Probing the massive star forming environment - a multiwavelength investigation of the filamentary IRDC G333.73+0.37

We present a multiwavelength study of the filamentary infrared dark cloud (IRDC) G333.73+0.37. The region contains two distinct mid-infrared sources S1 and S2 connected by dark lanes of gas and dust. Cold dust emission from the IRDC is detected at seven wavelength bands and we have identified 10 high density clumps in the region. The physical properties of the clumps such as temperature: 14.3-22.3 K and mass: 87-1530 M_sun are determined by fitting a modified blackbody to the spectral energy distribution of each clump between 160 micron and 1.2 mm. The total mass of the IRDC is estimated to be $~4700 M_sun. The molecular line emission towards S1 reveals signatures of protostellar activity. Low frequency radio emission at 1300 and 610 MHz is detected towards S1 (shell-like) and S2 (compact morphology), confirming the presence of newly formed massive stars in the IRDC. Photometric analysis of near and mid-infrared point sources unveil the young stellar object population associated with the cloud. Fragmentation analysis indicates that the filament is supercritical. We observe a velocity gradient along the filament, that is likely to be associated with accretion flows within the filament rather than rotation. Based on various age estimates obtained for objects in different evolutionary stages, we attempt to set a limit to the current age of this cloud.Comment: 26 pages, 20 figures, accepted by Ap

Evolution and excitation conditions of outflows in high-mass star-forming regions

Theoretical models suggest that massive stars form via disk-mediated accretion, with bipolar outflows playing a fundamental role. A recent study toward massive molecular outflows has revealed a decrease of the SiO line intensity as the object evolves. The present study aims at characterizing the variation of the molecular outflow properties with time, and at studying the SiO excitation conditions in outflows associated with massive YSOs. We used the IRAM30m telescope to map 14 massive star-forming regions in the SiO(2-1), SiO(5-4) and HCO+(1-0) outflow lines, and in several dense gas and hot core tracers. Hi-GAL data was used to improve the spectral energy distributions and the L/M ratio, which is believed to be a good indicator of the evolutionary stage of the YSO. We detect SiO and HCO+ outflow emission in all the sources, and bipolar structures in six of them. The outflow parameters are similar to those found toward other massive YSOs. We find an increase of the HCO+ outflow energetics as the object evolve, and a decrease of the SiO abundance with time, from 10^(-8) to 10^(-9). The SiO(5-4) to (2-1) line ratio is found to be low at the ambient gas velocity, and increases as we move to high velocities, indicating that the excitation conditions of the SiO change with the velocity of the gas (with larger densities and/or temperatures for the high-velocity gas component). The properties of the SiO and HCO+ outflow emission suggest a scenario in which SiO is largely enhanced in the first evolutionary stages, probably due to strong shocks produced by the protostellar jet. As the object evolves, the power of the jet would decrease and so does the SiO abundance. During this process, however, the material surrounding the protostar would have been been swept up by the jet, and the outflow activity, traced by entrained molecular material (HCO+), would increase with time.Comment: 31 pages, 10 figures and 5 tables (plus 2 figures and 3 tables in the appendix). Accepted for publication in A&A. [Abstract modified to fit the arXiv requirements.

Physical properties of high-mass clumps in different stages of evolution

(Abridged) Aims. To investigate the first stages of the process of high-mass star formation, we selected a sample of massive clumps previously observed with the SEST at 1.2 mm and with the ATNF ATCA at 1.3 cm. We want to characterize the physical conditions in such sources, and test whether their properties depend on the evolutionary stage of the clump. Methods. With ATCA we observed the selected sources in the NH3(1,1) and (2,2) transitions and in the 22 GHz H2O maser line. Ammonia lines are a good temperature probe that allow us to accurately determine the mass and the column-, volume-, and surface densities of the clumps. We also collected all data available to construct the spectral energy distribution of the individual clumps and to determine if star formation is already occurring, through observations of its most common signposts, thus putting constraints on the evolutionary stage of the source. We fitted the spectral energy distribution between 1.2 mm and 70 microns with a modified black body to derive the dust temperature and independently determine the mass. Results. The clumps are cold (T~10-30 K), massive (M~10^2-10^3 Mo), and dense (n(H2)>~10^5 cm^-3) and they have high column densities (N(H2)~10^23 cm^-2). All clumps appear to be potentially able to form high-mass stars. The most massive clumps appear to be gravitationally unstable, if the only sources of support against collapse are turbulence and thermal pressure, which possibly indicates that the magnetic field is important in stabilizing them. Conclusions. After investigating how the average properties depend on the evolutionary phase of the source, we find that the temperature and central density progressively increase with time. Sources likely hosting a ZAMS star show a steeper radial dependence of the volume density and tend to be more compact than starless clumps.Comment: Published in A&A, Vol. 556, A1

