Sintesi di PNA: una strategia semplice ed efficiente

Nell’ambito del nostro gruppo di ricerca è stato sviluppato un processo di sintesi dei singoli monomeri PNA, utilizzando metodologie efficienti e riproducibili, che non comportano purificazioni cromatografiche degli intermedi e che permettono di ottenere i monomeri su larga scala. Si è cercato di ottenere monomeri in cui fosse rispettata l’ortogonalità tra i vari gruppi protettori (Pg1, Pg2, Pg3) sia dello scheletro che delle nucleobasi

The AGB bump: a calibrator for the core mixing

The efficiency of convection in stars affects many aspects of their evolution and remains one of the key-open questions in stellar modelling. In particular, the size of the mixed core in core-He-burning low-mass stars is still uncertain and impacts the lifetime of this evolutionary phase and, e.g., the C/O profile in white dwarfs. One of the known observables related to the Horizontal Branch (HB) and Asymptotic Giant Branch (AGB) evolution is the AGB bump. Its luminosity depends on the position in mass of the helium-burning shell at its first ignition, that is affected by the extension of the central mixed region. In this preliminary work we show how various assumptions on near-core mixing and on the thermal stratification in the overshooting region affect the luminosity of the AGB bump, as well as the period spacing of gravity modes in core-He-burning models.Comment: Submitted to EPJ Web of Conferences, to appear in the Proceedings of the 3rd CoRoT Symposium, Kepler KASC7 joint meeting; 2 pages, 2 figure

The Horizontal Branch of NGC 1851: Constraints from its RR Lyrae Variables

We use the pulsational properties of the RR Lyrae variables in the globular cluster NGC 1851 to obtain detailed constraints of the various sub-stellar populations present along its horizontal branch. On the basis of detailed synthetic horizontal branch modeling, we find that minor helium variations (Y~0.248-0.280) are able to reproduce the observed periods and amplitudes of the RR Lyrae variables, as well as the frequency of fundamental and first-overtone RR Lyrae stars. Comparison of number ratios amongst the blue and red horizontal branch components and the two observed subgiant branches also suggest that the RR Lyrae variables originated from the progeny of the bright subgiant branch. The RR Lyrae variables with a slightly enhanced helium (Y~0.270-0.280) have longer periods at a given amplitude, as is seen with Oosterhoff II (OoII) RR Lyrae variables, whereas the RR Lyrae variables with Y~0.248-0.270 have shorter periods, exhibiting properties of Oosterhoff I (OoI) variables. This correlation does suggest that the pulsational properties of RR Lyrae stars can be very useful for tracing the various sub-populations and can provide suitable constraints on the multiple population phenomenon. It appears of great interest to explore whether this conclusion can be generalized to other globular clusters hosting multiple populations.Comment: accepted to A

The RR Lyrae variables and Horizontal Branch of NGC6656 (M22)

The first calibrated broadband UBVI time-series photometry is presented for the RR Lyrae variable stars in NGC6656 (M22), with observations spanning a range of twenty-two years. We have also redetermined the variability types and periods for the RR Lyrae stars identified previously by photographic observations, revising the number of fundamental-mode RR Lyrae variables (RR0) to 10 and the number of first-overtone variables (RR1) to 16. The mean periods of the RR0 and RR1 variables are _{RR0}=0.66 \pm 0.02 d and _{RR1}=0.33 \pm 0.01 d, respectively, supporting an Oosterhoff II classification for the cluster. The number ratio of RR1- to all RR-type variables is N_1/N_{RR}=0.61, also consistent with an Oosterhoff II designation. Both the RR Lyrae stars' minimum light colors and the blue edge of the RR Lyrae instability strip suggest E(B-V)=0.36 \pm 0.02 mag toward M22. Regarding the HB morphology of M22, we find (B-R)/(B+V+R)=+0.97 \pm 0.1 and at least one "gap" located in an unusual part of the blue HB, in the middle of the so-called hot HB stars.Comment: accepted to A

Computational Model For The Estimation Of Thermo-Energetic Properties In Dynamic Regime Of Existing Building Components

