Characterisation of a new Fast CPC and its application for atmospheric particle measurements

A new Fast CPC (FCPC) using butanol as working fluid has been built based on the setup described by Wang et al. (2002). In this study, we describe the new instrument. The functionality and stable operation of the FCPC in the laboratory, as well as under atmospheric conditions, is demonstrated. The counting efficiency was measured for three temperature differences between FCPC saturator and condenser, 25, 27, and 29 K, subsequently resulting in a lower detection limit between 6.1 and 8.5 nm. Above 25 nm the FCPC reached 98–100% counting efficiency compared to an electrometer used as the reference instrument. The FCPC demonstrated its ability to perform continuous measurements over a few hours in the laboratory with respect to the total particle counting. The instrument has been implemented into the airborne measurement platform ACTOS to perform measurements in the atmospheric boundary layer. Therefore, a stable operation over two hours is required. The mixing time of the new FCPC was estimated in two ways using a time series with highly fluctuating particle number concentrations. The analysis of a sharp ramp due to a concentration change results in a mixing time of 5 ms while a spectral analysis of atmospheric data demonstrates that for frequencies up to 10 Hz coherent structures can be resolved before sampling noise dominates

The asymmetric drift, the local standard of rest, and implications from RAVE data

Context. The determination of the local standard of rest (LSR), which corresponds to the measurement of the peculiar motion of the Sun based on the derivation of the asymmetric drift of stellar populations, is still a matter of debate. The classical value of the tangential peculiar motion of the Sun with respect to the LSR was challenged in recent years, claiming a significantly larger value. Aims. We present an improved Jeans analysis, which allows a better interpretation of the measured kinematics of stellar populations in the Milky Way disc. We show that the Radial Velocity Experiment (RAVE) sample of dwarf stars is an excellent data set to derive tighter boundary conditions to chemodynamical evolution models of the extended solar neighbourhood. Methods. We propose an improved version of the Stromberg relation with the radial scalelengths as the only unknown. We redetermine the asymmetric drift and the LSR for dwarf stars based on RAVE data. Additionally, we discuss the impact of adopting a different LSR value on the individual scalelengths of the subpopulations. Results. Binning RAVE stars in metallicity reveals a bigger asymmetric drift (corresponding to a smaller radial scalelength) for more metal-rich populations. With the standard assumption of velocity-dispersion independent radial scalelengths in each metallicity bin, we redetermine the LSR. The new Stromberg equation yields a joint LSR value of V-circle dot = 3.06 +/- 0.68 km s(-1), which is even smaller than the classical value based on Hipparcos data. The corresponding radial scalelength increases from 1.6 kpc for the metal-rich bin to 2.9 kpc for the metal-poor bin, with a trend of an even larger scalelength for young metal-poor stars. When adopting the recent Schonrich value of V-circle dot = 12.24 km s(-1) for the LSR, the new Stromberg equation yields much larger individual radial scalelengths of the RAVE subpopulations, which seem unphysical in part. Conclusions. The new Stromberg equation allows a cleaner interpretation of the kinematic data of disc stars in terms of radial scalelengths. Lifting the LSR value by a few km s(-1) compared to the classical value results in strongly increased radial scalelengths with a trend of smaller values for larger velocity dispersions

Aerosols-cloud microphysics-thermodynamics-turbulence: Evaluating supersaturation in a marine stratocumulus cloud

This work presents a unique combination of aerosol, cloud microphysical, thermodynamic and turbulence variables to characterize supersaturation fluctuations in a turbulent marine stratocumulus (SC) layer. The analysis is based on observations with the helicopter-borne measurement platform ACTOS and a detailed cloud microphysical parcel model following three different approaches: (1) From the comparison of aerosol number size distributions inside and below the SC layer, the number of activated particles is calculated as 435±87 cm−3 and compares well with the observed median droplet number concentration of Nd = 464 cm−3. Furthermore, a 50% activation diameter of Dp50≈115 nm was derived, which was linked to a critical supersaturation Scrit of 0.16% via Köhler theory. From the shape of the fraction of activated particles, we estimated a standard deviation of supersaturation fluctuations of σS' = 0.09%. (2) These estimates are compared to more direct thermodynamic observations at cloud base. Therefore, supersaturation fluctuations (S') are calculated based on highly-resolved thermodynamic data showing a standard deviation of S' ranging within 0.1%≤σS'≤0.3 %. (3) The sensitivity of the supersaturation on observed vertical wind velocity fluctuations is investigated with the help of a detailed cloud microphysical model. These results show highest fluctuations of S' with σS'=0.1% at cloud base and a decreasing σS' with increasing liquid water content and droplet number concentration. All three approaches are independent of each other and vary only within a factor of about two

