Anomalies of LF signal during seismic activity in November?December 2004

International audienceA signal transmitted by Japan Time Standard LF station (40 kHz, Fukushima prefecture) and recorded in Petropavlovsk-Kamchatski (Russia) is analyzed during a time interval from 1 July 2004 till 24 January 2005. This interval is characterized by quiet seismic conditions up to the beginning of November, but rather strong seismic activity occurs in November and December not far from Hokkaido (Japan) and in the region of northern Kuril Islands. There were three series of earthquakes with M=5.6?7.1 in a zone of sensitivity of our wave path during two months. Nighttime "bay-like" phase and amplitude anomalies of the LF signal are observed several days before and during every series of earthquakes. During the whole period of seismic activity a significant shift in terminator times is also evident. The spectrum of LF seismo-induced anomalies shows a clear increase for the period of about 25 min

Effectiveness of legislative changes obligating notification of prolonged sickness absence and assessment of remaining work ability on return to work and work participation : a natural experiment in Finland

Objectives Policies have been introduced to reduce sickness absence, but their effectiveness is largely unknown. In a natural experiment, we examined effects of legislative changes on return to work and work participation. Methods The source population consisted of up to 72164 Finnish public sector employees with a permanent job contract in 2008-2011 (before) and in 2013-2014 (after). We used employees with a continuous sickness absence of at least 30 calendar-days (n=5708-6393), 60 compensated days (n=1481-1655) and 90 compensated days (n=766-932). We examined sustainable return to work (a minimum of 28 consecutive working days) with survival analysis as well as monthly work participation after a sickness absence, and annual gain in work participation after the intervention, using trajectory analyses. Results Sustainable return to work after 60days of sickness absence occurred earlier after the legislative changes (p value 0.017), although the effect reduced towards the end of the follow-up. There were no differences in return to work after a 30 or 90days of sickness absence. The largest annual gain, postintervention versus preintervention, in monthly work participation was observed among employees with 60days of sickness absence and was 230.9 person-years/10000 employees. The corresponding annual gains among those with 30days and 90days of sickness absence were 51.8 and 39.6, respectively. Conclusions Our findings suggest that the legislative changes, obligating early notification of prolonged sickness absences as well as assessment of remaining work ability and possibilities to continue working, may enhance sustainable return to work in the short term. Other measures will be needed to enhance work participation, especially in the long term.Peer reviewe

Water-soluble hybrid materials based on {Mo₆X₈}⁴⁺ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate

Development of water-soluble forms of octahedral molybdenum clusters {Mo₆X₈}⁴⁺ (X = Cl, Br, I) is strongly motivated by the tremendous potential that these complexes have for biological applications, namely as agents for bioimaging and photodynamic therapy. In these work we report the first water-soluble hybrid materials, which represent sodium polystyrene sulfonate doped by molybdenum clusters, and evaluation of their photophysical and biological properties (dark and photoinduced cytotoxicity and cellular uptake) with the use of cervical cancer (HeLa) and human epidermoid larynx carcinoma (Hep-2) cell-lines as models

Preseismic ULF effectand possible interpretation

We present the results of ULF magnetic field observation at Karimshino station (Kamchatka, Russia). Using a case study we discovered an effect of suppression of ULF intensity about 2-6 days before rather strong and isolated seismic shocks (magnitude M = 4.6-6.6). It is revealed for nighttime and the horizontal component of ULF field (G) in the frequency range 0.01-0.1 Hz. Then we prove the reliability of the effect by computed correlation between G (or 1/G) and especially calculated seismic indexes Ks for the rather long period of observation from June 2000 to November 2001. Our recent data confirm the validity of the effect. We show here a similar result during a period of frequent strong seismic activity in April-May 2002. It is highly probable that the effect observed is connected with the increase in plasma density perturbations inside the ionosphere, which are induced by preseismic water and gas release at the ground surface and following energy transportation into the ionosphere by atmospheric gravity waves. Two models are discussed and computed: the first is a decrease of penetration coefficient of Alfven waves from the magnetosphere due to a turbulent increase in effective Pedersen conductivity in the ionosphere, and the second is a change in wave number (k) distribution of source ionospheric turbulence. One of the mechanisms or both could be responsible for the observed 2-3 times suppression of ULF magnetic field noise at the ground

