Magnetic properties of REE fluorcarbonate minerals and their implications for minerals processing

This is the final version. Available on open access from Elsevier via the DOI in this recordRare earth elements (REE) are considered as critical metals for electronics and green technology. The REE fluorcarbonates are one of the main REE ore minerals, common in many different types of REE deposit and yet some of their fundamental properties have still not been determined. This study measured the magnetic properties of pure REE fluorcarbonate single crystal minerals using a vibrating sample magnetometer (VSM) and determined their elemental compositions using electron probe microanalysis (EPMA). The results provide the first measurements of the magnetic behaviour and susceptibility of REE fluorcarbonates other than bastnäsite-(Ce). The magnetic susceptibility of REE fluorcarbonates varies systematically from one mineral to another and is highly dependent on the mineral chemistry. It is positive (paramagnetic) for bastnäsite-(Ce) and gradually decreases as the amount of Ca increases in parisite-(Ce), becoming negative (diamagnetic) for the Ca-rich member of the series, röntgenite. Synchysite-(Ce) is difficult to measure, generate good signal and acquire accurate readings because it practically always occurs as <5 mg crystals. Its magnetic susceptibility in samples from a REE ore deposit was experimentally determined by magnetic separation and checked by an associated study using a SQUID magnetometer, synchysite-(Ce) behaved as a diamagnetic mineral. This can be explained by the increase of Ca content and decrease of REE content, in addition to the variations in the layered structure common to the REE fluorcarbonate series minerals. Given the wide range of magnetic susceptibility of REE fluorcarbonates, it is important that the mineralogy is determined carefully before setting up a mineral processing flow sheet.Mkango Resources LtdNatural Environment Research Council (NERC

Ion Trap Mass Spectrometers for Identity, Abundance and Behavior of Volatiles on the Moon

NASA GSFC and The Open University (UK) are collaborating to deploy an Ion Trap Mass Spectrometer on the Moon to investigate the lunar water cycle. The ITMS is flight-proven throughthe Rosetta Philae comet lander mission. It is also being developed under ESA funding to analyse samples drilled from beneath the lunar surface on the Roscosmos Luna-27 lander (2025).Now, GSFC and OU will now develop a compact ITMS instrument to study the near-surface lunar exosphere on board a CLPS Astrobotic lander at Lacus Mortis in 2021

Beagle 2: Mission to Mars — current status

Beagle 2, developed in the UK, was launched on June 2, 2003. It landed on Mars on December 25th, 2003 in Isidis Planitia, a large sedimentary basin. To date, the team is awaiting signals from the Beagle 2 lander. Current status of the mission will be reported

Do ultrafast exciton-polaron decoherence dynamics govern photocarrier generation efficiencies in polymer solar cells?

All-organic-based photovoltaic solar cells have attracted considerable attention because of their low-cost processing and short energy payback time. In such systems the primary dissociation of an optical excitation into a pair of photocarriers has been recently shown to be extremely rapid and efficient, but the physical reason for this remains unclear. Here, two-dimensional photocurrent excitation spectroscopy, a novel non-linear optical spectroscopy, is used to probe the ultrafast coherent decay of photoexcitations into charge-producing states in a polymer:fullerene based solar cell. The two-dimensional photocurrent spectra are interpreted by introducing a theoretical model for the description of the coupling of the electronic states of the system to an external environment and to the applied laser fields. The experimental data show no cross-peaks in the two-dimensional photocurrent spectra, as predicted by the model for coherence times between the exciton and the photocurrent producing states of 20\,fs or less

MoonLITE – Technological feasibility of the penetrator concept

Introduction: While the surface missions to the Moon of the 1960s and 1970s achieved a great deal, scientifically a great deal was also left unresolved. The recent plethora of lunar missions (flown or proposed) reflects resurgence in interest in the Moon, not only in its own right, but also as a record of the formation of the Earth-Moon System and the interplanetary environment at 1 AU. Results from orbiter missions have indicated the possible presense of ice within permanently shaded craters at the lunar poles [1] – a situation that, if confirmed, will have profound impacts on lunar exploration

Descriptive epidemiology of Escherichia coli bacteraemia in England, April 2012 to March 2014

