135 research outputs found
Can we achieve controlled localised grading of continuous fibre polymer composite properties using out-of-autoclave process?
Manufacturing Multi-Matrix Composites:Out-of-Vacuum Bag Consolidation
The formation of porosity is a major challenge in any composite manufacturing process, particularly in the absence of vacuum assistance. Highly localized injection of polymer matrix into regions of interest in a dry preform is a route to manufacturing multi-matrix fiber-reinforced composites with high filler concentrations, which are otherwise difficult to achieve. Unlike traditional composites, such multi-matrix fiber-reinforced composite systems, which combine multiple resins in continuous form, offer improved structural performance around stress concentrators and multifunctional capabilities. As the process lacks vacuum assistance, porosity becomes a primary issue to be addressed. This paper presents a rheo-kinetic coupled rapid consolidation procedure for optimizing the quality of localized matrix patches. The procedure involves manufacturing trials and analytical consolidation models to determine the best processing program for minimal voidage in the patch. The results provide a step toward an efficient manufacturing process for the optimal design of multi-matrix composites without the need for complex vacuum bag arrangements, thus reducing cost and time while opening avenues to improve overall composite performance
Towards implementing high-precision mapping of structural and functional properties in composite components
Simple phosphinate ligands access zinc clusters identified in the synthesis of zinc oxide nanoparticles
The bottom-up synthesis of ligand-stabilized functional nanoparticles from molecular precursors is widely applied but is difficult to study mechanistically. Here we use 31P NMR spectroscopy to follow the trajectory of phosphinate ligands during the synthesis of a range of ligated zinc oxo clusters, containing 4, 6 and 11 zinc atoms. Using an organometallic route, the clusters interconvert rapidly and self-assemble in solution based on thermodynamic equilibria rather than nucleation kinetics. These clusters are also identified in situ during the synthesis of phosphinate-capped zinc oxide nanoparticles. Unexpectedly, the ligand is sequestered to a stable Zn11 cluster during the majority of the synthesis and only becomes coordinated to the nanoparticle surface, in the final step. In addition to a versatile and accessible route to (optionally doped) zinc clusters, the findings provide an understanding of the role of well-defined molecular precursors during the synthesis of small (2–4 nm) nanoparticles
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Discovery of next-generation battery electrodes using topology optimisation
Energy storage systems (ESSs) are essential components for the delivery of uninterrupted
renewable energy of the future. A key stride towards the development of these systems revolves
around the design of insertion-electrode batteries (IEBs). However, battery cell performance
metrics of capacity and rate capability in these batteries are limited by inefficient ion and electron
transport due to the complex transport channels the ions must navigate to reach storage sites – a
fundamental limitation of slurry-cast (SC) type electrodes. We present a gradient-driven approach
to derive optimal electrode architecture, constrained only by the underlying multiphysics system
defining transport mechanisms in and across solid and liquid phases. The derived framework
challenges the traditional manufacturing techniques for electrodes, inspiring novel strategies for
deriving new high-performance electrodes.Mechanical Engineerin
Carbon nanotube grafted silica fibres: Characterising the interface at the single fibre level
Interfacially-grafted Single Wall Carbon Nanotube / Poly (vinyl alcohol) Composite Fibers
Nanocomposites are critically influenced by interfacial interactions between the reinforcement and matrix. Polyvinyl alcohol (PVOH) of varying molecular weights were prepared and grafted to single-walled carbon nanotubes (SWCNTs), to improve the interfacial interaction with a homopolymer PVOH matrix. Nanocomposite fibers were coagulation spun across a broad range of loading fractions, controlled by the spinning dope composition. An intermediate grafted-PVOH molecular weight (10 kDa) maximized grafting ratio, and the final composite mechanical performance; the positive effects were attributed to the increased degree of dispersion of the SWCNTs in the dope, as well as the favorable interface. The PVOH grafting increased the stability of the SWCNT loading fractions (up to 45 wt.%), offering increased strength (up to 1100 MPa) and stiffness (up to 38.5 GPa); at the same time, strain to-failures remained high (up to 23.3%), resulting in high toughness (up to 125 J g-1)
Depleting Depletion: Maintaining Single-Walled Carbon Nanotube Dispersions after Graft-to Polymer Functionalization
Grafting polymers onto single-walled carbon nanotubes (SWCNTs) usefully alters properties but does not typically yield stable, solvated species directly. Despite the expectation of steric stabilization, a damaging (re)dispersion step is usually necessary. Here, poly(vinyl acetate)s (PVAc) of varying molecular weights are grafted to individualized, reduced SWCNTs at different concentrations to examine the extent of reaction and degree of solvation. The use of higher polymer concentrations leads to an increase in grafting ratio (weight fraction of grafted polymer relative to the SWCNT framework), approaching the limit of random sequentially adsorbed Flory ‘mushrooms’ on the surface. However, at higher polymer concentrations, a larger percentage of SWCNTs precipitate during the reaction; an effect which is more significant for larger weight polymers. The precipitation is attributed to depletion interactions generated by ungrafted homopolymer overcoming Coulombic repulsion of adjacent like-charged SWCNTs; a simple model is proposed. Larger polymers and greater degrees of functionalization favor stable solvation, but larger and more concentrated homopolymers increase depletion aggregation. By using low concentrations (25 μM) of larger molecular weight PVAc (10 kDa), up to 65% of grafted SWCNTs were retained in solution (at 65 μg mL-1) directly after the reaction
Property and Shape Modulation of Carbon Fibers Using Lasers
An exciting challenge is to create
unduloid-reinforcing fibers
with tailored dimensions to produce synthetic composites with improved
toughness and increased ductility. Continuous carbon fibers, the state-of-the-art
reinforcement for structural composites, were modified via controlled
laser irradiation to result in expanded outwardly tapered regions,
as well as fibers with Q-tip (cotton-bud) end shapes. A pulsed laser
treatment was used to introduce damage at the single carbon fiber
level, creating expanded regions at predetermined points along the
lengths of continuous carbon fibers, while maintaining much of their
stiffness. The range of produced shapes was quantified and correlated
to single fiber tensile properties. Mapped Raman spectroscopy was
used to elucidate the local compositional and structural changes.
Irradiation conditions were adjusted to create a swollen weakened
region, such that fiber failure occurred in the laser treated region
producing two fiber ends with outwardly tapered ends. Loading the
tapered fibers allows for viscoelastic energy dissipation during fiber
pull-out by enhanced friction as the fibers plough through a matrix.
In these tapered fibers, diameters were locally increased up to 53%,
forming outward taper angles of up to 1.8°. The tensile strength
and strain to failure of the modified fibers were significantly reduced,
by 75% and 55%, respectively, ensuring localization of the break in
the expanded region; however, the fiber stiffness was only reduced
by 17%. Using harsher irradiation conditions, carbon fibers were completely
cut, resulting in cotton-bud fiber end shapes. Single fiber pull-out
tests performed using these fibers revealed a 6.75-fold increase in
work of pull-out compared to pristine carbon fibers. Controlled laser
irradiation is a route to modify the shape of continuous carbon fibers
along their lengths, as well as to cut them into controlled lengths
leaving tapered or cotton-bud shapes
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