7,268 research outputs found
Ab initio electronic structure calculations of solid, solution-processed metallotetrabenzoporphyrins
An ab initio study of the electronic structures of solid
metallotetrabenzoporphyrins (MTBPs) utilized in organic transistors and
photovoltaics is presented. Bandstructures, densities of states, and orbitals
are calculated for H2, Cu, Ni, and Zn core substitutions of the unit cell of
solid TBP, as deposited via soluble precursors that are thermally annealed to
produce polycrystalline, semiconducting thin-films. While the unit cells of the
studied MTBPs are nearly isomorphous, substitution of the core atoms alters the
structure of the bands around the energy bandgap and the composition of the
densities of states. Cu and Ni core substitutions introduce
nearly-dispersionless energy bands near the valence and conduction band edges,
respectively, that form acceptor or deep generation/recombination states.Comment: 7 pages, 3 figures, 4 table
Further development of a charged liquid colloid source for electrostatic propulsion Final report
Performance characteristics of charged liquid droplet electrostatic propulsion syste
Empirical model for the Earth's cosmic ray shadow at 400 KM: Prohibited cosmic ray access
The possibility to construct a unit sphere of access that describes the cosmic radiation allowed to an Earth-orbiting spacecraft is discussed. It is found that it is possible to model the occluded portion of the cosmic ray sphere of access as a circular projection with a diameter bounded by the satellite-Earth horizon. Maintaining tangency at the eastern edge of the spacecraft-Earth horizon, this optically occluded area is projected downward by an angle beta which is a function of the magnetic field inclination and cosmic ray arrival direction. This projected plane, corresponding to the forbidden area of cosmic ray access, is bounded by the spacecraft-Earth horizon in easterly directions, and is rotated around the vertical axis by an angle alpha from the eastern direction, where the angle alpha is a function of the offset dipole latitude of the spacecraft
North-south asymmetry in activity on the Sun and cosmic ray density gradients
The marked N-S asymmetry in solar activity (with predominant activity in the Sun's Northern Hemisphere) during the 1960's could certainly account for a S-pointing cosmic ray gradient. It is also clear from the data that the response to this change in solar activity asymmetry, and the related change in the perpendicular cosmic ray density gradient, is different for cosmic ray telescopes in the Earth's Northern and Southern Hemispheres. Northern Hemisphere detectors see a S-pointing gradient in the 60's and a N-pointing gradient after 1971, while Southern Hemisphere telescopes see a S-pointing gradient both before and after the reversal
An Improved Model for Relativistic Solar Proton Acceleration applied to the 2005 January 20 and Earlier Events
This paper presents results on modelling the ground level response of the
higher energy protons for the 2005 January 20 ground level enhancement (GLE).
This event, known as GLE 69, produced the highest intensity of relativistic
solar particles since the famous event on 1956 February 23. The location of
recent X-ray and gamma-ray emission (N14 W61) was near to Sun-Earth connecting
magnetic field lines, thus providing the opportunity to directly observe the
acceleration source from Earth. We restrict our analysis to protons of energy
greater than 450 MeV to avoid complications arising from transport processes
that can affect the propagation of low energy protons. In light of this revised
approach we have reinvestigated two previous GLEs: those of 2000 July 14 (GLE
59) and 2001 April 15 (GLE 60). Within the limitations of the spectral forms
employed, we find that from the peak (06:55 UT) to the decline (07:30 UT)
phases of GLE 69, neutron monitor observations from 450 MeV to 10 GeV are best
fitted by the Gallegos-Cruz & Perez-Peraza stochastic acceleration model. In
contrast, the Ellison & Ramaty spectra did not fit the neutron monitor
observations as well. This result suggests that for GLE 69, a stochastic
process cannot be discounted as a mechanism for relativistic particle
acceleration, particularly during the initial stages of this solar event. For
GLE 59 we find evidence that more than one acceleration mechanism was present,
consistent with both shock and stochastic acceleration processes dominating at
different times of the event. For GLE 60 we find that Ellison & Ramaty spectra
better represent the neutron monitor observations compared to stochastic
acceleration spectra. The results for GLEs 59 and 60 are in agreement with our
previous work.Comment: 42 pages, 10 figures, 10 tables, published in ApJ, August 200
Deep radio observations of the radio halo of the bullet cluster 1E 0657-55.8
We present deep 1.1-3.1 GHz Australia Telescope Compact Array observations of
the radio halo of the bullet cluster, 1E 0657-55.8. In comparison to existing
images of this radio halo the detection in our images is at higher
significance. The radio halo is as extended as the X-ray emission in the
direction of cluster merger but is significantly less extended than the X-ray
emission in the perpendicular direction. At low significance we detect a faint
second peak in the radio halo close to the X-ray centroid of the smaller
sub-cluster (the bullet) suggesting that, similarly to the X-ray emission, the
radio halo may consist of two components. Finally, we find that the distinctive
shape of the western edge of the radio halo traces out the X-ray detected bow
shock. The radio halo morphology and the lack of strong point-to-point
correlations between radio, X-ray and weak-lensing properties suggests that the
radio halo is still being formed. The colocation of the X-ray shock with a
distinctive radio brightness edge illustrates that the shock is influencing the
structure of the radio halo. These observations support the theory that shocks
and turbulence influence the formation and evolution of radio halo synchrotron
emission.Comment: 15 pages, 16 figures, 3 tables. Accepted by MNRA
Recommended from our members
Spinal Progenitor-Laden Bridges Support Earlier Axon Regeneration Following Spinal Cord Injury.
