Automatic Reassembly Method of 3D Thin-wall Fragments Based on Derivative Dynamic Time Warping

In order to address the automatic virtual reassembling of 3D thin-wall fragments, this paper proposes a 3D fragment reassembly method based on derivative dynamic time warping. Firstly, a calculation method of discrete curvature and torsion is designed to solve the difficulty of calculating curvature and torsion of discrete data points and eliminate effectively the noise interferences in the calculation process. Then, it takes curvature and torsion as the feature descriptors of the curve, searches the candidate matching line segments by the derivative dynamic time warping (DDTW) method with the feature descriptors, and records the positions of the starting and ending points of each candidate matching segment. After that, it designs a voting mechanism with the geometric invariant as the constraint information to select further the optimal matching line segments. Finally, it adopts the least squares method to estimate the rotation and transformation matrices and uses the iterative closest point (ICP) method to complete the reassembly of fragments. The experimental results show that the reassembly error is less than 1mm and that the reassembly effect is good. The method can solve the 3D curve matching in case there are partial feature defects, and can achieve the virtual restoration of the broken thin-wall fragment model quickly and effectively

Fabrication and Properties of (Ti, W, Mo, Nb, Ta)(C, N)-Co-Ni Cermets

Abstract(#br)Fine single-phase (Ti, W, Mo, Nb, Ta)(C, N) solid solution powders were synthesized through the carbothermal reduction method. (Ti, W, Mo, Nb, Ta)(C, N)-Co-Ni cermets were fabricated via vacuum sintering.Micrographs of powders and microstructures of the cermets were observed using transmission electron microscopy and scanning electron microscopy in combination with energy-dispersive spectroscopy. Phase compositions were investigated using x-ray diffraction. The C and N contents were measured using elemental analysis (CHNS/O). The optimized conditions for the synthesis process of single-phase (Ti, W, Mo, Nb, Ta)(C, N) solid solution powders with high nitrogen content were 1500 °C for 2 h under a 2 kPa nitrogen atmosphere. Under such conditions, the particle size of the..

Fluorescence of functionalized graphene quantum dots prepared from infrared-assisted pyrolysis of citric acid and urea

Abstract(#br)This paper reports an efficient fabrication of N-doped graphene quantum dots (GQDs) showing controllable chemical and fluorescence (FL) properties through infrared carbonization (IRC) of citric acid and urea. The GQDs prefer to form an equilibrium shapes of circle with an average particle size ranged from 5 to 10 nm. The N/C atomic ratio in GQDs can be precisely tailored in a range from 21.6 to 49.6 at.% by simply controlling the weight ratio of citric acid to urea. With increasing the urea content, the GQDs not only contain N-doped graphene but also incorporate with crystalline cyanuric acid, forming a binary crystallinity. The quantum yield of 22.2% is achieved by N-doped GQDs, prepared from the IRC synthesis of chemical precursor at the citric acid/urea at 3:1. Excessive N and cyanuric acid can lead to FL quenching, red shift and wide spectral distribution. The design of GQDs possesses a multiple chromophoric band-gap structure, originated from the presence of cyanuric acid, defect-related emissive traps, and functional group distributions. This work offers an effective and inspiring approach to engineering both chemical compositions and unique crystalline structures of GQDs, and will therefore facilitate their fundamental research and applications to optical, sensing, energy and biological fields

Electrocatalytic Oxidation of Glucose on Boron and Nitrogen Codoped Graphene Quantum Dot Electrodes in Alkali Media

A novel solvothermal technique has been developed in the presence of C/N/B precursor for synthesizing B-N-coped graphene quantum dots (GQDs) as non-metal electrocatalysts towards the catalytic glucose oxidation reaction (GOR). Both N-doped GQD and B-N-codoped GQD particles (~4.0 nm) possess a similar oxidation and amidation level. The B-N-codoped GQD contains a B/C ratio of 3.16 at.%, where the B dopants were formed through different bonding types (i.e., N‒B, C‒B, BC2O, and BCO2) inserted into or decorated on the GQDs. The cyclic voltammetry measurement revealed that the catalytic activity of B-N-codoped GQD catalyst is significantly higher compared to the N-doped GQDs (~20% increase). It was also shown that the GOR activity was substantially enhanced due to the synergistic effect of B and N dopants within the GQD catalysts. Based on the analysis of Tafel plots, the B-N-codoped-GQD catalyst electrode displays an ultra-high exchange current density along with a reduced Tafel slope. The application of B-N-codoped GQD electrodes significantly enhances the catalytic activity and results in facile reaction kinetics towards the glucose oxidation reaction. Accordingly, the novel design of GQD catalyst demonstrated in this work sets the stage for designing inexpensive GQD-based catalysts as an alternative for precious metal catalysts commonly used in bio-sensors, fuel cells, and other electrochemical devices