677 research outputs found
The relationship of storm severity to directionally resolved radio emissions
Directionally resolved atmospheric radio frequency emission data were acquired from thunderstorms occurring in the central and southwestern United States. In addition, RF sferic tracking data were obtained from hurricanes and tropical depressions occurring in the Gulf of Mexico. The data were acquired using a crossed baseline phase interferometer operating at a frequency of 2.001 MHz. The received atmospherics were tested for phase linearity across the array, and azimuth/elevation angles of arrival were computed in real time. A histogram analysis of sferic burst count versus azimuth provided lines of bearing to centers of intense electrical activity. Analysis indicates a consistent capability of the phase linear direction finder to detect severe meteorological activity to distances of 2000 km from the receiving site. The technique evidences the ability to discriminate severe storms from nonsevere storms coexistent in large regional scale thunderstorm activity
Tensor Product Approximation (DMRG) and Coupled Cluster method in Quantum Chemistry
We present the Copupled Cluster (CC) method and the Density matrix
Renormalization Grooup (DMRG) method in a unified way, from the perspective of
recent developments in tensor product approximation. We present an introduction
into recently developed hierarchical tensor representations, in particular
tensor trains which are matrix product states in physics language. The discrete
equations of full CI approximation applied to the electronic Schr\"odinger
equation is casted into a tensorial framework in form of the second
quantization. A further approximation is performed afterwards by tensor
approximation within a hierarchical format or equivalently a tree tensor
network. We establish the (differential) geometry of low rank hierarchical
tensors and apply the Driac Frenkel principle to reduce the original
high-dimensional problem to low dimensions. The DMRG algorithm is established
as an optimization method in this format with alternating directional search.
We briefly introduce the CC method and refer to our theoretical results. We
compare this approach in the present discrete formulation with the CC method
and its underlying exponential parametrization.Comment: 15 pages, 3 figure
Directed Rh(I)-Catalyzed Asymmetric Hydroboration of Prochiral 1-Arylcycloprop-2-ene-1-carboxylic Acid Derivatives
This is the peer reviewed version of the following article: A. Edwards, M. Rubina, M. Rubin, Chem. Eur. J. 2018, 24, 1394., which has been published in final form at http://doi.org/10.1002/chem.201704443. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.A full account on rhodium-catalyzed asymmetric, directed hydroboration of functionalized prochiral cyclopropenes affording enantiomerically enriched cyclopropylboronates is reported. The scope and limitations of two alternate directing groups, ester and carboxamide, are evaluated. It was found that hydroboration of esters appeared to be more sensitive to substitution in the aromatic ring of the substrates. Specifically, ortho-halogens were detrimental for diastereo- and enantioselectivity, possibly because of additional coordination with rhodium. In contrast, more Lewis-basic amide directing groups allowed for stronger chelation to the transition metal, leading to consistently high diastereo- and enantioselectivity in hydroboration across a broader range of substrates
Nuclear Theory and Science of the Facility for Rare Isotope Beams
The Facility for Rare Isotope Beams (FRIB) will be a world-leading laboratory
for the study of nuclear structure, reactions and astrophysics. Experiments
with intense beams of rare isotopes produced at FRIB will guide us toward a
comprehensive description of nuclei, elucidate the origin of the elements in
the cosmos, help provide an understanding of matter in neutron stars, and
establish the scientific foundation for innovative applications of nuclear
science to society. FRIB will be essential for gaining access to key regions of
the nuclear chart, where the measured nuclear properties will challenge
established concepts, and highlight shortcomings and needed modifications to
current theory. Conversely, nuclear theory will play a critical role in
providing the intellectual framework for the science at FRIB, and will provide
invaluable guidance to FRIB's experimental programs. This article overviews the
broad scope of the FRIB theory effort, which reaches beyond the traditional
fields of nuclear structure and reactions, and nuclear astrophysics, to explore
exciting interdisciplinary boundaries with other areas.
