An experimental investigation of a micro-tubular SOFC membrane-separated liquid desiccant dehumidification and cooling tri-generation system

This paper reports the results of experimental work carried out on a micro-tubular solid oxide fuel cell tri-generation systemthat uses the waste heat from the fuel cell for dehumidification and cooling though the integration of an open cycle liquid desiccant dehumidification and cooling system. The experimental results demonstrate regeneration of the potassium formate solution using the thermal output from the SOFC in the first of its kind tri-generation system. Optimisation has shown that a 2.2L.min-1 regenerator desiccant volumetric flow facilitates best performance.When integrated with the micro-SOFC, the open cycle desiccant system demonstrates a COP of approaching 0.7, an encouraging value for a waste heat driven cooling system of this capacity. A tri-generation performance analysis is presented which serves to demonstrate the novel system operating in a building. The system achieved an electrical efficiency of 11% and regeneration efficiency of approximately 37%. The electrical efficiency is lower than that predicted by the company supplying the micro-tubular SOFC, because the unit suffered sulphur poisoning during preliminary tests. The electrical power output decreased from 250W to 150W, which reduced the electrical efficiency from around 18% to 11% and the overall efficiency from approximately 45% to just over 37%. Low temperature (33-36°C) regeneration was demonstrated

Synthesis of a magnetic π-extended carbon nanosolenoid with Riemann surfaces

Riemann surfaces are deformed versions of the complex plane in mathematics. Locally they look like patches of the complex plane, but globally, the topology may deviate from a plane. Nanostructured graphitic carbon materials resembling a Riemann surface with helicoid topology are predicted to have interesting electronic and photonic properties. However, fabrication of such processable and large π-extended nanographene systems has remained a major challenge. Here, we report a bottom-up synthesis of a metal-free carbon nanosolenoid (CNS) material with a low optical bandgap of 1.97 eV. The synthesis procedure is rapid and possible on the gram scale. The helical molecular structure of CNS can be observed by direct low-dose high-resolution imaging, using integrated differential phase contrast scanning transmission electron microscopy. Magnetic susceptibility measurements show paramagnetism with a high spin density for CNS. Such a π-conjugated CNS allows for the detailed study of its physical properties and may form the base of the development of electronic and spintronic devices containing CNS species

High temperature (HT) polymer electrolyte membrande fuel cells (PEMFC) - A review

One possible solution of combating issues posed by climate change is the use of the High Temperature (HT) Polymer Electrolyte Membrane (PEM) Fuel Cell (FC) in some applications. The typical HT-PEMFC operating temperatures are in the range of 100e200 o C which allows for co-generation of heat and power, high tolerance to fuel impurities and simpler system design. This paper reviews the current literature concerning the HT-PEMFC, ranging from cell materials to stack and stack testing. Only acid doped PBI membranes meet the US DOE (Department of Energy) targets for high temperature membranes operating under no humidification on both anode and cathode sides (barring the durability). This eliminates the stringent requirement for humidity however, they have many potential drawbacks including increased degradation, leaching of acid and incompatibility with current state-of-the-art fuel cell materials. In this type of fuel cell, the choice of membrane material determines the other fuel cell component material composition, for example when using an acid doped system, the flow field plate material must be carefully selected to take into account the advanced degradation. Novel research is required in all aspects of the fuel cell components in order to ensure that they meet stringent durability requirements for mobile applications.Web of Scienc

Interference of Dihydrocoumarin with Hormone Transduction and Phenylpropanoid Biosynthesis Inhibits Barnyardgrass (Echinochloa crus-galli) Root Growth

Botanical compounds with herbicidal activity exhibit safety, low toxicity, and low chances of herbicide resistance development in plants. They have widespread applications in green agricultural production and the development of organic agriculture. In the present study, dihydrocoumarin showed potential as a botanical herbicide, and its phenotypic characteristics and mechanism of action were studied in barnyardgrass [Echinochloa crus-galli (L.) P.Beauv.] seedlings. The results indicated that dihydrocoumarin inhibited the growth of barnyardgrass without causing significant inhibition of rice seedling growth at concentrations ranging between 0.5 and 1.0 g/L. Additionally, dihydrocoumarin treatment could cause oxidative stress in barnyardgrass, disrupt the cell membrane, and reduce the root cell activity, resulting in root cell death. Transcriptomic analyses revealed that dihydrocoumarin could inhibit barnyardgrass normal growth by affecting the signal transduction of plant hormones. The results showed significant differential expression of plant hormone signal transduction genes in barnyardgrass. Additionally, dihydrocoumarin interfered with the expression of numerous phenylpropanoid biosynthesis genes in barnyardgrass that affect the production of various vital metabolites. We speculate that the barnyardgrass growth was suppressed by the interaction among hormones and phenylpropanoid biosynthesis genes, indicating that dihydrocoumarin can be applied as a bioherbicide to control barnyardgrass growth in rice transplanting fields

