311 research outputs found
Magnetoresistance in two-component systems
Two-component systems with equal concentrations of electrons and holes
exhibit non-saturating, linear magnetoresistance in classically strong magnetic
fields. The effect is predicted to occur in finite-size samples at charge
neutrality in both disorder- and interaction-dominated regimes. The phenomenon
originates in the excess quasiparticle density developing near the edges of the
sample due to the compensated Hall effect. The size of the boundary region is
of the order of the electron-hole recombination length that is inversely
proportional to the magnetic field. In narrow samples and at strong enough
magnetic fields, the boundary region dominates over the bulk leading to linear
magnetoresistance. Our results are relevant for semimetals and narrow-band
semiconductors including most of the topological insulators.Comment: 11 pages, 3 figure
Initial Stages of Sodium Deposition onto Au(111) from [MPPip][TFSI]: An InâSitu STM Study for SodiumâIon Battery Electrolytes
Sodium-ion batteries are promising candidates for post-lithium-ion batteries. While sodium has a less negative standard electrode potential compared to lithium, it is still a strong reducing agent. Ionic liquids are suitable solvents for sodium metal batteries, since metallic sodium is very reactive, particularly with water and molecules containing acidic hydrogen atoms. In this study, the initial stages of electrodeposition of sodium on Au(111) from N-methyl-N-propylpiperidinium [MPPip] bis(trifluoromethanesulfonyl)imide [TFSI] were studied using voltammetry and in-situ scanning tunnelling microscopy. Four subsequent underpotential deposition stages were observed: (i)â
nucleation at the Au(111) reconstruction elbows, followed by (ii)â
growth of small monoatomically high islands that form (iii)â
a smooth layer via coalescence, and (iv)â
further island growth on top of the existing layers. The electrocrystallisation mode changed from smooth layer formation to 3D growth, resulting in cauliflower-like structures. The deposition process was accompanied by simultaneous alloy formation
Inductive Heating for Research in Electrocatalysis: Theory, Practical Considerations, and Examples
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Digital Orthopaedics: A Glimpse Into the Future in the Midst of a Pandemic.
BackgroundThe response to COVID-19 catalyzed the adoption and integration of digital health tools into the health care delivery model for musculoskeletal patients. The change, suspension, or relaxation of Medicare and federal guidelines enabled the rapid implementation of these technologies. The expansion of payment models for virtual care facilitated its rapid adoption. The authors aim to provide several examples of digital health solutions utilized to manage orthopedic patients during the pandemic and discuss what features of these technologies are likely to continue to provide value to patients and clinicians following its resolution.ConclusionThe widespread adoption of new technologies enabling providers to care for patients remotely has the potential to permanently change the expectations of all stakeholders about the way care is provided in orthopedics. The new era of Digital Orthopaedics will see a gradual and nondisruptive integration of technologies that support the patient's journey through the successful management of their musculoskeletal disease
Electrodeposition of Zinc onto Au(111) and Au(100) from the Ionic Liquid [MPPip][TFSI]
The improvement of rechargeable zinc/air batteries was a hot topic in recent years. Predominantly, the influence of water and additives on the structure of the Zn deposit and the possible dendrite formation were studied. However, the effect of the surface structure of the underlying substrate was not focused on in detail, yet. We now show the differences in electrochemical deposition of Zn onto Au(111) and Au(100) from the ionic liquid N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide. The fundamental processes were initially characterized via cyclic voltammetry and in situ scanning tunnelling microscopy. Bulk deposits were then examined using Auger electron spectroscopy and scanning electron microscopy. Different structures of Zn deposits are observed during the initial stages of electrocrystallisation on both electrodes, which reveals the strong influence of the crystallographic orientation on the metal deposition of zinc on gold
The Green Bank North Celestial Cap Pulsar Survey. IV: Four New Timing Solutions
We present timing solutions for four pulsars discovered in the Green Bank
Northern Celestial Cap (GBNCC) survey. All four pulsars are isolated with spin
periods between 0.26s and 1.84s. PSR J00382501 has a 0.26s
period and a period derivative of ,
which is unusually low for isolated pulsars with similar periods. This low
period derivative may be simply an extreme value for an isolated pulsar or it
could indicate an unusual evolution path for PSR J00382501, such as a
disrupted recycled pulsar (DRP) from a binary system or an orphaned central
compact object (CCO). Correcting the observed spin-down rate for the Shklovskii
effect suggests that this pulsar may have an unusually low space velocity,
which is consistent with expectations for DRPs. There is no X-ray emission
detected from PSR J00382501 in an archival swift observation, which suggests
that it is not a young orphaned CCO. The high dispersion measure of PSR
J1949+3426 suggests a distance of 12.3kpc. This distance indicates that PSR
J1949+3426 is among the most distant 7% of Galactic field pulsars, and is one
of the most luminous pulsars.Comment: 7 pages, 5 figure
