
gradient, to determine the conditions under which a previous classical
description is valid. A density matrix treatment is required for two reasons.
The first arises because the particles initially are not in a pure state due to
thermal motion. The second reason is that each particle interacts with the
magnetic field and the other particles, with the latter taken to be via a
2-body central force. The equations for the 1-body Wigner distribution
functions are written in a general manner, and the places where quantum
mechanical effects can play a role are identified. One that may not have been
considered previously concerns the momentum associated with the magnetic field
gradient, which is proportional to the time integral of the gradient. Its
relative magnitude compared with the important momenta in the problem is a
significant parameter, and if their ratio is not small some non-classical
effects contribute to the solution.
Assuming the field gradient is sufficiently small, and a number of other
inequalities are satisfied involving the mean wavelength, range of the force,
and the mean separation between particles, we solve the integro- partial
differential equations for the Wigner functions to second order in the strength
of the gradient. When the same reasoning is applied to a different problem with
no field gradient, but having instead a gradient to the z-component of
polarization, the connection with the diffusion coefficient is established, and
we find agreement with the classical result for the rate of decrease of the
transverse component of magnetization.Comment: 22 pages, no figure
PAID TO PUMP: How a tax credit could discourage conservation of the High Plains Aquifer
In 1965’s United States v. Shurbet case, an irrigator from Texas asserted his claim for a depletion tax deduction for groundwater pumped from the High Plains Aquifer. He argued that the unique conditions of the southern High Plains region - a plateau where the shallow aquifer is recharged only through precipitation at a slow rate - meant the groundwater resource would be depleted in time. The state argued that groundwater was not fundamentally an exhaustible natural deposit, but the Supreme Court concluded the tax deduction was appropriate given the “peculiar” conditions in the area. It was stated the decision was not meant to establish a precedent regarding cost depletion of groundwater. The findings of the Shurbet case were intended to be limited to the southern High Plains region. However, in a 1980 lawsuit against the IRS, the Gigot brothers of Kansas sought to expand the deduction to allow depletion of the aquifer beneath their 30,000 acre farm in Kansas. The case was settled in the district court with a ruling allowing the brothers’ deductions to continue, thereby extending the Shurbet decision to include all landowners extracting from the approximately 174,000 square miles of land overlying the High Plains Aquifer. Currently, the estimated value of the credit is highest in parts of northern Texas, eastern Colorado, western Kansas, and south central Nebraska
Formation of convective cells in the scrape-off layer of the CASTOR tokamak
Understanding of the scrape-off layer (SOL) physics in tokamaks requires
diagnostics with sufficient temporal and spatial resolution. This contribution
describes results of experiments performed in the SOL of the CASTOR tokamak
(R=40 cm, a = 6 cm) by means of a ring of 124 Langmuir probes surrounding the
whole poloidal cross section. The individual probes measure either the ion
saturation current of the floating potential with the spatial resolution up to
3 mm. Experiments are performed in a particular magnetic configuration,
characterized by a long parallel connection length in the SOL, L_par ~q2piR. We
report on measurements in discharges, where the edge electric field is modified
by inserting a biased electrode into the edge plasma. In particular, a complex
picture is observed, if the biased electrode is located inside the SOL. The
poloidal distribution of the floating potential appears to be strongly
non-uniform at biasing. The peaks of potential are observed at particular
poloidal angles. This is interpreted as formation of a biased flux tube, which
emanates from the electrode along the magnetic field lines and snakes q times
around the torus. The resulting electric field in the SOL is 2-dimensional,
having the radial as well as the poloidal component. It is demonstrated that
the poloidal electric field E_pol convects the edge plasma radially due to the
E_pol x B_T drift either inward or outward depending on its sign. The
convective particle flux is by two orders of magnitude larger than the
fluctuation-induced one and consequently dominates.Comment: 12th International Congress on Plasma Physics, 25-29 October 2004,
Nice (France
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