Aerosols-cloud microphysics-thermodynamics-turbulence: Evaluating supersaturation in a marine stratocumulus cloud

This work presents a unique combination of aerosol, cloud microphysical, thermodynamic and turbulence variables to characterize supersaturation fluctuations in a turbulent marine stratocumulus (SC) layer. The analysis is based on observations with the helicopter-borne measurement platform ACTOS and a detailed cloud microphysical parcel model following three different approaches: (1) From the comparison of aerosol number size distributions inside and below the SC layer, the number of activated particles is calculated as 435 ± 87 cm -3 and compares well with the observed median droplet number concentration of N̄ d = 464 cm -3. Furthermore, a 50% activation diameter of D p50 ≈ 115 nm was derived, which was linked to a critical supersaturation S crit of 0.16% via Köhler theory. From the shape of the fraction of activated particles, we estimated a standard deviation of supersaturation fluctuations of σ S′ = 0.09 %. (2) These estimates are compared to more direct thermodynamic observations at cloud base. Therefore, supersaturation fluctuations (S′) are calculated based on highly-resolved thermodynamic data showing a standard deviation of S′ ranging within 0.1%≤ σ S′ ≤ 0.3 %. (3) The sensitivity of the supersaturation on observed vertical wind velocity fluctuations is investigated with the help of a detailed cloud microphysical model. These results show highest fluctuations of σ S′ with σ S′ =0.1% at cloud base and a decreasing σS′ with increasing liquid water content and droplet number concentration. All three approaches are independent of each other and vary only within a factor of about two

Alimentación, ocio y cultura en el pazo de Goiáns en el siglo XVIII

Actas de la XII Reunión Científica de la Fundación Española de Historia Moderna, celebrada en la Universidad de León en 19-21 de junio de 2012. José Manuel Vázquez Lijó, Universidad de Coruña ([email protected])En esta comunicación se analizan algunos aspectos del micro cosmos cultural de un pazo gallego, el de Goiáns, cuya excepcional ubicación a orillas de la ría de Arousa dota de alto valor añadido a este solar con espacios singulares como pesquera y embarcadero. Los inventarios de bienes de la casa informan de varios indicadores culturales de las elites (libros, juegos, obras artísticas, instrumentos musicales) y otros, como la alimentación, pueden estudiarse gracias a la documentación contable. El breve esplendor material del pazo parece datarse a mediados del siglo XVIII coincidiendo con la exitosa promoción social de los señores de Goiáns y sus hijos consecuencia de un cúmulo de factores (relaciones familiares, poder económico, bodas ventajosas, educación privilegiada…). La carrera militar de los sucesivos dueños les obligó a residir allí donde ejercían estos empleos y Goiáns pasó a ser una segunda residencia, cada vez más vacía de vida y de muebles, convirtiéndose a partir de la década de 1820 en un simple centro de administración de rentas.Peer reviewe

Weighing the local dark matter with RAVE red clump stars

We determine the Galactic potential in the solar neigbourhood from RAVE observations. We select red clump stars for which accurate distances, radial velocities, and metallicities have been measured. Combined with data from the 2MASS and UCAC catalogues, we build a sample of 4600 red clump stars within a cylinder of 500 pc radius oriented in the direction of the South Galactic Pole, in the range of 200 pc to 2000 pc distances. We deduce the vertical force and the total mass density distribution up to 2 kpc away from the Galactic plane by fitting a distribution function depending explicitly on three isolating integrals of the motion in a separable potential locally representing the Galactic one with four free parameters. Because of the deep extension of our sample, we can determine nearly independently the dark matter mass density and the baryonic disc surface mass density. We find (i) at 1kpc Kz/(2piG) = 68.5 pm 1.0 Msun/pc2, and (ii) at 2 kpc Kz/(2piG) = 96.9 pm 2.2 Msun/pc2. Assuming the solar Galactic radius at R0 = 8.5 kpc, we deduce the local dark matter density rhoDM (z=0) = 0.0143 pm 0.0011Msun pc3 = 0.542 pm 0.042 Gev/cm3 and the baryonic surface mass density Sigma = 44.4 pm 4.1 Msun/pc2 . Our results are in agreement with previously published Kz determinations up to 1 kpc, while the extension to 2 kpc shows some evidence for an unexpectedly large amount of dark matter. A flattening of the dark halo of order 0.8 can produce such a high local density in combination with a circular velocity of 240 km/s . Another explanation, allowing for a lower circular velocity, could be the presence of a secondary dark component, a very thick disc resulting either from the deposit of dark matter from the accretion of multiple small dwarf galaxies, or from the presence of an effective phantom thick disc in the context of effective galactic-scale modifications of gravity.Comment: 14 pages, 13 figures, accepted to Astronomy and Astrophysic