A Review of Atmosphere–Ocean Forcings Outside the Tropical Pacific on the El Niño–Southern Oscillation Occurrence

The El Niño⁻Southern Oscillation (ENSO) is the strongest interannual air⁻sea coupled variability mode in the tropics, and substantially impacts the global weather and climate. Hence, it is important to improve our understanding of the ENSO variability. Besides the well-known air⁻sea interaction process over the tropical Pacific, recent studies indicated that atmospheric and oceanic forcings outside the tropical Pacific also play important roles in impacting and modulating the ENSO occurrence. This paper reviews the impacts of the atmosphere⁻ocean variability outside the tropical Pacific on the ENSO variability, as well as their associated physical processes. The review begins with the contribution of the atmosphere⁻ocean forcings over the extratropical North Pacific, Atlantic, and Indian Ocean on the ENSO occurrence. Then, an overview of the extratropical atmospheric forcings over the Northern Hemisphere (including the Arctic Oscillation and the Asian monsoon systems) and the Southern Hemisphere (including the Antarctic Oscillation and the Pacific⁻South American teleconnection), on the ENSO occurrence, is presented. It is shown that the westerly (easterly) wind anomaly over the tropical western Pacific is essential for the occurrence of an El Niño (a La Niña) event. The wind anomalies over the tropical western Pacific also play a key role in relaying the impacts of the atmosphere⁻ocean forcings outside the tropical Pacific on the ENSO variability. Finally, some relevant questions, that remain to be explored, are discussed

Proteomic Analysis Comparison on the Ecological Adaptability of Quinclorac-Resistant Echinochloa crus-galli

Barnyardgrass (Echinochloa crus-galli L.) is the most serious weed threatening rice production, and its effects are aggravated by resistance to the quinclorac herbicide in the Chinese rice fields. This study conducted a comparative proteomic characterization of the quinclorac-treated and non-treated resistant and susceptible E. crus-galli using isobaric tags for relative and absolute quantification (iTRAQ). The results indicated that the quinclorac-resistant E. crus-galli had weaker photosynthesis and a weaker capacity to mitigate abiotic stress, which suggested its lower environmental adaptability. Quinclorac treatment significantly increased the number and expression of the photosynthesis-related proteins in the resistant E. crus-galli and elevated its photosynthetic parameters, indicating a higher photosynthetic rate compared to those of the susceptible E. crus-galli. The improved adaptability of the resistant E. crus-galli to quinclorac stress could be attributed to the observed up-regulated expression of eight herbicide resistance-related proteins and the down-regulation of two proteins associated with abscisic acid biosynthesis. In addition, high photosynthetic parameters and low glutathione thiotransferase (GST) activity were observed in the quinclorac-resistant E. crus-galli compared with the susceptible biotype, which was consistent with the proteomic sequencing results. Overall, this study demonstrated that the resistant E. crus-galli enhanced its adaptability to quinclorac by improving the photosynthetic efficiency and GST activity

Proteomic Analysis Comparison on the Ecological Adaptability of Quinclorac-Resistant <i>Echinochloa crus-galli</i>