The guidelines of the European community towards a low-carbon economic society identify one of the most important scenarios in the energy efficiency of existing buildings. The discrepancy between the requirement and availability of free heat (endogenous heat, solar radiation) in certain hours of the day and operating conditions, makes the steady-state hypothesis generally inappropriate. In particular, the oscillating component of the transmitted flow, compared to the average temperature difference, is regressive in winter and dominant in summer. From this it follows the reliability of the stationary forecast models in winter and the need for dynamic forecast models in summer. The dominance of the continental climate in the EU, compared to the Mediterranean one, led to the actual delay in the development of dynamic models, especially at a regulatory level. In this paper, a methodology for assessing the dynamic properties of a building component is evaluated. The methodology, based on heat transmission equations implements a numerical model for existing building components whose input data can be obtained from experimental measurements. The developed model has been used to estimate the energetic and thermal behaviour of a building envelope subjected to energy efficiency measure

Rapidly rotating second-generation progenitors for the blue hook stars of {\omega} Cen

Horizontal Branch stars belong to an advanced stage in the evolution of the oldest stellar galactic population, occurring either as field halo stars or grouped in globular clusters. The discovery of multiple populations in these clusters, that were previously believed to have single populations gave rise to the currently accepted theory that the hottest horizontal branch members (the blue hook stars, which had late helium-core flash ignition, followed by deep mixing) are the progeny of a helium-rich "second generation" of stars. It is not known why such a supposedly rare event (a late flash followed by mixing) is so common that the blue hook of {\omega} Cen contains \sim 30% of horizontal branch stars 10 , or why the blue hook luminosity range in this massive cluster cannot be reproduced by models. Here we report that the presence of helium core masses up to \sim 0.04 solar masses larger than the core mass resulting from evolution is required to solve the luminosity range problem. We model this by taking into account the dispersion in rotation rates achieved by the progenitors, whose premain sequence accretion disc suffered an early disruption in the dense environment of the cluster's central regions where second-generation stars form. Rotation may also account for frequent late-flash-mixing events in massive globular clusters.Comment: 44 pages, 8 figures, 2 tables in Nature, online june 22, 201

The Aarhus red giants challenge: II. Stellar oscillations in the red giant branch phase

[Contact] The large quantity of high-quality asteroseismic data that have been obtained from space-based photometric missions and the accuracy of the resulting frequencies motivate a careful consideration of the accuracy of computed oscillation frequencies of stellar models, when applied as diagnostics of the model properties.[Aims] Based on models of red-giant stars that have been independently calculated using different stellar evolution codes, we investigate the extent to which the differences in the model calculation affect the model oscillation frequencies and other asteroseismic diagnostics.[Methods] For each of the models, which cover four different masses and different evolution stages on the red-giant branch, we computed full sets of low-degree oscillation frequencies using a single pulsation code and, from these frequencies, typical asteroseismic diagnostics. In addition, we carried out preliminary analyses to relate differences in the oscillation properties to the corresponding model differences.[Results] In general, the differences in asteroseismic properties between the different models greatly exceed the observational precision of these properties. This is particularly true for the nonradial modes whose mixed acoustic and gravity-wave character makes them sensitive to the structure of the deep stellar interior and, hence, to details of their evolution. In some cases, identifying these differences led to improvements in the final models presented here and in Paper I; here we illustrate particular examples of this.[Conclusions] Further improvements in stellar modelling are required in order fully to utilise the observational accuracy to probe intrinsic limitations in the modelling and improve our understanding of stellar internal physics. However, our analysis of the frequency differences and their relation to stellar internal properties provides a striking illustration of the potential, in particular, of the mixed modes of red-giant stars for the diagnostics of stellar interiors.Funding for the Stellar Astrophysics Centre is provided by The Danish National Research Foundation (Grant agreement No. DNRF106). The research was supported by the ASTERISK project (ASTERoseismic Investigations with SONG and Kepler) funded by the European Research Council (Grant agreement No. 267864). This research was supported in part by the National Science Foundation under Grant No. NSF PHY-1748958. VSA acknowledges support from VILLUM FONDEN (research grant 10118) and the Independent Research Fund Denmark (Research grant 7027-00096B). DS is the recipient of an Australian Research Council Future Fellowship (project number FT1400147). SC acknowledges support from Premiale INAF MITiC, from INAF “Progetto mainstream” (PI: S. Cassisi), and grant AYA2013-42781P from the Ministry of Economy and Competitiveness of Spain. AMS is partially supported by grants ESP2017-82674-R (Spanish Government) and 2017-SGR-1131 (General-itat de Catalunya). TC acknowledges support from the European Research Council AdG No 320478-TOFU and the STFC Consolidated Grant ST/R000395/1. SH received funding for this research from the European Research Council under the European Community’s Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement no 338251 (StellarAges). AM acknowledges the support of the Government of India, Department of Atomic Energy, under Project No. 12-R&D-TFR-6.04-0600. DB is supported in the form of work contract FCT/MCTES through national funds and by FEDER through COMPETE2020 in connection to these grants: UID/FIS/04434/2019; PTDC/FIS-AST/30389/2017 & POCI-01-0145-FEDER-030389