Ruthenium(II)-bis(4'-(4-ethynylphenyl)-2,2':6', 2''-terpyridine) - A versatile synthon in supramolecular chemistry. Synthesis and characterization

A homoleptic ethynyl-substituted ruthenium(II)-bisterpyridine complex representing a versatile synthon in supramolecular chemistry was synthesized and analyzed by NMR spectroscopy, mass spectrometry and X-ray diffractometry. Furthermore, its photophysical properties were detailed by UV/Vis absorption, emission and resonance Raman spectroscopy. In order to place the results obtained in the context of the vast family of ruthenium coordination compounds, two structurally related complexes were investigated accordingly. These reference compounds bear either no or an increased chromophore in the 4̀-position. The spectroscopic investigations reveal a systematic bathochromic shift of the absorption and emission maximum upon increasing chromophore size. This bathochromic shift of the steady state spectra occurs hand in hand with increasing resonance Raman intensities upon excitation of the metal-to-ligand charge-transfer transition. The latter feature is accompanied by an increased excitation delocalization over the chromophore in the 4̀-position of the terpyridine. Thus, the results presented allow for a detailed investigation of the electronic effects of the ethynyl substituent on the metal-to-ligand charge-transfer states in the synthon for click reactions leading to coordination polymers

An X-ray and Optical Investigation of the Environments Around Nearby Radio Galaxies

Investigations of the cluster environment of radio sources have not shown a correlation between radio power and degree of clustering. However, it has been demonstrated that extended X-ray luminosity and galaxy clustering do exhibit a positive correlation. This study investigates a complete sample of 25 nearby (z less than 0.06) radio galaxies which are not cataloged members of Abell clusters. The environment of these radio galaxies is studied in both the X-ray and the optical by means of the ROSAT All-Sky Survey (RASS), ROSAT pointed observations, and the Palomar optical Digitized Sky Survey (DSS). X-ray luminosities and extents are determined from the RASS, and the DSS is used to quantify the degree of clustering via the spatial two-point correlation coefficient, Bgg. Of the 25 sources, 20 are greater than sigma detections in the X-ray and 11 possessed Bgg's significantly in excess of that expected for an isolated galaxy. Adding the criterion that the X-ray emission be resolved, 10 of the radio galaxies do appear to reside in poor clusters with extended X-ray emission suggestive of the presence of an intracluster medium. Eight of these galaxies also possess high spatial correlation coefficients. Taken together, these data suggest that the radio galaxies reside in a low richness extension of the Abell clusters. The unresolved X-ray emission from the other galaxies is most likely associated with AGN phenomena. Furthermore, although the sample size is small, it appears that the environments of FR I and FR II sources differ. FR I's tend to be more frequently associated with extended X-ray emission (10 of 18), whereas FR II's are typically point sources or non-detections in the X-ray (none of the 7 sources exhibit extended X-ray emission).Comment: 28 page postscript file including figures and tables, plus one landscape table and 5 GIF figure

Constraining the Galaxy's dark halo with RAVE stars

We use the kinematics of $\sim200\,000$ giant stars that lie within $\sim 1.5$ kpc of the plane to measure the vertical profile of mass density near the Sun. We find that the dark mass contained within the isodensity surface of the dark halo that passes through the Sun ($(6\pm0.9)\times10^{10}\,\mathrm{M_\odot}$), and the surface density within $0.9$ kpc of the plane ($(69\pm10)\,\mathrm{M_\odot\,pc^{-2}}$) are almost independent of the (oblate) halo's axis ratio $q$. If the halo is spherical, 46 per cent of the radial force on the Sun is provided by baryons, and only 4.3 per cent of the Galaxy's mass is baryonic. If the halo is flattened, the baryons contribute even less strongly to the local radial force and to the Galaxy's mass. The dark-matter density at the location of the Sun is $0.0126\,q^{-0.89}\,\mathrm{M_\odot\,pc^{-3}}=0.48\,q^{-0.89}\,\mathrm{GeV\,cm^{-3}}$. When combined with other literature results we find hints for a mildly oblate dark halo with $q \simeq 0.8$. Our value for the dark mass within the solar radius is larger than that predicted by cosmological dark-matter-only simulations but in good agreement with simulations once the effects of baryonic infall are taken into account. Our mass models consist of three double-exponential discs, an oblate bulge and a Navarro-Frenk-White dark-matter halo, and we model the dynamics of the RAVE stars in the corresponding gravitational fields by finding distribution functions $f(\mathbf{J})$ that depend on three action integrals. Statistical errors are completely swamped by systematic uncertainties, the most important of which are the distance to the stars in the photometric and spectroscopic samples and the solar distance to the Galactic centre. Systematics other than the flattening of the dark halo yield overall uncertainties $\sim 15$ per cent.Comment: 20 pages, 17 figures, accepted for publication in MNRA