Anomalies in VLF radio signals prior the Abruzzo earthquake (M=6.3) on 6 April 2009

Abstract. The VLF/LF radio signals method for studying preseimic activity is applied to the Abruzzo earthquake (M=6.3, 6 April 2009). The data collected by three receivers located in Moscow (Russia), Graz (Austria) and Bari (Italy) at about 3000 km, 1000 km and 500 km from the epicenter were used. The signals received from the Sardinia (20.27 kHz) and the Sicily (45.9 kHz) transmitters, both located in Italy, were compared with those received from the Iceland (37.5 kHz), the Great Britain (19.58 kHz) and the Germany (23.4 kHz) transmitters. The propagation paths of the two Italian transmitters cross the epicentral area (seismic paths) unlike the paths of the other three signals (control paths). Using two different analyses, that are the study of the night-time signal and the research of shifts in the evening terminator times, clear anomalies were revealed 2–8 days before the occurrence of the Abruzzo earthquake in the seismic paths, while no anomalies have been found in the control paths

Possible seismo-ionosphere perturbations revealed by VLF signals collected on ground and on a satellite

The results of the monitoring of three VLF/LF signals collected in Petropavlovsk station (Kamchatka, Russia) and one VLF signal collected on board of the DEMETER French satellite are presented. Two periods of the seismic activity occurred in the Japan-Kamchatka area during November–December 2004 and July–September 2005 were investigated and the earthquakes with M≥6.0 in the Japan-Kamchatka area, located inside one or more of the third Fresnel zones of the three radio paths were considered. The ground data were analysed using residual signal of phase <i>dP</i> or of amplitude <i>dA</i>, defined as the difference between the signal and the average of few quiet days (±5 days) immediately preceding or following the current day. Also the satellite data were processed by a method based on the difference between the real signal and the reference one, but in order to obtain this last signal it was necessary to construct previously a model of the signal distribution over the selected area. The method consists: (a) in averaging all the data available in the considered region over a period characterized by low level seismicity, regardless of the global disturbances, in particular, of the magnetic activity; (b) in computing a polynomial expression for the surface as a function of the longitude and the latitude. The model well describes the real data in condition of their completeness and in absence of magnetic storms or seismic forcing. In the quoted periods of seismic activity clear anomalies both in the ground and in satellite data were revealed. The influence of the geomagnetic activity cannot to be excluded, but the seismic forcing seems more probable

A comparative study of hydrophilic phosphine hexanuclear rhenium cluster complexes’ toxicity

Octahedral rhenium cluster compound Na2H8[{Re6Se8}(P(C2H4CONH2)(C2H4COO)2)6] has recently emerged as a very promising X-ray contrast agent for biomedical applications. However, the synthesis of this compound is rather challenging due to difficulty to control the hydrolysis of initial P(C2H4CN)3 ligand during the reaction process. Therefore, in this report we compare the in vitro and in vivo toxicity of Na2H8[{Re6Se8}(P(C2H4CONH2)(C2H4COO)2)6] with those of related compounds featuring fully hydrolysed form of the phosphine ligand, namely Na2H14[{Re6Q8}(P(C2H4COO)3)6] (Q = S or Se). Our results demonstrate that cytotoxicity and acute in vivo toxicity of the complex Na2H8[{Re6Se8}(P(C2H4CONH2)(C2H4COO)2)6] solutions were considerably lower than those of compounds with fully hydrolysed ligand P(C2H4COOH)3. Such behavior can be explained by the higher osmolality of Na2H14[{Re6Q8}(P(C2H4COO)3)6] versus Na2H8[{Re6Se8}(P(C2H4CONH2)(C2H4COO)2)6]

Mild template synthesis of a copper(II)-containing macrocyclic compound with 4,4,6-trimethyl-2,3,7,8-tetraazanonen-6-dithiohydrazide-1,9 in a gelatin-immbolized matrix

The complexing processes in the triple copper(II)-thiocarbohydrazide-propanone system taking place in a copper(II) hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous-alkaline solutions (pH∼12), containing thiocarbohydrazide and propanone, have been studied. Template synthesis leading to a macrocyclic coordination compound with the tetradentate N,N,S,S-donor ligand, (4,4,6-trimethyl-2,3,7,8-tetraazanonen-6-dithiohydrazide-1,9), occurs under these specific conditions when thiocarbohydrazide and propanone are the ligand synthons