14 research outputs found
Optical Probe of Quantum Shot Noise Reduction at a Single-Atom Contact
Visible and infra-red light emitted at a Ag-Ag(111) junction has been
investigated from tunneling to single atom contact conditions with a scanning
tunneling microscope. The light intensity varies in a highly nonlinear fashion
with the conductance of the junction and exhibits a minimum at conductances
close to the conductance quantum. The data are interpreted in terms of current
noise at optical frequencies, which is characteristic of partially open
transport channels
Demokratie auf dem RĂŒckzug? Zur Konfrontation zwischen amerikanischem PrĂ€sidenten und Kongress ĂŒber einen Truppenabzug aus dem Irak
Im US-PrĂ€sidentschaftswahlkampf 2008 ist der Irakkrieg eines der wichtigsten Themen. Die Amerikaner sind allmĂ€hlich kriegsmĂŒde und die Mehrheit befĂŒrwortet einen TruppenrĂŒckzug aus dem Irak. Das brachten bereits der Ausgang der Kongresswahlen im Jahr 2006 sowie regelmĂ€Ăige Meinungsumfragen zum Ausdruck.
Es ist nun anzunehmen, dass in der Ă€ltesten Demokratie der Welt Volkes Wille direkten Einfluss auf die Politik haben mĂŒsste. Doch dies ist nur bedingt der Fall. Besonders PrĂ€sident George W. Bush hat wiederholt klargestellt, dass die Stimmung in der Bevölkerung fĂŒr ihn in der Irakfrage nicht maĂgebend sei. FĂŒr ihn zĂ€hle vielmehr, wie die GenerĂ€le vor Ort die aktuelle Sicherheitslage und die Fortschritte einschĂ€tzen. Dagegen versucht der seit Ende 2006 von Demokraten dominierte Kongress immer wieder, RĂŒckzugsplĂ€ne mit festen Fristen zu etablieren. Bislang ist sein Erfolg jedoch bescheiden.
Vor allem die fehlende UnterstĂŒtzung der Republikaner im Kongress und die Blockadepolitik des PrĂ€sidenten waren dafĂŒr verantwortlich. Hinter der Konfrontation steht eine tiefergehende Auseinandersetzung ĂŒber die Kompetenzverteilung zwischen PrĂ€sident und Kongress bei Kriegsentscheidungen, die in der US-Verfassung in einer Grauzone bleibt.
Stephanie Sohnius verknĂŒpft vor diesem verfassungsrechtlichen Hintergrund die Aufarbeitung der aktuell wichtigsten USauĂenpolitischen Debatte mit der Frage, ob sich die Demokratie in den USA in der Ăra des âKrieges gegen den Terrorismusâ (weiterhin) auf dem RĂŒckzug befindet
Fluorescent single-molecule STM probe
The plasmonic tip of a scanning tunnelling microscope (STM) is functionalized
with a single fluorescent molecule and is scanned on a plasmonic substrate. The
tunneling current flowing through the tip-molecule-substrate junction generates
a narrow-line emission of light corresponding to the fluorescence of the
negatively charged molecule suspended at the apex of the tip, i.e., the
emission of the excited molecular anion (trion). The fluorescence of this
molecular probe is recorded for tip-substrate nanocavities featuring different
plasmonic resonances, for different tip-substrate distances and applied bias
voltages, and on different substrates. We demonstrate that the width of the
emission peak can be used as a probe of the trion-plasmon coupling strength and
that the energy of the emitted photons is governed by the molecule interactions
with its electrostatic environment. Additionally, we theoretically elucidate
why the direct contact of the suspended molecule with the metallic tip does not
totally quench the radiative emission of the molecule.Comment: 9 pages in the main manuscript, including 4 figures, 11 pages in the
supporting info, including 5 figures and 1 tabl
Magnetism of CoPd self-organized alloy clusters on Au(111)
Magnetic properties of gold-encapsulated CoxPd1-x self-organized nano-clusters on Au(111) are analyzed by x-ray magnetic circular dichroism for x = 0.5, 0.7, and 1.0. The clusters are superparamagnetic with a blocking temperature decreasing with increasing Pd concentration, due to a reduction of the out-of-plane anisotropy strength. No magnetic moment is detected on Pd in these clusters, within the detection limit, contrary to thick CoPd films. Both reduction of anisotropy and vanishing Pd moment are attributed to strain. (C) 2013 AIP Publishing LLC
Charged pions from Ni on Ni collisions between 1 and 2 AGeV
Charged pions from Ni + Ni reactions at 1.05, 1.45 and 1.93 AGeV are measured with the FOPI detector. The mean multiplicities per mean number of participants increase with beam energy, in accordance with earlier studies of the Ar + KCl and La + La systems. The pion kinetic energy spectra have concave shape and are fitted by the superposition of two Boltzmann distributions with different temperatures. These apparent temperatures depend only weakly on bombarding energy. The pion angular distributions show a forward/backward enhancement at all energies, but not the enhancement which was observed in case of the Au + Au system. These features also determine the rapidity distributions which are therefore in disagreement with the hypothesis of one thermal source. The importance of the Coulomb interaction and of the pion rescattering by spectator matter in producing these phenomena is discussed
