Atmospheric methanol measurement using selective catalytic methanol to formaldehyde conversion

International audienceA novel atmospheric methanol measurement technique, employing selective gas-phase catalytic conversion of methanol to formaldehyde followed by detection of the formaldehyde product, has been developed and tested. The effects of temperature, gas flow rate, gas composition, reactor-bed length, and reactor-bed composition on the methanol conversion efficiency of a molybdenum-rich, iron-molybdate catalyst [Mo-Fe-O] were studied. Best results were achieved using a 1:4 mixture (w/w) of the catalyst in quartz sand. Optimal methanol to formaldehyde conversion (>95% efficiency) occurred at a catalyst housing temperature of 345°C and an estimated sample-air/catalyst contact time of <0.2 seconds. Potential interferences arising from conversion of methane and a number of common volatile organic compounds (VOC) to formaldehyde were found to be negligible under most atmospheric conditions and catalyst housing temperatures. Using the new technique, atmospheric measurements of methanol were made at the University of Bremen campus from 1 to 15 July 2004. Methanol mixing ratios ranged from 1 to 5 ppb with distinct maxima at night. Formaldehyde mixing ratios, obtained in conjunction with methanol by periodically bypassing the catalytic converter, ranged from 0.2 to 1.6 ppb with maxima during midday. These results suggest that selective, catalytic methanol to formaldehyde conversion, coupled with existing formaldehyde measurement instrumentation, is an inexpensive and effective means for monitoring atmospheric methanol

Discovery of a New Quadruple Lens HST 1411+5211

Gravitational lensing is an important tool for probing the mass distribution of galaxies. In this letter we report the discovery of a new quadruple lens HST 1411+5211 found in archived WFPC2 images of the galaxy cluster CL140933+5226. If the galaxy is a cluster member then its redshift is $z=0.46$. The images of the source appear unresolved in the WFC implying that the source is a quasar. We have modeled the lens as both a single galaxy and a galaxy plus a cluster. The latter model yields excellent fits to the image positions along with reasonable parameters for the galaxy and cluster making HST 1411+5211 a likely gravitational lens. Determination of the source redshift and confirmation of the lens redshift would allow us to put strong constraints on the mass distribution of the lensing galaxy.Comment: 11 pages including 1 postscript figure, aastex. Accepted to the ApJL. Also available from: http://www.astro.lsa.umich.edu:80/users/philf/www/papers/list.htm

Semantic analysis of citizen sensing, crowdsourcing and VGI

This paper describes a semantic analysis of terms used to describe citizen sensing and crowdsourced data use in scientific analyses. It applies a latency analysis to journal abstracts downloaded from Scopus that matched one of number of terms related to crowd sourced data and citizen science. The latency analysis shows how the terms associated with crowdsourcing are related and how they have evolved over time.JRC.H.6-Digital Earth and Reference Dat

Evidence of a Uniform Muscle-Tendon Unit Adaptation in Healthy Elite Track and Field Jumpers: A Cross Sectional Investigation.

Different adaptive responses to mechanical loading between muscle and tendon can lead to non-uniform biomechanical properties within the muscle-tendon unit. The current study aimed to analyze the mechanical properties of the triceps surae muscle-tendon unit in healthy male and female elite track and field jumpers in order to detect possible inter-limb differences and intra-limb non-uniformities in muscle and tendon adaptation. The triceps surae muscle strength and tendon stiffness were analyzed in both limbs during maximal voluntary isometric plantar flexion contractions using synchronous dynamometry and ultrasonography in sixty-seven healthy young male (n = 35) and female (n = 32) elite international level track and field jumpers (high jump, long jump, triple jump, pole vault). Triceps surae muscle-tendon unit intra-limb uniformity was assessed using between limb symmetry indexes in the muscle strength and tendon stiffness. Independent from sex and jumping discipline the take-off leg showed a significantly higher (p < 0.05) triceps surae muscle strength and tendon stiffness, suggesting different habitual mechanical loading between legs. However, despite these inter-limb discrepancies no differences were detected in the symmetry indexes of muscle strength (5.9 ± 9.4%) and tendon stiffness (8.1 ± 11.5%). This was accompanied by a significant correlation between the symmetry indexes of muscle strength and tendon stiffness (r = 0.44; p < 0.01; n = 67). Thus, the current findings give evidence for a uniform muscle-tendon unit adaptation in healthy elite track and field jumpers, which can be reflected as a protective mechanism to maintain its integrity to meet the functional demand

