Laboratory Measurement of Volatile Ice Vapor Pressures with a Quartz Crystal Microbalance

Nitrogen, carbon monoxide, and methane are key materials in the far outer Solar System where their high volatility enables them to sublimate, potentially driving activity at very low temperatures. Knowledge of their vapor pressures and latent heats of sublimation at relevant temperatures is needed to model the processes involved. We describe a method for using a quartz crystal microbalance to measure the sublimation flux of these volatile ices in the free molecular flow regime, accounting for the simultaneous sublimation from and condensation onto the quartz crystal to derive vapor pressures and latent heats of sublimation. We find vapor pressures to be somewhat lower than previous estimates in literature, with carbon monoxide being the most discrepant of the three species, almost an order of magnitude lower than had been thought. These results have important implications across a variety of astrophysical and planetary environments

29P/Schwassmann-Wachmann: A Rosetta Stone for Amorphous Water Ice and CO <-> CO2 Conversion in Centaurs and Comets?

Centaur 29P/Schwassmann-Wachmann 1 (SW1) is a highly active object orbiting in the transitional Gateway region (Sarid et al. 2019) between the Centaur and Jupiter Family Comet regions. SW1 is unique among the Centaurs in that it experiences quasi-regular major outbursts and produces CO emission continuously; however, the source of the CO is unclear. We argue that due to its very large size (approx. 32 km radius), SW1 is likely still responding, via amorphous water ice (AWI) conversion to crystalline water ice (CWI), to the rapid change in its external thermal environment produced by its dynamical migration from the Kuiper belt to the Gateway Region at the inner edge of the Centaur region at 6 au. It is this conversion process that is the source of the abundant CO and dust released from the object during its quiescent and outburst phases. If correct, these arguments have a number of important predictions testable via remote sensing and in situ spacecraft characterization, including: the quick release on Myr timescales of CO from AWI conversion for any few km-scale scattered disk KBO transiting into the inner system; that to date SW1 has only converted between 50 to 65% of its nuclear AWI to CWI; that volume changes upon AWI conversion could have caused subsidence and cave-ins, but not significant mass wasting or crater loss on SW1; that SW1s coma should contain abundant amounts of CWI CO2-rich icy dust particles; and that when SW1 transits into the inner system within the next 10,000 years, it will be a very different kind of JFC comet.Comment: 29 Pages, 3 Figures, 2 Tables, accepted 16-Sept-2022 by the Planetary Science Journal Corrected proof version 26-Oct-202

The Science of Sungrazers, Sunskirters, and Other Near-Sun Comets

This review addresses our current understanding of comets that venture close to the Sun, and are hence exposed to much more extreme conditions than comets that are typically studied from Earth. The extreme solar heating and plasma environments that these objects encounter change many aspects of their behaviour, thus yielding valuable information on both the comets themselves that complements other data we have on primitive solar system bodies, as well as on the near-solar environment which they traverse. We propose clear definitions for these comets: We use the term near-Sun comets to encompass all objects that pass sunward of the perihelion distance of planet Mercury (0.307 AU). Sunskirters are defined as objects that pass within 33 solar radii of the Sun’s centre, equal to half of Mercury’s perihelion distance, and the commonly-used phrase sungrazers to be objects that reach perihelion within 3.45 solar radii, i.e. the fluid Roche limit. Finally, comets with orbits that intersect the solar photosphere are termed sundivers. We summarize past studies of these objects, as well as the instruments and facilities used to study them, including space-based platforms that have led to a recent revolution in the quantity and quality of relevant observations. Relevant comet populations are described, including the Kreutz, Marsden, Kracht, and Meyer groups, near-Sun asteroids, and a brief discussion of their origins. The importance of light curves and the clues they provide on cometary composition are emphasized, together with what information has been gleaned about nucleus parameters, including the sizes and masses of objects and their families, and their tensile strengths. The physical processes occurring at these objects are considered in some detail, including the disruption of nuclei, sublimation, and ionisation, and we consider the mass, momentum, and energy loss of comets in the corona and those that venture to lower altitudes. The different components of comae and tails are described, including dust, neutral and ionised gases, their chemical reactions, and their contributions to the near-Sun environment. Comet-solar wind interactions are discussed, including the use of comets as probes of solar wind and coronal conditions in their vicinities. We address the relevance of work on comets near the Sun to similar objects orbiting other stars, and conclude with a discussion of future directions for the field and the planned ground- and space-based facilities that will allow us to address those science topics

Titan: Earth-like on the outside, ocean world on the inside

Thanks to the Cassini-Huygens mission, Titan, the pale orange dot of Pioneer and Voyager encounters, has been revealed to be a dynamic, hydrologically shaped, organic-rich ocean world offering unparalleled opportunities to explore prebiotic chemistry. And while Cassini-Huygens revolutionized our understanding of each of the three "layers" of Titan-the atmosphere, the surface, and the interior-we are only beginning to hypothesize how these realms interact. In this paper, we summarize the current state of Titan knowledge and discuss how future exploration of Titan would address some of the next decade's most compelling planetary science questions. We also demonstrate why exploring Titan, both with and beyond the Dragonfly New Frontiers mission, is a necessary and complementary component of an Ocean Worlds Program that seeks to understand whether habitable environments exist elsewhere in our solar system

Optical Constants of Ices Important to Planetary Science From Laboratory Reflectance Spectroscopy

Laboratory-derived optical constants are essential for identifying ices and measuring their relative abundances on Solar System objects. Almost all optical constants of ices important to planetary science come from experiments with transmission geometries. Here, we describe our new experimental setup and the modification of an iterative algorithm in the literature to measure the optical constants of ices from experiments with reflectance geometries. We apply our techniques to CH4 ice and H2O ice samples and find good agreement between our values and those in the literature, except for one CH4 band in the literature that likely suffers from saturation. The work we present here demonstrates that labs with reflectance geometries can generate optical constants essential for the proper analysis of near- and mid-infrared spectra of outer Solar System objects such as those obtained with the James Webb Space Telescope

Optical Constants of Ices Important to Planetary Science From Laboratory Reflectance Spectroscopy

Laboratory-derived optical constants are essential for identifying ices and measuring their relative abundances on Solar System objects. Almost all optical constants of ices important to planetary science come from experiments with transmission geometries. Here, we describe our new experimental setup and the modification of an iterative algorithm in the literature to measure the optical constants of ices from experiments with reflectance geometries. We apply our techniques to CH4 ice and H2O ice samples and find good agreement between our values and those in the literature, except for one CH4 band in the literature that likely suffers from saturation. The work we present here demonstrates that labs with reflectance geometries can generate optical constants essential for the proper analysis of near- and mid-infrared spectra of outer Solar System objects such as those obtained with the James Webb Space Telescope

Science Opportunities offered by Mercury's Ice-Bearing Polar Deposits

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