We determined the incidence, risk factors and antimicrobial susceptibility associated with Escherichia coli bacteraemia in England over a 24 month period. Case data were obtained from the national mandatory surveillance database, with susceptibility data linked from LabBase2, a voluntary national microbiology database. Between April 2012 and March 2014, 66,512 E. coli bacteraemia cases were reported. Disease incidence increased by 6% from 60.4 per 100,000 population in 2012-13 to 63.5 per 100,000 population in 2013-14 (p < 0.0001). Rates of E. coli bacteraemia varied with patient age and sex, with 70.5% (46,883/66,512) of cases seen in patients aged ≥ 65 years and 52.4% (33,969/64,846) of cases in females. The most common underlying cause of bacteraemia was infection of the genital/urinary tract (41.1%; 27,328/66,512), of which 98.4% (26,891/27,328) were urinary tract infections (UTIs). The majority of cases (76.1%; 50,617/66,512) had positive blood cultures before or within two days of admission and were classified as community onset cases, however 15.7% (10,468/66,512) occurred in patients who had been hospitalised for over a week. Non-susceptibility to ciprofloxacin, third-generation cephalosporins, piperacillin-tazobactam, gentamicin and carbapenems were 18.4% (8,439/45,829), 10.4% (4,256/40,734), 10.2% (4,694/46,186), 9.7% (4,770/49,114) and 0.2% (91/42,986), respectively. Antibiotic non-susceptibility was higher in hospital-onset cases than for those presenting from the community (e.g. ciprofloxacin non-susceptibility was 22.1% (2,234/10,105) for hospital-onset vs 17.4% (5,920/34,069) for community-onset cases). Interventions to reduce the incidence of E. coli bacteraemia will have to target the community setting and UTIs if substantial reductions are to be realised

Investigating TriHaloMethanes with respect to humidity

The disinfection of potable water has dramatically reduced the instances of Cholera and similar ailments within a population drawing upon that water source. There is however the possibility that Natural Organic Matter (NOM) can interact with the disinfection compounds to form Disinfection By-Products (DBP). One group of DBPs are Trihalomethanes (THMs) with several compounds of the group being suspected carcinogens. Within the UK the total concentration of all THMs within drinking water must not exceed 100µg/l. At present water authorities take samples of the water supply and return them to a central laboratory for analysis. This provides an accurate test but one which can involve a long lead time in discovering a potential hazard to public health. A Field Asymmetric Ion Mobility Spectrometer (FAIMS) sensor may be ideally placed to perform in situ continuous monitoring at particular sites. As part of a PhD co-sponsored by The Open University and Owlstone Nanotech Plc an investigation is ongoing to discover how sensitive a FAIMS device is with respect to THMs and humidity when sampling. Initial results and the method of data processing, which involves peak fitting to evolving spectra are presented

User testing digital, multimedia information to inform children, adolescents and their parents about healthcare trials

Digital, multimedia information resources (MMIs) containing text, video, animation and pictures are a promising alternative to written participant information materials designed to inform children, adolescents and parents about healthcare trials, but little research has tested whether they are fit for purpose. This study employed a consecutive groups design and user testing questionnaire to assess whether participants were able to find and understand key information in multimedia resources. Two rounds of testing were completed. In each round, seven children aged 7–11 tested the MMI with a parent; six adolescents aged 12–17 and seven parents tested the MMI independently. After round 1, the resources were revised based on participant scores, behaviour and feedback. Round 1 identified problems with 2/10 information items (length of trial and use of insulin pump); only 3/20 participants could locate all information items without difficulty. After revisions, 14/20 participants scored a clear round. Information comprehension was high: 96% understood in round 1 and 99% in round 2. Participant feedback on the multimedia resources was positive, although presentation preferences varied. User testing was employed successfully with children, adolescents and parents to identify issues with, and improve, multimedia resources developed to inform potential healthcare trial participants

In Vitro Hydrodynamic Assessment of a New Transcatheter Heart Valve Concept (the TRISKELE)

This study presents the in vitro hydrodynamic assessment of the TRISKELE, a new system suitable for transcatheter aortic valve implantation (TAVI), aiming to mitigate the procedural challenges experienced with current technologies. The TRISKELE valve comprises three polymeric leaflet and an adaptive sealing cuff, supported by a novel fully retrievable self-expanding nitinol wire frame. Valve prototypes were manufactured in three sizes of 23, 26, and 29 mm by automated dip-coating of a biostable polymer, and tested in a hydrodynamic bench setup in mock aortic roots of 21, 23, 25, and 27 mm annulus, and compared to two reference valves suitable for equivalent implantation ranges: Edwards SAPIEN XT and Medtronic CoreValve. The TRISKELE valves demonstrated a global hydrodynamic performance comparable or superior to the controls with significant reduction in paravalvular leakage. The TRISKELE valve exhibits enhanced anchoring and improved sealing. The valve is currently under preclinical investigation