Barnyardgrass (Echinochloa crus-galli L.) is the most serious weed threatening rice production, and its effects are aggravated by resistance to the quinclorac herbicide in the Chinese rice fields. This study conducted a comparative proteomic characterization of the quinclorac-treated and non-treated resistant and susceptible E. crus-galli using isobaric tags for relative and absolute quantification (iTRAQ). The results indicated that the quinclorac-resistant E. crus-galli had weaker photosynthesis and a weaker capacity to mitigate abiotic stress, which suggested its lower environmental adaptability. Quinclorac treatment significantly increased the number and expression of the photosynthesis-related proteins in the resistant E. crus-galli and elevated its photosynthetic parameters, indicating a higher photosynthetic rate compared to those of the susceptible E. crus-galli. The improved adaptability of the resistant E. crus-galli to quinclorac stress could be attributed to the observed up-regulated expression of eight herbicide resistance-related proteins and the down-regulation of two proteins associated with abscisic acid biosynthesis. In addition, high photosynthetic parameters and low glutathione thiotransferase (GST) activity were observed in the quinclorac-resistant E. crus-galli compared with the susceptible biotype, which was consistent with the proteomic sequencing results. Overall, this study demonstrated that the resistant E. crus-galli enhanced its adaptability to quinclorac by improving the photosynthetic efficiency and GST activity

Thin film electrodes from Pt nanorods supported on aligned N-CNTs for proton exchange membrane fuel cells

The enhanced performance of carbon nanotubes (CNTs) over carbon black as a catalyst support and the outstanding catalytic activities of one-dimensional (1D) Pt nanostructures endow them big potential for applications in fuel cells. However, the research has been mainly focused on the materials, and a combination of both 1D Pt nanostructures and CNTs to fabricate practical high power performance fuel cell electrodes still remains a challenge. In this work, we demonstrate catalyst electrodes from Pt nanorods grown on aligned nitrogen doped CNTs for proton exchange membrane fuel cell (PEMFC) applications. Short Pt nanorods are grown on CNTs deposited directly on 16 cm2 carbon paper gas diffusion layers (GDLs) via plasma enhanced chemical vapour deposition (PECVD) and nitrided using active screen plasma (ASP) treatment, which are directly employed as cathodes for H2/air PEMFCs. The thin open catalyst layer effectively enhances mass transfer performance and, with a less than half of the Pt loading, 1.23 fold power density is achieved as compared with that from commercial Pt/C catalysts. A better durability is also confirmed which can be attributed to the good structure stability of nanorods and the enhancement effects from the N-CNT support

Cyclostratigraphy and paleoclimate analysis of the Lingshui Formation in Changchang Sag, Qiongdongnan Basin, China

The Qiongdongnan Basin, located in the sea between Hainan Island and the Xisha Islands, is a faulted Cenozoic basin on the northern continental margin of the South China Sea. The Changchang Sag, situated in the eastern part of the central depressional zone in the deepwater area of the Qiongdongnan Basin, exhibits a near EW-striking morphology and represents an important potential target for oil/gas exploration. However, the age of the interface of the Lingshui Formation remains controversial, which hinders a comprehensive understanding of the tectonic evolution and hydrocarbon accumulation pattern in the Changchang Sag. This study focuses on well A, located in the depositional center of the Changchang Sag, and employs cyclostratigraphic analysis to identify cyclic signals of the Milankovitch cycles recorded in the sedimentary strata. Spectral analysis of natural gamma logging data from this well reveals the presence of 405 kyr long eccentricity cycles, 100 kyr short eccentricity cycles, 39.3 kyr obliquity cycles, and 20.58 kyr age precession cycles. By employing astronomical tuning, a “floating” astronomical time scale of the Lingshui Formation spanning 5.483 million years (Myr) is established. The top interface of the Oligocene in the International Geological Time Scale 2020 (GTS2020), with a geological age of 23.03 Ma, is used as the time anchor to establish a high-precision absolute astronomical age framework for the Lingshui Formation. The results indicate that the bottom interface of the first member of the Lingshui Formation is dated at 23.79 Ma, the bottom interface of the second member is dated at 25.08 Ma, and the bottom interface of the third member is dated at 28.51 Ma. Additionally, the average sedimentation rate during this period is estimated to be 9.261 cm/kyr. Furthermore, paleoclimate and paleoenvironmental reconstructions were carried out through quantitative analysis of spore and pollen assemblages, as well as foraminifera within the Lingshui Formation. These analyses suggest that the deposition of the Lingshui Formation occurred under warm and humid temperate climatic conditions. The results of paleoclimate proxy analysis and comparative fitting analysis of the astronomical time scale confirm that the climate evolution during this period was influenced by astronomical orbital forces, such as eccentricity and precession