Impact statementSpinal cord injury (SCI) results in loss of tissue innervation below the injury. Spinal progenitors have a greater ability to repair the damage and can be injected into the injury, but their regenerative potential is hampered by their poor survival after transplantation. Biomaterials can create a cell delivery platform and generate a more hospitable microenvironment for the progenitors within the injury. In this work, polymeric bridges are used to deliver embryonic spinal progenitors to the injury, resulting in increased progenitor survival and subsequent regeneration and functional recovery, thus demonstrating the importance of combined therapeutic approaches for SCI
Forecasting basketball players’ performance using sparse functional data
Statistics and analytic methods are becoming increasingly important in basketball. In particular, predicting players’ performance using past observations is a considerable challenge. The purpose of this study is to forecast
the future behavior of basketball players. The available data are sparse functional data, which are very common in sports. So far, however, no forecasting method designed for sparse functional data has been used in sports.
A methodology based on two methods to handle sparse and irregular data,
together with the analogous method and functional archetypoid analysis is
proposed. Results in comparison with traditional methods show that our
approach is competitive and additionally provides prediction intervals. The
methodology can also be used in other sports when sparse longitudinal data
are available
Relativistic Proton Production During the 14 July 2000 Solar Event: The Case for Multiple Source Mechanisms
Protons accelerated to relativistic energies by transient solar and
interplanetary phenomena caused a ground-level cosmic ray enhancement on 14
July 2000, Bastille Day. Near-Earth spacecraft measured the proton flux
directly and ground-based observatories measured the secondary responses to
higher energy protons. We have modelled the arrival of these relativistic
protons at Earth using a technique which deduces the spectrum, arrival
direction and anisotropy of the high-energy protons that produce increased
responses in neutron monitors. To investigate the acceleration processes
involved we have employed theoretical shock and stochastic acceleration
spectral forms in our fits to spacecraft and neutron monitor data. During the
rising phase of the event (10:45 UT and 10:50 UT) we find that the spectrum
between 140 MeV and 4 GeV is best fitted by a shock acceleration spectrum. In
contrast, the spectrum at the peak (10:55 UT and 11:00 UT) and in the declining
phase (11:40 UT) is best fitted with a stochastic acceleration spectrum. We
propose that at least two acceleration processes were responsible for the
production of relativistic protons during the Bastille Day solar event: (1)
protons were accelerated to relativistic energies by a shock, presumably a
coronal mass ejection (CME). (2) protons were also accelerated to relativistic
energies by stochastic processes initiated by magnetohydrodynamic (MHD)
turbulence.Comment: 38 pages, 9 figures, accepted for publication in the Astrophysical
Journal, January, 200
Polycistronic Delivery of IL-10 and NT-3 Promotes Oligodendrocyte Myelination and Functional Recovery in a Mouse Spinal Cord Injury Model.
One million estimated cases of spinal cord injury (SCI) have been reported in the United States and repairing an injury has constituted a difficult clinical challenge. The complex, dynamic, inhibitory microenvironment postinjury, which is characterized by proinflammatory signaling from invading leukocytes and lack of sufficient factors that promote axonal survival and elongation, limits regeneration. Herein, we investigated the delivery of polycistronic vectors, which have the potential to coexpress factors that target distinct barriers to regeneration, from a multiple channel poly(lactide-co-glycolide) (PLG) bridge to enhance spinal cord regeneration. In this study, we investigated polycistronic delivery of IL-10 that targets proinflammatory signaling, and NT-3 that targets axonal survival and elongation. A significant increase was observed in the density of regenerative macrophages for IL-10+NT-3 condition relative to conditions without IL-10. Furthermore, combined delivery of IL-10+NT-3 produced a significant increase of axonal density and notably myelinated axons compared with all other conditions. A significant increase in functional recovery was observed for IL-10+NT-3 delivery at 12 weeks postinjury that was positively correlated to oligodendrocyte myelinated axon density, suggesting oligodendrocyte-mediated myelination as an important target to improve functional recovery. These results further support the use of multiple channel PLG bridges as a growth supportive substrate and platform to deliver bioactive agents to modulate the SCI microenvironment and promote regeneration and functional recovery. Impact statement Spinal cord injury (SCI) results in a complex microenvironment that contains multiple barriers to regeneration and functional recovery. Multiple factors are necessary to address these barriers to regeneration, and polycistronic lentiviral gene therapy represents a strategy to locally express multiple factors simultaneously. A bicistronic vector encoding IL-10 and NT-3 was delivered from a poly(lactide-co-glycolide) bridge, which provides structural support that guides regeneration, resulting in increased axonal growth, myelination, and subsequent functional recovery. These results demonstrate the opportunity of targeting multiple barriers to SCI regeneration for additive effects
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