1,463 research outputs found
N′-[(E)-4-ChloroÂbenzylÂidene]-2-(4-isobutylÂphenÂyl)propanohydrazide
The asymmetric unit of title compound, C20H23ClN2O, consists of two crystallographically independent molÂecules (A and B) in which the orientations of the 4-isobutylÂphenyl units are different. The isobutyl group of molÂecule B is disordered over two positions with occupancies of 0.850 (5) and 0.150 (5). The dihedral angle between the two benzene rings is 88.70 (9)° in molÂecule A and 89.38 (9)° in molÂecule B. The independent molÂecules are linked together into chains along [100] by N—H⋯O and C—H⋯O hydrogen bonds, and by C—H⋯π interÂactions. In the chain, N—H⋯O and C—H⋯O hydrogen bonds generate R
2
1(6) ring motifs. In addition, C—H⋯N hydrogen bonds are observed. The presence of pseudosymmetry in the structure suggests the higher symmetry space group Pbca but attempts to refine the structure in this space group resulted in high R (0.119) and wR (0.296) values
Polaron physics and crossover transition in magnetite probed by pressure-dependent infrared spectroscopy
The optical properties of magnetite at room temperature were studied by
infrared reflectivity measurements as a function of pressure up to 8 GPa. The
optical conductivity spectrum consists of a Drude term, two sharp phonon modes,
a far-infrared band at around 600 cm, and a pronounced mid-infrared
absorption band. With increasing pressure both absorption bands shift to lower
frequencies and the phonon modes harden in a linear fashion. Based on the shape
of the MIR band, the temperature dependence of the dc transport data, and the
occurrence of the far-infrared band in the optical conductivity spectrum the
polaronic coupling strength in magnetite at room temperature should be
classified as intermediate. For the lower-energy phonon mode an abrupt increase
of the linear pressure coefficient occurs at around 6 GPa, which could be
attributed to minor alterations of the charge distribution among the different
Fe sites.Comment: 7 pages, 7 figure
Spin dynamics in the low-dimensional magnet TiOCl
We present detailed ESR investigations on single crystals of the
low-dimensional quantum magnet TiOCl. The anisotropy of the g-factor indicates
a stable orbital configuration below room temperature, and allows to estimate
the energy of the first excited state as 0.3(1) eV ruling out a possible
degeneracy of the orbital ground state. Moreover, we discuss the possible spin
relaxation mechanisms in TiOCl and analyze the angular and temperature
dependence of the linewidth up to 250 K in terms of anisotropic exchange
interactions. Towards higher temperatures an exponential increase of the
linewidth is observed, indicating an additional relaxation mechanism.Comment: 10 pages, 8 figures; accepted for publication in Phys. Rev.
Two-Spinon and Orbital Excitations of the Spin-Peierls System TiOCl
We combine high-resolution resonant inelastic x-ray scattering with cluster
calculations utilizing a recently derived effective magnetic scattering
operator to analyze the polarization, excitation energy, and momentum dependent
excitation spectrum of the low-dimensional quantum magnet TiOCl in the range
expected for orbital and magnetic excitations (0 - 2.5 eV). Ti 3d orbital
excitations yield complete information on the temperature-dependent
crystal-field splitting. In the spin-Peierls phase we observe a dispersive
two-spinon excitation and estimate the inter- and intra-dimer magnetic exchange
coupling from a comparison to cluster calculations
Circular dichroism and bilayer splitting in the normal state of underdoped (Pb,Bi)Sr(CaY)CuO and overdoped (Pb,Bi)SrCaCuO
We report an ARPES investigation of the circular dichroism in the first
Brillouin zone (BZ) of under- and overdoped Pb-Bi2212 samples. We show that the
dichroism has opposite signs for bonding and antibonding components of the
bilayer-split CuO-band and is antisymmetric with respect to reflections in both
mirror planes parallel to the c-axis. Using this property of the energy and
momentum intensity distributions we prove the existence of the bilayer
splitting in the normal state of the underdoped compound and compare its value
with the splitting in overdoped sample. In agreement with previous studies the
magnitude of the interlayer coupling does not depend significantly on doping.
