924 research outputs found
Homogeneous Gold Catalysis through Relativistic Effects: Addition of Water to Propyne
In the catalytic addition of water to propyne the Au(III) catalyst is not
stable under non-relativistic conditions and dissociates into a Au(I) compound
and Cl2. This implies that one link in the chain of events in the catalytic
cycle is broken and relativity may well be seen as the reason why Au(III)
compounds are effective catalysts.Comment: 12 pages, 3 figures, 1 tabl
Strain bursts in plastically deforming Molybdenum micro- and nanopillars
Plastic deformation of micron and sub-micron scale specimens is characterized
by intermittent sequences of large strain bursts (dislocation avalanches) which
are separated by regions of near-elastic loading. In the present investigation
we perform a statistical characterization of strain bursts observed in
stress-controlled compressive deformation of monocrystalline Molybdenum
micropillars. We characterize the bursts in terms of the associated elongation
increments and peak deformation rates, and demonstrate that these quantities
follow power-law distributions that do not depend on specimen orientation or
stress rate. We also investigate the statistics of stress increments in between
the bursts, which are found to be Weibull distributed and exhibit a
characteristic size effect. We discuss our findings in view of observations of
deformation bursts in other materials, such as face-centered cubic and
hexagonal metals.Comment: 14 pages, 8 figures, submitted to Phil Ma
Identification of the slow E3 transition 136mCs -> 136Cs with conversion electrons
We performed at ISOLDE the spectroscopy of the decay of the 8- isomer in
136Cs by and conversion-electron detection. For the first time the excitation
energy of the isomer and the multipolarity of its decay have been measured. The
half-life of the isomeric state was remeasured to T1/2 = 17.5(2) s. This isomer
decays via a very slow 518 keV E3 transition to the ground state. In addition
to this, a much weaker decay branch via a 413 keV M4 and a subsequent 105 keV
E2 transition has been found. Thus we have found a new level at 105 keV with
spin 4+ between the isomeric and the ground state. The results are discussed in
comparison to shell model calculations.Comment: Phys. Rev. C accepted for publicatio
First identification of large electric monopole strength in well-deformed rare earth nuclei
Excited states in the well-deformed rare earth isotopes Sm and
Er were populated via ``safe'' Coulomb excitation at the Munich MLL
Tandem accelerator. Conversion electrons were registered in a cooled Si(Li)
detector in conjunction with a magnetic transport and filter system, the
Mini-Orange spectrometer. For the first excited state in Sm at
1099 keV a large value of the monopole strength for the transition to the
ground state of could be extracted. This confirms the interpretation of the lowest
excited state in Sm as the collective -vibrational
excitation of the ground state. In Er the measured large electric
monopole strength of clearly identifies the state at 1934 keV to be the
-vibrational excitation of the ground state.Comment: submitted to Physics Letters
From sticky-hard-sphere to Lennard-Jones-type clusters.
A relation M_{SHS→LJ} between the set of nonisomorphic sticky-hard-sphere clusters M_{SHS} and the sets of local energy minima M_{LJ} of the (m,n)-Lennard-Jones potential V_{mn}^{LJ}(r)=ɛ/n-m[mr^{-n}-nr^{-m}] is established. The number of nonisomorphic stable clusters depends strongly and nontrivially on both m and n and increases exponentially with increasing cluster size N for N≳10. While the map from M_{SHS}→M_{SHS→LJ} is noninjective and nonsurjective, the number of Lennard-Jones structures missing from the map is relatively small for cluster sizes up to N=13, and most of the missing structures correspond to energetically unfavorable minima even for fairly low (m,n). Furthermore, even the softest Lennard-Jones potential predicts that the coordination of 13 spheres around a central sphere is problematic (the Gregory-Newton problem). A more realistic extended Lennard-Jones potential chosen from coupled-cluster calculations for a rare gas dimer leads to a substantial increase in the number of nonisomorphic clusters, even though the potential curve is very similar to a (6,12)-Lennard-Jones potential.epsr
Excited States of Ladder-type Poly-p-phenylene Oligomers
Ground state properties and excited states of ladder-type paraphenylene
oligomers are calculated applying semiempirical methods for up to eleven
phenylene rings. The results are in qualitative agreement with experimental
data. A new scheme to interpret the excited states is developed which reveals
the excitonic nature of the excited states. The electron-hole pair of the
S1-state has a mean distance of approximately 4 Angstroem.Comment: 24 pages, 21 figure
Yielding and irreversible deformation below the microscale: Surface effects and non-mean-field plastic avalanches
Nanoindentation techniques recently developed to measure the mechanical
response of crystals under external loading conditions reveal new phenomena
upon decreasing sample size below the microscale. At small length scales,
material resistance to irreversible deformation depends on sample morphology.
Here we study the mechanisms of yield and plastic flow in inherently small
crystals under uniaxial compression. Discrete structural rearrangements emerge
as series of abrupt discontinuities in stress-strain curves. We obtain the
theoretical dependence of the yield stress on system size and geometry and
elucidate the statistical properties of plastic deformation at such scales. Our
results show that the absence of dislocation storage leads to crucial effects
on the statistics of plastic events, ultimately affecting the universal scaling
behavior observed at larger scales.Comment: Supporting Videos available at
http://dx.plos.org/10.1371/journal.pone.002041
Comparison of the atmosphere above the South Pole, Dome C and Dome A: first attempt
The atmospheric properties above three sites (Dome C, Dome A and the South
Pole) on the Internal Antarctic Plateau are investigated for astronomical
applications using the monthly median of the analyses from ECMWF (the European
Centre for Medium-Range Weather Forecasts). Radiosoundings extended on a yearly
time scale at the South Pole and Dome C are used to quantify the reliability of
the ECMWF analyses in the free atmosphere as well as in the boundary and
surface layers, and to characterize the median wind speed in the first 100 m
above the two sites. Thermodynamic instability properties in the free
atmosphere above the three sites are quantified with monthly median values of
the Richardson number. We find that the probability to trigger thermodynamic
instabilities above 100 m is smaller on the Internal Antarctic Plateau than on
mid-latitude sites. In spite of the generally more stable atmospheric
conditions of the Antarctic sites compared to mid-latitude sites, Dome C shows
worse thermodynamic instability conditions than those predicted above the South
Pole and Dome A above 100 m. A rank of the Antarctic sites done with respect to
the strength of the wind speed in the free atmosphere (ECMWF analyses) as well
as the wind shear in the surface layer (radiosoundings) is presented.Comment: Accepted for publishing in MNRAS. 14 pages, 10 figures. The
definitive version is available at http://www.blackwell-synergy.co
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