The Aarhus red giants challenge: II. Stellar oscillations in the red giant branch phase

Contact. The large quantity of high-quality asteroseismic data that have been obtained from space-based photometric missions and the accuracy of the resulting frequencies motivate a careful consideration of the accuracy of computed oscillation frequencies of stellar models, when applied as diagnostics of the model properties. Aims. Based on models of red-giant stars that have been independently calculated using different stellar evolution codes, we investigate the extent to which the differences in the model calculation affect the model oscillation frequencies and other asteroseismic diagnostics. Methods. For each of the models, which cover four different masses and different evolution stages on the red-giant branch, we computed full sets of low-degree oscillation frequencies using a single pulsation code and, from these frequencies, typical asteroseismic diagnostics. In addition, we carried out preliminary analyses to relate differences in the oscillation properties to the corresponding model differences. Results. In general, the differences in asteroseismic properties between the different models greatly exceed the observational precision of these properties. This is particularly true for the nonradial modes whose mixed acoustic and gravity-wave character makes them sensitive to the structure of the deep stellar interior and, hence, to details of their evolution. In some cases, identifying these differences led to improvements in the final models presented here and in Paper I; here we illustrate particular examples of this. Conclusions. Further improvements in stellar modelling are required in order fully to utilise the observational accuracy to probe intrinsic limitations in the modelling and improve our understanding of stellar internal physics. However, our analysis of the frequency differences and their relation to stellar internal properties provides a striking illustration of the potential, in particular, of the mixed modes of red-giant stars for the diagnostics of stellar interiors. © ESO 2020

Controlling the Plain. The Analysis of the Settlement Patterns of the Salmas Plain, Iran,from the Prehistoric to the Sasanian Periods.

This contribution aims to provide a detailed diachronic analysis of the settlement patterns in the Salmas plain, in north-western Iran. The chronological period taken into consideration goes from Prehistory to the Sasanian period, covering the entire pre-Islamic period. The work is based on a comprehensive re-evaluation of the archaeological data available to us, as well as new data produced using remote sensing. The contribution analyses the forms of interaction and control of the territory operated by the sites, in particular the fortified ones, and reconstructs for the periods for which the data are sufficient the management strategies of the plain using GIS software, as well as the analysis of the points of sight and intervisibility. The result is a highly complex and articulated situation where the settlement patterns have not always been the same over time although some forms of continuity can be noted. Due to its position and geographical characteristics, the Salmas plain is in all respects a place of great importance in the study of the archaeology of north-western Iran. It is no coincidence that key-sites such as Haftavan Tappeh or Qara Tappeh have had a long history spanning from Protohistory to the historical period. The aim of this contribution is therefore to be a first review and re-evaluation of the archaeological information of the Salmas plain and a recontextualisation of the sites in the pre-protohistoric and historical dynamics of the area examined using tools like G.I.S