We also discuss possible origins of the observed dichroism.Comment: 4 RevTex pages, 4 EPS figure
Transit spectrophotometry of the exoplanet HD189733b. I. Searching for water but finding haze with HST NICMOS
We present Hubble Space Telescope near-infrared transit photometry of the
nearby hot-Jupiter HD189733b. The observations were taken with the NICMOS
instrument during five transits, with three transits executed with a narrowband
filter at 1.87 microns and two performed with a narrowband filter at 1.66
microns. Our observing strategy using narrowband filters is insensitive to the
usual HST intra-orbit and orbit-to-orbit measurement of systematic errors,
allowing us to accurately and robustly measure the near-IR wavelength
dependance of the planetary radius. Our measurements fail to reproduce the
Swain et al. absorption signature of atmospheric water below 2 microns at a
5-sigma confidence level. We measure a planet-to-star radius contrast of
0.15498+/-0.00035 at 1.66 microns and a contrast of 0.15517+/-0.00019 at 1.87
microns. Both of our near-IR planetary radii values are in excellent agreement
with the levels expected from Rayleigh scattering by sub-micron haze particles,
observed at optical wavelengths, indicating that upper-atmospheric haze still
dominates the near-IR transmission spectra over the absorption from gaseous
molecular species at least below 2 microns.Comment: 9 pages, 7 figures. Accepted for publication in A&
Laser ablation loading of a radiofrequency ion trap
The production of ions via laser ablation for the loading of radiofrequency
(RF) ion traps is investigated using a nitrogen laser with a maximum pulse
energy of 0.17 mJ and a peak intensity of about 250 MW/cm^2. A time-of-flight
mass spectrometer is used to measure the ion yield and the distribution of the
charge states. Singly charged ions of elements that are presently considered
for the use in optical clocks or quantum logic applications could be produced
from metallic samples at a rate of the order of magnitude 10^5 ions per pulse.
A linear Paul trap was loaded with Th+ ions produced by laser ablation. An
overall ion production and trapping efficiency of 10^-7 to 10^-6 was attained.
For ions injected individually, a dependence of the capture probability on the
phase of the RF field has been predicted. In the experiment this was not
observed, presumably because of collective effects within the ablation plume.Comment: submitted to Appl. Phys. B., special issue on ion trappin
Spectroscopic signatures of spin-charge separation in the quasi-one-dimensional organic conductor TTF-TCNQ
The electronic structure of the quasi-one-dimensional organic conductor
TTF-TCNQ is studied by angle-resolved photoelectron spectroscopy (ARPES). The
experimental spectra reveal significant discrepancies to band theory. We
demonstrate that the measured dispersions can be consistently mapped onto the
one-dimensional Hubbard model at finite doping. This interpretation is further
supported by a remarkable transfer of spectral weight as function of
temperature. The ARPES data thus show spectroscopic signatures of spin-charge
separation on an energy scale of the conduction band width.Comment: 4 pages, 4 figures; to appear in PR
Terahertz Conductivity at the Verwey Transition in Magnetite
The complex conductivity at the (Verwey) metal-insulator transition in
Fe_3O_4 has been investigated at THz and infrared frequencies. In the
insulating state, both the dynamic conductivity and the dielectric constant
reveal a power-law frequency dependence, the characteristic feature of hopping
conduction of localized charge carriers. The hopping process is limited to low
frequencies only, and a cutoff frequency nu_1 ~ 8 meV must be introduced for a
self-consistent description. On heating through the Verwey transition the
low-frequency dielectric constant abruptly decreases and becomes negative.
Together with the conductivity spectra this indicates a formation of a narrow
Drude-peak with a characteristic scattering rate of about 5 meV containing only
a small fraction of the available charge carriers. The spectra can be explained
assuming the transformation of the spectral weight from the hopping process to
the free-carrier conductivity. These results support an interpretation of
Verwey transition in magnetite as an insulator-semiconductor transition with
structure-induced changes in activation energy.Comment: 6 Pages, 3 Figure
HST PanCET program: A Cloudy Atmosphere for the promising JWST target WASP-101b
We present results from the first observations of the Hubble Space Telescope
(HST) Panchromatic Comparative Exoplanet Treasury (PanCET) program for
WASP-101b, a highly inflated hot Jupiter and one of the community targets
proposed for the James Webb Space Telescope (JWST) Early Release Science (ERS)
program. From a single HST Wide Field Camera 3 (WFC3) observation, we find that
the near-infrared transmission spectrum of WASP-101b contains no significant
HO absorption features and we rule out a clear atmosphere at 13{\sigma}.
Therefore, WASP-101b is not an optimum target for a JWST ERS program aimed at
observing strong molecular transmission features. We compare WASP-101b to the
well studied and nearly identical hot Jupiter WASP-31b. These twin planets show
similar temperature-pressure profiles and atmospheric features in the
near-infrared. We suggest exoplanets in the same parameter space as WASP-101b
and WASP-31b will also exhibit cloudy transmission spectral features. For
future HST exoplanet studies, our analysis also suggests that a lower count
limit needs to be exceeded per pixel on the detector in order to avoid unwanted
instrumental systematics.Comment: 7 pages, 4 figures, 1 table, Accepted to ApJ
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