Dating the incision of the Yangtze River gorge at the First Bend using three-nuclide burial ages

Incision of the Yangtze River gorge is widely interpreted as evidence for lower crustal flow beneath the southeast margin of the Tibetan Plateau. Previous work focused on the onset of incision, but the duration of incision remains unknown. Here we present cosmogenic nuclide burial ages of sediments collected from caves on the walls of the gorge that show the gorge was incised ~1 km sometime between 18 and 9 Ma. Thereafter, incision slowed substantially. We resolve middle Miocene burial ages by using three nuclides and accounting for in situ muogenic production. This approach explains the absolute concentrations of 10Be, 26Al, and 21Ne, as well as 26Al/10Be and 21Ne/10Be ratios. A declining incision rate challenges existing geodynamic interpretations by suggesting that either (1) surface uplift has ceased immediately south of the plateau margin or (2) gorge incision is not a useful proxy for the timing of surface uplift

Maximizing and stabilizing luminescence from halide perovskites with potassium passivation

Metal halide perovskites are of great interest for various high-performance optoelectronic applications. The ability to tune the perovskite bandgap continuously by modifying the chemical composition opens up applications for perovskites as coloured emitters, in building-integrated photovoltaics, and as components of tandem photovoltaics to increase the power conversion efficiency. Nevertheless, performance is limited by non-radiative losses, with luminescence yields in state-of-the-art perovskite solar cells still far from 100 per cent under standard solar illumination conditions. Furthermore, in mixed halide perovskite systems designed for continuous bandgap tunability2 (bandgaps of approximately 1.7 to 1.9 electronvolts), photoinduced ion segregation leads to bandgap instabilities. Here we demonstrate substantial mitigation of both non-radiative losses and photoinduced ion migration in perovskite films and interfaces by decorating the surfaces and grain boundaries with passivating potassium halide layers. We demonstrate external photoluminescence quantum yields of 66 per cent, which translate to internal yields that exceed 95 per cent. The high luminescence yields are achieved while maintaining high mobilities of more than 40 square centimetres per volt per second, providing the elusive combination of both high luminescence and excellent charge transport. When interfaced with electrodes in a solar cell device stack, the external luminescence yield—a quantity that must be maximized to obtain high efficiency—remains as high as 15 per cent, indicating very clean interfaces. We also demonstrate the inhibition of transient photoinduced ion-migration processes across a wide range of mixed halide perovskite bandgaps in materials that exhibit bandgap instabilities when unpassivated. We validate these results in fully operating solar cells. Our work represents an important advance in the construction of tunable metal halide perovskite films and interfaces that can approach the efficiency limits in tandem solar cells, coloured-light-emitting diodes and other optoelectronic applications.M.A.-J. thanks Nava Technology Limited and Nyak Technology Limited for their funding and technical support. Z.A.-G. acknowledges funding from a Winton Studentship, and ICON Studentship from the Lloyd’s Register Foundation. This project has received funding from the European Union’s Seventh Framework Programme (FP7/2007-2013) under REA grant agreement number PIOF-GA-2013-622630, the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement number 756962), and the Royal Society and Tata Group (UF150033). We thank the Engineering and Physical Sciences Research Council (EPSRC) for support. XMaS is a mid-range facility at the European Synchrotron Radiation Facility supported by the EPSRC and we are grateful to the XMaS beamline team staff for their support. We thank Diamond Light Source for access to beamline I09 and staff member T.-L. Lee as well as U. Cappel for assistance during the HAXPES measurements. S.C., C.D. and G.D. acknowledge funding from the ERC under grant number 25961976 PHOTO EM and financial support from the European Union under grant number 77 312483 ESTEEM2. M.A. thanks the president of the UAE’s Distinguished Student Scholarship Program, granted by the Ministry of Presidential Affairs. H.R. and B.P. acknowledge support from the Swedish research council (2014-6019) and the Swedish foundation for strategic research. E.M.H. and T.J.S. were supported by the Netherlands Organization for Scientific Research under the Echo grant number 712.014.007

High-precision U-Pb zircon geochronology of the late triassic chinle formation, Petrififed Forest National Park (Arizona, USA): Temporal constraints on the early evolution of dinosaurs

The Triassic successions of the Colorado Plateau preserve an important record of vertebrate evolution and climate change, but correlations to a global Triassic framework are hampered by a lack of geochronological control. Tuffaceous sandstones and siltstones were collected from the Upper Triassic Chinle Formation exposed in the Petrified Forest National Park, Arizona, USA, within a refined stratigraphic context of 31 detailed measured sections. U-Pb analyses by the isotope dilution-thermal ionization mass spectrometry (ID-TIMS) method constrain maximum depositional ages for nine tuffaceous beds and provide new insights into the depositional history of the Chinle fluvial system. The base of the Blue Mesa Member of the Chinle Formation is placed at ca. 225 Ma, and the top of the Petrified Forest Member is placed at 208 Ma or younger, bracketing an ̃280-m-thick section that spans nearly the entire Norian Stage of the Late Triassic. Estimated sediment accumulation rates throughout the section reflect extensive hiatuses and/ or sediment removal by channel erosion. The new geochronology for the Chinle Formation underscores the potential pitfalls of correlation of fluvial units based solely on lithostratigraphic criteria. A mid-Norian age (ca. 219-213 Ma) for the distinctive Sonsela conglomeratic sandstone bed constrains the Adamanian-Revueltian land vertebrate faunachron boundary. Our new data permit a significant time overlap between the lower Chinle sequence and the dinosauromorphrich Ischigualasto Formation of northwestern Argentina. Near-contemporaneity of the trans-American deposits and their faunal similarities imply that early dinosaur evolution occurred rapidly across the Americas. © 2011 Geological Society of America