Infrared spectroscopy of phytochrome and model pigments

Fourier-transform infrared difference spectra between the red-absorbing and far-red-absorbing forms of oat phytochrome have been measured in H2O and 2H2O. The difference spectra are compared with infrared spectra of model compounds, i.e. the (5Z,10Z,15Z)- and (5Z,10Z,15E)-isomers of 2,3,7,8,12,13,17,18-octaethyl-bilindion (Et8-bilindion), 2,3-dihydro-2,3,7,8,12,13,17,18-octaethyl-bilindion (H2Et8-bilindion), and protonated H2Et8-bilindion in various solvents. The spectra of the model compounds show that only for the protonated forms can clear differences between the two isomers be detected. Since considerable differences are present between the spectra of Et8-bilindion and H2Et8-bilindion, it is concluded that only the latter compound can serve as a model system of phytochrome. The 2H2O effect on the difference spectrum of phytochrome supports the view that the chromophore in red-absorbing phytochrome is protonated and suggests, in addition, that it is also protonated in far-red-absorbing phytochrome. The spectra show that protonated carboxyl groups are influenced. The small amplitudes in the difference spectra exclude major changes of protein secondary structure

On the derivative of the associated Legendre function of the first kind of integer order with respect to its degree

In our recent works [R. Szmytkowski, J. Phys. A 39 (2006) 15147; corrigendum: 40 (2007) 7819; addendum: 40 (2007) 14887], we have investigated the derivative of the Legendre function of the first kind, $P_{\nu}(z)$, with respect to its degree $\nu$. In the present work, we extend these studies and construct several representations of the derivative of the associated Legendre function of the first kind, $P_{\nu}^{\pm m}(z)$, with respect to the degree $\nu$, for $m\in\mathbb{N}$. At first, we establish several contour-integral representations of $\partial P_{\nu}^{\pm m}(z)/\partial\nu$. They are then used to derive Rodrigues-type formulas for $[\partial P_{\nu}^{\pm m}(z)/\partial\nu]_{\nu=n}$ with $n\in\mathbb{N}$. Next, some closed-form expressions for $[\partial P_{\nu}^{\pm m}(z)/\partial\nu]_{\nu=n}$ are obtained. These results are applied to find several representations, both explicit and of the Rodrigues type, for the associated Legendre function of the second kind of integer degree and order, $Q_{n}^{\pm m}(z)$; the explicit representations are suitable for use for numerical purposes in various regions of the complex $z$-plane. Finally, the derivatives $[\partial^{2}P_{\nu}^{m}(z)/\partial\nu^{2}]_{\nu=n}$, $[\partial Q_{\nu}^{m}(z)/\partial\nu]_{\nu=n}$ and $[\partial Q_{\nu}^{m}(z)/\partial\nu]_{\nu=-n-1}$, all with $m>n$, are evaluated in terms of $[\partial P_{\nu}^{-m}(\pm z)/\partial\nu]_{\nu=n}$.Comment: LateX, 40 pages, 1 figure, extensive referencin

Corporate governance and financial constraints on strategic turnarounds

The paper extends the Robbins and Pearce (1992) two-stage turnaround response model to include governance factors. In addition to the retrenchment and recovery, the paper proposes the addition of a realignment stage, referring specifically to the re-alignment of expectations of principal and agent groups. The realignment stage imposes a threshold that must be crossed before the retrenchment and hence recovery stage can be entered. Crossing this threshold is problematic to the extent that the interests of governance-stakeholder groups diverge in a crisis situation. The severity of the crisis impacts on the bases of strategy contingent asset valuation leading to the fragmentation of stakeholder interests. In some cases the consequence may be that management are prevented from carrying out turnarounds by governance constraints. The paper uses a case study to illustrate these dynamics, and like the Robbins and Pearce study, it focuses on the textile industry. A longitudinal approach is used to show the impact of the removal of governance constraints. The empirical evidence suggests that such financial constraints become less serious to the extent that there is a functioning market for corporate control. Building on governance research and turnaround literature, the paper also outlines the general case necessary and sufficient conditions for successful turnarounds

A generalized invariant imbedding equation II

Research into fetal development and medicin

Thirty Years After Michael E. Porter: What Do We Know About Business Exit?

Although a business exit is an important corporate change initiative, the buyer’s side seems to be more appealing to management researchers than the seller’s because acquisitions imply growth, i.e., success. Yet from an optimistic viewpoint, business exit can effectively create value for the selling company. In this paper we attempt to bring the relevance of the seller’s side back into our consciousness by asking: What do we know about business exit? We start our exploration with Porter (1976), focusing on literature that investigates the antecedents of, barriers to, and outcomes of business exit. We also include studies from related fields such as finance and economics.1 Through this research we determine three clusters of findings: factors promoting business exit, exit barriers, and exit outcomes. Overall, it is the intention of this paper to highlight the importance of business exit for research and practice. Knowing what we know about business exits and their high financial value we should bear in mind that exit need not mean failure but a new beginning for a corporation

Demographic profile of families and children in the Study to Explore Early Development (SEED): Case-control study of autism spectrum disorder

The Study to Explore Early Development (SEED) is designed to enhance knowledge of autism spectrum disorder characteristics and etiologies