Shape of the Galactic Orbits in the CNOC1 Clusters

We present an analysis of the orbital properties in 9 intermediate-redshifts cluster of the CNOC1 survey and we compare them to a control sample of 12 nearby clusters. Similar to the nearby elliptical galaxies, the bulge-dominated galaxies in clusters at redshifts ~0.1-0.4 present orbits that are more eccentric than those for disk-dominated galaxies. However, the orbital segregation is less significant than that found for elliptical and spiral galaxies in nearby cluster. When galaxies are separated by colors - red galaxies with colors in the rest frame (U-V)_o > 1.4, and blue galaxies with (U-V)_o =< 1.4 - the strongest orbital segregation is found. Therefore, the segregation we found seems to modify more efficiently the star formation activity than the internal shape of the galaxies. When we compare the orbits of early-type galaxies at intermediate-redshift with those for z=0, they seem to develop significant changes getting much more eccentric. A different behavior is observed in the late-type galaxies, which present no-significant evolution in their orbit shapes.Comment: Accepted for publication in ApJ, April 2000. Latex with aaspp4.sty, 20 pages, 4 tables, 6 eps figure

The Size Function of Galaxy Disks out to z ~ 1 from the Canada-France-Hawaii-Telescope Legacy Survey

The formation and growth of galaxy disks over cosmic time is crucial to our understanding of galaxy formation. Despite steady improvements in the size and quality of disk samples over the last decade, many aspects of galaxy disk evolution remain unclear. Using two square degrees of deep, wide-field i'-band imaging from the Canada-France-Hawaii Telescope Legacy Survey, we compute size functions for 6000 disks from z=0.2 to z=1 and explore luminosity and number density evolution scenarios with an emphasis on the importance of selection effects on the interpretation of the data. We also compute the size function of a very large sample of disks from the Sloan Digital Sky Survey to use as a local (z ~ 0.1) comparison. CFHTLS size functions computed with the same fixed luminosity-size selection window at all redshifts exhibit evolution that appears to be best modelled by a pure number density evolution. The z = 0.3 size function is an excellent match to the z = 0.9 one if disks at the highest redshift are a factor of 2.5 more abundant than in the local universe. The SDSS size function would also match the z = 0.9 CFHTLS size function very well with a similar change in number density. On the other hand, the CFHTLS size functions computed with a varying luminosity-size selection window with redshift remain constant if the selection window is shifted by 1.0$-$1.5 mag towards fainter magnitudes with decreasing redshift. There is a weak dependence on disk scale length with smaller ($h \lesssim$ 4 kpc) disks requiring more luminosity evolution than larger ones. Given that changes in number density are primarily due to mergers and that current estimates of merger rates below z = 1 are low, luminosity evolution appears to be a more plausible scenario to explain the observations.Comment: 11 pages, 9 figures, Accepted for publication in Ap

Assessing cognitive dysfunction in Parkinson's disease: An online tool to detect visuo-perceptual deficits.

BackgroundPeople with Parkinson's disease (PD) who develop visuo-perceptual deficits are at higher risk of dementia, but we lack tests that detect subtle visuo-perceptual deficits and can be performed by untrained personnel. Hallucinations are associated with cognitive impairment and typically involve perception of complex objects. Changes in object perception may therefore be a sensitive marker of visuo-perceptual deficits in PD.ObjectiveWe developed an online platform to test visuo-perceptual function. We hypothesised that (1) visuo-perceptual deficits in PD could be detected using online tests, (2) object perception would be preferentially affected, and (3) these deficits would be caused by changes in perception rather than response bias.MethodsWe assessed 91 people with PD and 275 controls. Performance was compared using classical frequentist statistics. We then fitted a hierarchical Bayesian signal detection theory model to a subset of tasks.ResultsPeople with PD were worse than controls at object recognition, showing no deficits in other visuo-perceptual tests. Specifically, they were worse at identifying skewed images (P &lt; .0001); at detecting hidden objects (P = .0039); at identifying objects in peripheral vision (P &lt; .0001); and at detecting biological motion (P = .0065). In contrast, people with PD were not worse at mental rotation or subjective size perception. Using signal detection modelling, we found this effect was driven by change in perceptual sensitivity rather than response bias.ConclusionsOnline tests can detect visuo-perceptual deficits in people with PD, with object recognition particularly affected. Ultimately, visuo-perceptual tests may be developed to identify at-risk patients for clinical trials to slow PD dementia. © 2018 The Authors. Movement Disorders published by Wiley Periodicals, Inc. on behalf of International Parkinson and Movement Disorder Society