Inhibitive effect of sodium (E)-4-(4-nitrobenzylidenamino) benzoate on the corrosion of some metals in sodium chloride solution

The inhibition performance of a novel anionic carboxylic Schiff base, sodium (E)-4-(4-nitrobenzylideneamino)benzoate (SNBB), was investigated for various metals, namely low carbon steel F111, pure iron and copper, in neutral 10 mM NaCl solution. Potentiodynamic polarization, scanning vibrating electrode technique (SVET), quantum chemical (QC) calculation, and molecular dynamics (MD) simulation were employed. The potentiodynamic polarization data showed that SNBB acts as an effective corrosion inhibitor for both iron and F111 steel, but it is not effective for the copper. In situ spatially-resolved SVET maps evidenced a major change in surface reactivity for Fe and F111 steel immersed in 10 mM aqueous solution in the absence and in the presence of SNBB. Featureless ionic current density distributions were recorded in the presence of SNBB at both their spontaneous open circuit potential (OCP) and under mild anodic polarization conditions, while major ionic flows were monitored above the metals in the absence of SNBB. On the basis of computer simulations, it is proposed that SNBB produces a stable chelate film on iron and steel surfaces that accounts for the good corrosion inhibition efficiency observed. The different inhibition efficiencies of SNBB molecules on the iron and copper was attributed to the special chemical structure of SNBB molecule and its different chelation ability with the released metal ions on the metal surface. The QC calculations also confirmed the high corrosion inhibition efficiency of SNBB. The MD simulation indicated higher binding energy of SNBB on iron surface compared to that of copper surface. The interaction mode of SNBB on iron and F111 steel surfaces corresponds to a mixed chemical and physical adsorption, and it obeys the Langmuir isother

In Vitro Microleakage of Class V Composite Restorations in Use of Three Adhesive Systems

Background and Aim: Microleakage is a drawback of composite restorations and it is more noticeable in dentinal walls. Despite advances in dentin bonding agents, no adhesive can completely eliminate microleakage and provide a hermetic seal. This study aimed to compare microleakage of three resin bonding agents namely a universal adhesive, two-step self-etch system and two-step total-etch system. Materials and Methods: This in vitro, experimental study was conducted on 68 human molars. Class V cavities were prepared in the buccal or lingual surfaces of the teeth with occlusal margins in the enamel and gingival margins in dentin. The teeth were then randomly divided into four groups of 17. Group A: Adper Single Bond 2, group B: Clearfil SE Bond, group C: Scotchbond Universal adhesive (self-etch) and group D: Scotchbond Universal adhesive (total-etch). The teeth were then restored using different bonding agents and a microhybrid composite resin. The specimens were then subjected to 1000 thermal cycles between 5-55°C. The entire restoration surface except for 1mm around the margins was coated with nail varnish. The teeth were immersed in 2% methylene blue for 24 hours and sectioned longitudinally in a buccolingual direction and observed under a stereomicroscope to determine microleakage. Microleakage in use of the three bonding agents was compared using the Kruskal Wallis test (P<0.05). Results: Based on the Kruskal Wallis test, no significant difference was noted in enamel and dentin margins among different adhesives but the enamel margin showed less microleakage than the dentin margin. Conclusion: Different adhesive systems tested in this study showed similar microleakage at the enamel and dentinal margins