Thermal Jeans fragmentation within 1000 AU in OMC-1S

We present subarcsecond 1.3 mm continuum ALMA observations towards the Orion Molecular Cloud 1 South (OMC-1S) region, down to a spatial resolution of 74 AU, which reveal a total of 31 continuum sources. We also present subarcsecond 7 mm continuum VLA observations of the same region, which allow to further study fragmentation down to a spatial resolution of 40 AU. By applying a Mean Surface Density of Companions method we find a characteristic spatial scale at ~560 AU, and we use this spatial scale to define the boundary of 19 `cores' in OMC-1S as groupings of millimeter sources. We find an additional characteristic spatial scale at ~2900 AU, which is the typical scale of the filaments in OMC-1S, suggesting a two-level fragmentation process. We measured the fragmentation level within each core and find a higher fragmentation towards the southern filament. In addition, the cores of the southern filament are also the densest (within 1100 AU) cores in OMC-1S. This is fully consistent with previous studies of fragmentation at spatial scales one order of magnitude larger, and suggests that fragmentation down to 40 AU seems to be governed by thermal Jeans processes in OMC-1S.Comment: Accepted to Ap

Synthesis of quinoxaline 1,4-di-N-oxide derivatives on solid support using room temperature and microwave-assisted solvent-free procedures

We describe the synthesis of 12 new ethyl and methyl quinoxaline-7-carboxylate 1,4-di-N-oxide derivatives on solid supports with room temperature and microwave-assisted solvent-free procedures. Results show that solid supports have good catalytic activity in the formation of quinoxaline 1,4-di-N-oxide derivatives. We found that florisil and montmorillonite KSF and K10 could be used as new, easily available, inexpensive alternatives of catalysts. Additionally, room temperature and microwave-irradiation solvent-free synthesis was more efficient than a conventional procedure (Beirut reaction), reducing reaction time and increasing yield

Deuteration and evolution in the massive star formation process: the role of surface chemistry

An ever growing number of observational and theoretical evidence suggests that the deuterated fraction (column density ratio between a species containing D and its hydrogenated counterpart, Dfrac) is an evolutionary indicator both in the low- and the high-mass star formation process. However, the role of surface chemistry in these studies has not been quantified from an observational point of view. In order to compare how the deuterated fractions of species formed only in the gas and partially or uniquely on grain surfaces evolve with time, we observed rotational transitions of CH3OH, 13CH3OH, CH2DOH, CH3OD at 3 and 1.3~mm, and of NH2D at 3~mm with the IRAM-30m telescope, and the inversion transitions (1,1) and (2,2) of NH3 with the GBT, towards most of the cores already observed by Fontani et al.~(2011, 2014) in N2H+, N2D+, HNC, DNC. NH2D is detected in all but two cores, regardless of the evolutionary stage. Dfrac(NH3) is on average above 0.1, and does not change significantly from the earliest to the most evolved phases, although the highest average value is found in the protostellar phase (~0.3). Few lines of CH2DOH and CH3OD are clearly detected, and only towards protostellar cores or externally heated starless cores. This work clearly confirms an expected different evolutionary trend of the species formed exclusively in the gas (N2D+ and N2H+) and those formed partially (NH2D and NH3) or totally (CH2DOH and CH3OH) on grain mantles. The study also reinforces the idea that Dfrac(N2H+) is the best tracer of massive starless cores, while high values of Dfrac(CH3OH) seem rather good tracers of the early protostellar phases, at which the evaporation/sputtering of the grain mantles is most efficient.Comment: 14 pages, 7 figures, 2 Appendice

Gravity or turbulence? -III. Evidence of pure thermal Jeans fragmentation at ~0.1 pc scale

We combine previously published interferometric and single-dish data of relatively nearby massive dense cores that are actively forming stars to test whether their `fragmentation level' is controlled by turbulent or thermal support. We find no clear correlation between the fragmentation level and velocity dispersion, nor between the observed number of fragments and the number of fragments expected when the gravitationally unstable mass is calculated including various prescriptions for `turbulent support'. On the other hand, the best correlation is found for the case of pure thermal Jeans fragmentation, for which we infer a core formation efficiency around 13 per cent, consistent with previous works. We conclude that the dominant factor determining the fragmentation level of star-forming massive dense cores at 0.1 pc scale seems to be thermal Jeans fragmentation.Comment: accepted in MNRA