Development of battery separator composites

Improved inorganic-organic separators developed by NASA were commercially prepared. A single-ply asbestos substrate was developed, as well as alternative substrates based on cellulose and on polypropylene fibers. The single-ply asbestos was bound with butyl rubber and was functionally superior to the formerly used polyphenylene oxide saturated sheet. Commercially prepared separators exhibited better measured separator properties than the NASA standard. Cycle life in Ni/Zn and Ag/Zn cells was related to substrate, decreasing in the order; asbestos cellulose paper nonwoven polypropylene. The cycle life of solvent-coated separators was better than aqueous in Ni/Zn cells, while aqueous coatings were better in Ag/Zn cells

Alkaline battery, separator therefore

An improved battery separator for alkaline battery cells has low resistance to electrolyte ion transfer and high resistance to electrode ion transfer. The separator is formed by applying an improved coating to an electrolyte absorber. The absorber, preferably, is a flexible, fibrous, and porous substrate that is resistant to strong alkali and oxidation. The coating composition includes an admixture of a polymeric binder, a hydrolyzable polymeric ester and inert fillers. The coating composition is substantially free of reactive fillers and plasticizers commonly employed as porosity promoting agents in separator coatings. When the separator is immersed in electrolyte, the polymeric ester of the film coating reacts with the electrolyte forming a salt and an alcohol. The alcohol goes into solution with the electrolyte while the salt imbibes electrolyte into the coating composition. When the salt is formed, it expands the polymeric chains of the binder to provide a film coating substantially permeable to electrolyte ion transfer but relatively impermeable to electrode ion transfer during use

A Survey for Low-Surface-Brightness Galaxies Around M31. I. The Newly Discovered Dwarf Andromeda V

We present images and a color-magnitude diagram for And V, a new dwarf spheroidal companion to M31 that was found using a digital filtering technique applied to 1550 square degrees of the second Palomar Sky Survey. And V resolves into stars easily in follow-up 4-m V- and I-band images, from which we deduce a distance of 810 +/- 45 kpc using the tip of the red giant branch method. Within the uncertainties, this distance is identical to the Population II distances for M31 and, combined with a projected separation of 112 kpc, provides strong support for a physical association between the two galaxies. There is no emission from And V detected in H alpha, 1.4 GHz radio continuum, or IRAS bandpasses, and there is no young population seen in the color-magnitude diagram that might suggest that And V is an irregular. Thus, the classification as a new dwarf spheroidal member of the Local Group seems secure. With an extinction-corrected central surface brightness of 25.2 V mag per square arcsec, a mean metal abundance of [Fe/H] approximately -1.5, and no evidence for upper AGB stars, And V resembles And I & III.Comment: Accepted for publication in The Astronomical Journal, November 1998 issue; 4 embedded PostScript figures, 4 JPEG figures; see http://aloe.tuc.noao.edu/jacoby/dwarfs.html for a complete full-resolution PostScript versio

SMM behaviour and magnetocaloric effect in heterometallic 3d-4f coordination clusters with high azide : metal ratios

We present the synthesis and characterization of heterometallic compounds with a very large azide to metal ratio and fascinating magnetic properties

The median and the mode as robust meta-analysis estimators in the presence of small-study effects and outliers

Meta-analyses based on systematic literature reviews are commonly used to obtain a quantitative summary of the available evidence on a given topic. However, the reliability of any meta-analysis is constrained by that of its constituent studies. One major limitation is the possibility of small-study effects, when estimates from smaller and larger studies differ systematically. Small-study effects may result from reporting biases (ie, publication bias), from inadequacies of the included studies that are related to study size, or from reasons unrelated to bias. We propose two estimators based on the median and mode to increase the reliability of findings in a meta-analysis by mitigating the influence of small-study effects. By re-examining data from published meta-analyses and by conducting a simulation study, we show that these estimators offer robustness to a range of plausible bias mechanisms, without making explicit modelling assumptions. They are also robust to outlying studies without explicitly removing such studies from the analysis. When meta-analyses are suspected to be at risk of bias because of small-study effects, we recommend reporting the mean, median and modal pooled estimates.</p

The HELLAS2XMM survey: IV. Optical identifications and the evolution of the accretion luminosity in the Universe

We present results from the photometric and spectroscopic identification of 122 X-ray sources recently discovered by XMM-Newton in the 2-10 keV band (the HELLAS2XMM 1dF sample). Their flux cover the range 8E-15-4E-13 cgs and the total area surveyed is 0.9 deg2. About 20% of the hard X-ray selected sources have an X-ray to optical flux ratio (X/O) ten times or more higher than that of optically selected AGN. Unlike the faint sources found in the ultra-deep Chandra and XMM-Newton surveys, which reach X-ray (and optical) fluxes more than one order of magnitude lower than the HELLAS2XMM survey sources, many of the extreme X/O sources in our sample have R<=25 and are therefore accessible to optical spectroscopy. We report the identification of 13 sources with X/O>10: 8 are narrow line QSO (i.e. QSO2), four are broad line QSO. We use a combined sample of 317 hard X-ray selected sources (HELLAS2XMM 1dF, CDFN 1Msec, SSA13 and Lockman Hole flux limited samples), 221 with measured z, to evaluate the cosmological evolution of the hard X-ray source's number and luminosity densities. Looking backward in time, the low luminosity sources (logL(2-10keV) = 43-44 erg/s) increase in number at a rate different than the high luminosity sources (logL(2-10keV)>44.5 erg/s), reaching a maximum around z=1 and then levelling off beyond z=2. This translates into an accretion driven luminosity density which is dominated by sources with logL(2-10keV) < 44.5 erg/s up to at least z=1, while the contribution of the same sources and of those with logL(2-10keV)>44.5 erg/s appear to be comparable between z=2 and 4.Comment: v2, minor changes, A&A in pres

On the propagation of jump discontinuities in relativistic cosmology

A recent dynamical formulation at derivative level \ptl^{3}g for fluid spacetime geometries $({\cal M}, {\bf g}, {\bf u})$, that employs the concept of evolution systems in first-order symmetric hyperbolic format, implies the existence in the Weyl curvature branch of a set of timelike characteristic 3-surfaces associated with propagation speed |v| = \sfrac{1}{2} relative to fluid-comoving observers. We show it is the physical role of the constraint equations to prevent realisation of jump discontinuities in the derivatives of the related initial data so that Weyl curvature modes propagating along these 3-surfaces cannot be activated. In addition we introduce a new, illustrative first-order symmetric hyperbolic evolution system at derivative level \ptl^{2}g for baryotropic perfect fluid cosmological models that are invariant under the transformations of an Abelian $G_{2}$ isometry group.Comment: 19 pages, 1 table, REVTeX v3.1 (10pt), submitted for publication to Physical Review D; added Report-No, corrected typo

Using Both Sides of Your Brain: The Case for Rapid Interhemispheric Switching

Individual brain hemispheres are often specialized for specific aspects of a behavior. How both sides of the brain coordinate their output to produce a perfectly seamless behavior is not known. Songbirds appear to achieve this by rapidly switching back and forth between hemispheres