\keywords{Nuclear Structure and Reactions. Nuclear
Astrophysics. Fundamental Interactions. High Performance
Computing. Rare Isotopes. Radioactive Beams.Comment: 20 pages, 7 figure
Measurement of E2 Transitions in the Coulomb Dissociation of 8B
In an effort to understand the implications of Coulomb dissociation
experiments for the determination of the 7Be(p,gamma)8B reaction rate,
longitudinal momentum distributions of 7Be fragments produced in the Coulomb
dissociation of 44 and 81 MeV/nucleon 8B beams on a Pb target were measured.
These distributions are characterized by asymmetries interpreted as the result
of interference between E1 and E2 transition amplitudes in the Coulomb breakup.
At the lower beam energy, both the asymmetries and the measured cross sections
are well reproduced by perturbation theory calculations, allowing a
determination of the E2 strength.Comment: 8 pages, 3 figure
S17(0) Determined from the Coulomb Breakup of 83 MeV/nucleon 8B
A kinematically complete measurement was made of the Coulomb dissociation of
8B nuclei on a Pb target at 83 MeV/nucleon. The cross section was measured at
low relative energies in order to infer the astrophysical S factor for the
7Be(p,gamma)8B reaction. A first-order perturbation theory analysis of the
reaction dynamics including E1, E2, and M1 transitions was employed to extract
the E1 strength relevant to neutrino-producing reactions in the solar interior.
By fitting the measured cross section from Erel = 130 keV to 400 keV, we find
S17(0) = 17.8 (+1.4, -1.2) eV b
Long term (5 Year) safety of bronchial thermoplasty: Asthma Intervention Research (AIR) trial
<b>Background:</b>
Bronchial thermoplasty (BT) is a bronchoscopic procedure that improves asthma control by reducing excess airway smooth muscle. Treated patients have been followed out to 5 years to evaluate long-term safety of this procedure.
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<b>Methods:</b>
Patients enrolled in the Asthma Intervention Research Trial were on inhaled corticosteroids ≥200 μg beclomethasone or equivalent + long-acting-beta2-agonists and demonstrated worsening of asthma on long-acting-β2-agonist withdrawal. Following initial evaluation at 1 year, subjects were invited to participate in a 4 year safety study. Adverse events (AEs) and spirometry data were used to assess long-term safety out to 5 years post-BT.
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<b>Results:</b>
45 of 52 treated and 24 of 49 control group subjects participated in long-term follow-up of 5 years and 3 years respectively. The rate of respiratory adverse events (AEs/subject) was stable in years 2 to 5 following BT (1.2, 1.3, 1.2, and 1.1, respectively,). There was no increase in hospitalizations or emergency room visits for respiratory symptoms in Years 2, 3, 4, and 5 compared to Year 1. The FVC and FEV1 values showed no deterioration over the 5 year period in the BT group. Similar results were obtained for the Control group.
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<b>Conclusions:</b>
The absence of clinical complications (based on AE reporting) and the maintenance of stable lung function (no deterioration of FVC and FEV1) over a 5-year period post-BT in this group of patients with moderate to severe asthma support the long-term safety of the procedure out to 5 years
Isotopic distribution of fission fragments in collisions between 238U beam and 9Be and 12C targets at 24 MeV/u
Inverse kinematics coupled to a high-resolution spectrometer is used to
investigate the isotopic yields of fission fragments produced in reactions
between a 238U beam at 24 MeV/u and 9Be and 12C targets. Mass, atomic number
and isotopic distributions are reported for the two reactions. These
informations give access to the neutron excess and the isotopic distribution
widths, which together with the atomic-number and mass distributions are used
to investigate the fusion-fission dynamics.Comment: Submitted to PR
Thermal Density Functional Theory in Context
This chapter introduces thermal density functional theory, starting from the
ground-state theory and assuming a background in quantum mechanics and
statistical mechanics. We review the foundations of density functional theory
(DFT) by illustrating some of its key reformulations. The basics of DFT for
thermal ensembles are explained in this context, as are tools useful for
analysis and development of approximations. We close by discussing some key
ideas relating thermal DFT and the ground state. This review emphasizes thermal
DFT's strengths as a consistent and general framework.Comment: Submitted to Spring Verlag as chapter in "Computational Challenges in
Warm Dense Matter", F. Graziani et al. ed
A Q-TWiST analysis comparing panitumumab plus best supportive care (BSC) with BSC alone in patients with wild-type KRAS metastatic colorectal cancer
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