Versatile 3D-Printed Micro-Reference Electrodes for Aqueous and Non-Aqueous Solutions
While numerous reference electrodes suitable for aqueous electrolytes exist, there is no well-defined standard for non-aqueous electrolytes. Furthermore, reference electrodes are often large and do not meet the size requirements for small cells. In this work, we present a simple method for fabricating stable 3D-printed micro-reference electrodes. The prints are made from polyvinylidene fluoride, which is chemically inert in strong acids, bases, and commonly used non-aqueous solvents. We chose six different reference systems based on Ag, Cu, Zn, and Na, including three aqueous and three non-aqueous systems to demonstrate the versatility of the approach. Subsequently, we conducted cyclic voltammetry experiments and measured the potential difference between the aqueous homemade reference electrodes and a commercial Ag/AgCl-electrode. For the non-aqueous reference electrodes, we chose the ferrocene redox couple as an internal standard. From these measurements, we deduced that this new class of micro-reference electrodes is leak-tight and shows a stable electrode potential
Coordinated optimization of visual cortical maps (II) Numerical studies
It is an attractive hypothesis that the spatial structure of visual cortical
architecture can be explained by the coordinated optimization of multiple
visual cortical maps representing orientation preference (OP), ocular dominance
(OD), spatial frequency, or direction preference. In part (I) of this study we
defined a class of analytically tractable coordinated optimization models and
solved representative examples in which a spatially complex organization of the
orientation preference map is induced by inter-map interactions. We found that
attractor solutions near symmetry breaking threshold predict a highly ordered
map layout and require a substantial OD bias for OP pinwheel stabilization.
Here we examine in numerical simulations whether such models exhibit
biologically more realistic spatially irregular solutions at a finite distance
from threshold and when transients towards attractor states are considered. We
also examine whether model behavior qualitatively changes when the spatial
periodicities of the two maps are detuned and when considering more than 2
feature dimensions. Our numerical results support the view that neither minimal
energy states nor intermediate transient states of our coordinated optimization
models successfully explain the spatially irregular architecture of the visual
cortex. We discuss several alternative scenarios and additional factors that
may improve the agreement between model solutions and biological observations.Comment: 55 pages, 11 figures. arXiv admin note: substantial text overlap with
arXiv:1102.335
Coverage, Continuity and Visual Cortical Architecture
The primary visual cortex of many mammals contains a continuous
representation of visual space, with a roughly repetitive aperiodic map of
orientation preferences superimposed. It was recently found that orientation
preference maps (OPMs) obey statistical laws which are apparently invariant
among species widely separated in eutherian evolution. Here, we examine whether
one of the most prominent models for the optimization of cortical maps, the
elastic net (EN) model, can reproduce this common design. The EN model
generates representations which optimally trade of stimulus space coverage and
map continuity. While this model has been used in numerous studies, no
analytical results about the precise layout of the predicted OPMs have been
obtained so far. We present a mathematical approach to analytically calculate
the cortical representations predicted by the EN model for the joint mapping of
stimulus position and orientation. We find that in all previously studied
regimes, predicted OPM layouts are perfectly periodic. An unbiased search
through the EN parameter space identifies a novel regime of aperiodic OPMs with
pinwheel densities lower than found in experiments. In an extreme limit,
aperiodic OPMs quantitatively resembling experimental observations emerge.
Stabilization of these layouts results from strong nonlocal interactions rather
than from a coverage-continuity-compromise. Our results demonstrate that
optimization models for stimulus representations dominated by nonlocal
suppressive interactions are in principle capable of correctly predicting the
common OPM design. They question that visual cortical feature representations
can be explained by a coverage-continuity-compromise.Comment: 100 pages, including an Appendix, 21 + 7 figure
PirB regulates a structural substrate for cortical plasticity
Experience-driven circuit changes underlie learning and memory. Monocular deprivation (MD) engages synaptic mechanisms of ocular dominance (OD) plasticity and generates robust increases in dendritic spine density on L5 pyramidal neurons. Here we show that the paired immunoglobulin-like receptor B (PirB) negatively regulates spine density, as well as the threshold for adult OD plasticity. In PirB(-/-) mice, spine density and stability are significantly greater than WT, associated with higher-frequency miniature synaptic currents, larger long-term potentiation, and deficient long-term depression. Although MD generates the expected increase in spine density in WT, in PirB(-/-) this increase is occluded. In adult PirB(-/-), OD plasticity is larger and more rapid than in WT, consistent with the maintenance of elevated spine density. Thus, PirB normally regulates spine and excitatory synapse density and consequently the threshold for new learning throughout life
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