Caracterização da dinùmica da complexação do receptor tipo Toll 4 humano a MD-2
Os receptores tipo Toll desempenham um importante papel na resposta imune inata, reconhecendo tanto padrĂ”es moleculares associados a patĂłgenos (PAMPs), quanto padrĂ”es moleculares associados a danos (DAMPs), liberados sob condiçÔes de injĂșria ou estresse celular. O receptor tipo Toll 4 humano (hTLR4), associado ao seu co-receptor, o fator de diferenciação mielĂłide 2 (MD-2), forma um heterodĂmero caracterizado como responsĂĄvel pelo reconhecimento de lipopolissacarĂdeos bacterianos (LPS), derivados de bactĂ©rias Gram-negativas. Nestes casos, sabe-se que o MD-2 reconhece LPS e promove a dimerização do complexo hTLR4 - MD-2 - LPS, promovendo a sinalização intracelular. JĂĄ foi reportada a ausĂȘncia da associação hTLR4 a MD-2, no reconhecimento de outros ligantes por hTLR4, e, nesses casos, pouco Ă© conhecido a respeito das mudanças estruturais e conformacionais sofridas por este receptor. No presente estudo, empregando a tĂ©cnica de simulação por dinĂąmica molecular, foram exploradas as propriedades dinĂąmicas do complexo de reconhecimento de LPS, hTLR4 - MD-2, bem como investigou-se as implicaçÔes da presença do co-receptor para a biologia estrutural do hTLR4. Os resultados mostram que o receptor apresenta um movimento do tipo pinça, o qual leva a um estado final mais aberto da estrutura em forma de ferradura. Ademais, a estabilidade desta estrutura parece ser influenciada pela presença do co-receptor, MD-2.Toll-like receptors (TLRs) play an important role in innate immunity recognizing pathogen-associated molecular patterns (PAMPs), as also damageassociated molecular patterns (DAMPs), released after cellular injury or stress. Human Toll-Like Receptor 4 (hTLR4) and its co-receptor, myeloid differentiation factor 2 (MD-2), as a heterodimer, is a well-known complex of Gram-negative bacteria lipopolysaccharide (LPS) recognition. In this process, MD-2 recognizes LPS and promotes the dimerization of the complex hTLR4 - MD-2 - LPS, initiating an intracellular immune signaling. Moreover, it has been reported that hTLR4 can also act in the absence of MD-2, in the case of other ligands recognition, and, in these cases, little is known about the structural and conformational changes that hTLR4 structure underwent. In the current study, employing molecular dynamics simulations, we had explored the dynamical properties of the hTLR4 - MD-2 complex and investigated the implications of the co-receptor complexation to the structural biology of hTR4. We observed that the receptor showed a tweezers-like movement, leading to a more oppened final state of its horseshoe-shaped structure. Additionally, the stability of this structure seems to be influenced by the presence of the co-receptor, MD-2
Electroluminescence of monolayer WS in a scanning tunneling microscope: the effect of bias polarity on the spectral and angular distribution of the emitted light
Inelastic electron tunneling in a scanning tunneling microscope (STM) is used
to generate excitons in monolayer tungsten disulfide (WS). Excitonic
electroluminescence is measured both at positive and negative sample bias.
Using optical spectroscopy and Fourier-space optical microscopy, we show that
the bias polarity of the tunnel junction determines the spectral and angular
distribution of the emitted light. At positive sample bias, only emission from
excitonic species featuring an in-plane transition dipole moment is detected.
Based on the spectral distribution of the emitted light, we infer that the
dominant contribution is from charged excitons, i.e., trions. At negative
sample bias, additional contributions from lower-energy excitonic species are
evidenced in the emission spectra and the angular distribution of the emitted
light reveals a mixed character of in-plane and out-of-plane transition dipole
moments
Tip-Induced and Electrical Control of the Photoluminescence Yield of Monolayer WS<sub>2</sub>
The photoluminescence (PL) of monolayer tungsten disulfide
(WS2) is locally and electrically controlled using the
nonplasmonic
tip and tunneling current of a scanning tunneling microscope (STM).
The spatial and spectral distribution of the emitted light is determined
using an optical microscope. When the STM tip is engaged, short-range
PL quenching due to near-field electromagnetic effects is present,
independent of the sign and value of the bias voltage applied to the
tipâsample tunneling junction. In addition, a bias-voltage-dependent
long-range PL quenching is measured when the sample is positively
biased. We explain these observations by considering the native n-doping
of monolayer WS2 and the charge carrier density gradients
induced by electron tunneling in micrometer-scale areas around the
tip position. The combination of wide-field PL microscopy and charge
carrier injection using an STM opens up new ways to explore the interplay
between excitons and charge carriers in two-dimensional semiconductors