Geochemical Endmembers preserved in Gale Crater: A tale of two mudstones and their compositional differences according to ChemCam

Gale crater contains two fine-grained mudstone sedimentary units: The Sheepbed mudstone member, and the Murray formation mud-stones. These mudstones formed as part of an ancient fluviolacustrine system. The NASA Curiosity rover has analysed these mudstone units using the Chemistry and Camera (ChemCam), Alpha Particle X-ray Spectrometer (APXS) and Chemistry and Mineralogy (CheMin) onboard instrument suites. Subsequent mineralogical analyses have uncovered a wide geochemical and mineralogical diversity across and within these two mudstone formations. This study aims to determine the principal cause (alteration or source region) of this geochemical variation through a statistical analysis of the ChemCam dataset up to sol 1482, including the lower to middle Murray formation

Development of a viable route for lithium-6 supply of DEMO and future fusion power plants

In the European DEMO program, the design development of a demonstration power plant (DEMO) is currently in its pre-conceptual phase. In DEMO, breeding blankets will use large quantities of lithium, enriched in the isotope lithium-6 (6Li), for breeding the tritium needed to feed the DT fusion reaction. Unfortunately, enriched lithium is commercially not available in the required quantities, which is threatening the success of future power plant applications of nuclear fusion. Even if the manufacturing of the breeding blankets is still two decades ahead of us, it is now mandatory to address the topic of lithium-6 supply and to make sure that a viable supply (and reprocessing) route is available when needed. This paper presents an unbiased systems engineering approach assessing a number of available lithium isotope separation methods by defining requirements, rating them systematically and finally calculating a ranking number expressing the value of different methods. As a result, we suggest using a chemical exchange method based on a lithium amalgam system, but including some important improvements leading to a more efficient and ‘clean’ process (the ICOMAX process) in comparison with the formerly used COLEX process. Furthermore, by modelling activities and experiments in the KIT mercury laboratory (HgLab Karlsruhe), it is shown which work has to be done in the next years to make sure that the technical-scale process is available in time to supply DEMO and future fusion power plants by middle of the 21st century

Operational Tritium Inventories in the EU-DEMO Fuel Cycle

The European Demonstration Fusion Power Reactor (EU-DEMO) has to operate in a completely tritium self-sufficient mode after initial start-up, which includes producing excess tritium to allow the start-up of other reactors. The initial start-up inventory is mainly dictated by operational inventories in the fuel cycle (FC). Advances in FC technologies and immediate recycling of a large fraction of the torus exhaust gas in the direct internal recycling loop are expected to contribute greatly to an overall low operational inventory. The remainder of the torus exhaust gas, as well as tritium from the blankets, nevertheless requires treatment in the tritium plant in order to perform the necessary purification and isotope rebalancing. Here, the employed systems still feature significant operational inventories and predominantly require steady-state operation in order to maximize their performance. In this paper the operational tritium inventories in the major FC systems are reported based on the pre-concept FC design. Additionally, major dependencies of these inventories on key design drivers of the FC are discussed. It is predicted that the EU-DEMO FC will be able to operate with an overall tritium inventory of less than 2 kg

3D Surface Measurement for Medical Application—Technical Comparison of Two Established Industrial Surface Scanning Systems

In 3D mapping of flexible surfaces (e.g. human faces) measurement errors due to movement or positioning occur. Aggravated by equipment- or researcher-caused mistakes considerable deviations can result. Therefore first the appliances' precision handling and reliability in clinical environment must be established. Aim of this study was to investigate accuracy and precision of two contact-free 3D measurement systems (white light vs. laser). Standard specimens of known diameter for sphere deviation, touch deviation and plane deviation were tested. Both systems are appropriate for medical application acquiring solid data (<mm). The more complex white-light system shows better accuracy at 0.2s measuring time. The laser system is superior concerning robustness, while accuracy is poorer and input time (1.5-2.5s) longer. Due to the clinical demand the white-light system is superior in a laboratory environment, while the laser system is easier to handle under non-laboratory condition

Characterisation of Float Rocks at Ireson Hill, Gale Crater

Float rocks discovered by surface missions on Mars have given unique insights into the sedimentary, diagenetic and igneous processes that have operated throughout the planets history. In addition, Gale sedimentary rocks, both float and in situ, record a combination of source compositions and diagenetic overprints. We examine a group of float rocks that were identified by the Mars Science Laboratory missions Curiosity rover at the Ireson Hill site, circa. sol 1600 using ChemCam LIBS, APXS and images from the MastCam, Mars Hand Lens Imager (MAHLI) and ChemCam Remote Micro-Imager (RMI) cameras. Geochemical data provided by the APXS and ChemCam instruments allow us to compare the compositions of these rocks to known rock types from Gale crater, as well as elsewhere on Mars. Ireson Hill is a 15 m long butte in the Murray formation with a dark cap-ping unit with chemical and stratigraphic consistency with the Stimson formation. A total of 6 float rocks have been studied on the butte

What the Infrared Behaviour of QCD Vertex Functions in Landau gauge can tell us about Confinement

The infrared behaviour of Landau gauge QCD vertex functions is investigated employing a skeleton expansion of the Dyson-Schwinger and Renormalization Group equations. Results for the ghost-gluon, three-gluon, four-gluon and quark-gluon vertex functions are presented. Positivity violation of the gluon propagator, and thus gluon confinement, is demonstrated. Results of the Dyson-Schwinger equations for a finite volume are compared to corresponding lattice data. It is analytically demonstrated that a linear rising potential between heavy quarks can be generated by infrared singularities in the dressed quark-gluon vertex. The selfconsistent mechanism that generates these singularities necessarily entails the scalar Dirac amplitudes of the full vertex and the quark propagator. These can only be present when chiral symmetry is broken, either explicitly or dynamically.Comment: 13 pages, 13 figures; to appear in the Proceedings of ``X Hadron Physics 2007'', Florianopolis, Brazil, March 26 - 31, 200

The igneous end member compositions preserved in Gale Crater sediments

The sedimentary outcrop and float rocks in Gale Crater contain evidence of a mixture of igneous protoliths: basaltic, trachybasaltic, SiO2-rich, and alkali-rich. The fine grain size of many of the sediments offers the possibility of estimating accurate bulk compositions of igneous protoliths. However, the sediments also have undergone extensive diagenesis, veining and silica-rich alteration zones. Here we test a hypothesis that end member igneous compositions are recorded within the Gale Crater sediments, compare to other martian datasets, and distinguish alteration trends from the igneous detrital input sourced in the ancient highlands. We analyse this data from the first 1500 sols of Mars Science Laboratory operations using the Gale stratigraphic column. With over 400,000 ChemCam LIBS spectra, 198 APXS analyses and 19 CheMin analyses, the MSL results provide a unique compositional and stratigraphic sampling of the martian crust. The use of density contours with the large ChemCam dataset allows us to distinguish the key compositional end members from fractionation based on mineral density during deposition, or localised remobilisation during post depositional alteration