Synchronizing terrestrial and marine records of environmental change across the Eocene–Oligocene transition

Records of terrestrial environmental change indicate that continental cooling and/or aridification may have predated the greenhouse–icehouse climate shift at the Eocene–Oligocene transition (EOT) by ca. 600 kyr. In North America, marine-terrestrial environmental change asynchronicity is inferred from a direct comparison between the astronomically tuned marine EOT record and published 40Ar/39Ar geochronology of volcanic tuffs from the White River Group (WRG) sampled at Flagstaff Rim (Wyoming) and Toadstool Geologic Park (Nebraska), which are type sections for the Chadronian and Orellan North American Land Mammal Ages. We present a new age-model for the WRG, underpinned by high-precision 206Pb/238U zircon dates from 15 volcanic tuffs, including six tuffs previously dated using the 40Ar/39Ar technique. Weighted mean zircon 206Pb/238U dates from this study are up to 1.0 Myr younger than published anorthoclase and biotite 40Ar/39Ar data (calibrated relative to Fish Canyon sanidine at 28.201 Ma). Giving consideration to the complexities, strengths, and limitations associated with both the 40Ar/39Ar and 206Pb/238U datasets, our interpretation is that the recalculated 40Ar/39Ar dates are anomalously old, and the 206Pb/238U (zircon) dates more accurately constrain deposition. 206Pb/238U calibrated age–depth models were developed in order to facilitate a robust intercomparison between marine and terrestrial archives of environmental change, and indicate that: (i) early Orellan (terrestrial) cooling recorded at Toadstool Geologic Park was synchronous with the onset of early Oligocene Antarctic glaciation and (ii) the last appearance datums of key Chadronian mammal taxa are diachronous by ca. 0.7 Myr between central Wyoming and NW Nebraska

Timescales of methane seepage on the Norwegian margin following collapse of the Scandinavian Ice Sheet

Gas hydrates stored on continental shelves are susceptible to dissociation triggered by environmental changes. Knowledge of the timescales of gas hydrate dissociation and subsequent methane release are critical in understanding the impact of marine gas hydrates on the ocean–atmosphere system. Here we report a methane efflux chronology from five sites, at depths of 220–400 m, in the southwest Barents and Norwegian seas where grounded ice sheets led to thickening of the gas hydrate stability zone during the last glaciation. The onset of methane release was coincident with deglaciation-induced pressure release and thinning of the hydrate stability zone. Methane efflux continued for 7–10 kyr, tracking hydrate stability changes controlled by relative sea-level rise, bottom water warming and fluid pathway evolution in response to changing stress fields. The protracted nature of seafloor methane emissions probably attenuated the impact of hydrate dissociation on the climate system

Corrigendum to “Insights into methane dynamics from analysis of authigenic carbonates and chemosynthetic mussels at newly-discovered Atlantic Margin seeps” [Earth Planet. Sci. Lett. 449 (2016) 332–344]

This paper is not subject to U.S. copyright. The definitive version was published in Earth and Planetary Science Letters 475 (2017): 268, doi:10.1016/j.epsl.2017.07.037

Going with the flow: sedimentary processes along karst conduits within Chalk aquifers, northern France

Sediment-filled caves, conduits and voids are common in many karst regions. These voids and the sediment they contain are important palaeoclimatic and palaeoenvironmental archives, but often have an adverse impact on engineering projects, mineral extraction and hydrogeology. Most studies into fluvial sedimentation in karst aquifers have focussed on more traditional karst areas. However, the nature and extent of fluvial sedimentation within caves and conduits in the important Upper Cretaceous Chalk Group aquifer (NW and Central Europe), and their impacts are less well known. This is principally due to a lack of accessible Chalk caves with exposed 3D sediment archives for study. Fortunately, the discovery of the World's longest Chalk cave system by underground quarrying at Caumont in the Seine valley near Rouen, northern France, has exposed numerous sediment sections along 2.4 km of passage. Detailed analysis of the stratigraphy, mineralogy, sedimentology, provenance and the chronology of the exposed sediments including the novel use of Gamma-ray spectrometry, reveals complex stratigraphy and lateral facies distribution along a karst conduit. The depositional model comprises five allostratigraphical units since the mid-Chibanian, separated by periods of erosion. The units are derived from hyper-concentrated and sediment-laden flows, and include thalweg, channel, slackwater, backswamp speleothem facies and debris flow deposits that are interbedded. Speleothems precipitated during MIS 7, 6, 5e and 1. During MIS 7–6, detrital sediments filled almost all Chalk conduits, similar to other caves in the European Atlantic Margin, coevally with the Penultima (Saalian) Glacial Cycle and a maximum of the Earth eccentricity. Detrital sediments are derived from the erosion of local Chalk bedrocks as well as metamorphic and igneous rocks of remote areas, such as Morvan massif and Massif Central. The depositional model is consistent with the conception of the Chalk as a karst aquifer. Significant sediment aggradation caused upwards dissolution (paragenesis), conduit occlusion and subsequent genesis of new conduits by flow diversion, potentially altering the functioning of the chalk aquifer and the interpretation of Chalk hydrogeology (e.g., dye-tracing tests)

Reconstructing fluvial incision rates based upon palaeo‐water tables in Chalk karst networks along the Seine valley (Normandy, France)

Quantifying rates of river incision and continental uplift over Quaternary timescales offer the potential for modelling landscape change due to tectonic and climatic forcing. In many areas, river terraces form datable archives that help constrain the timing and rate of valley incision. However, old river terraces, with high‐level deposits, are prone to weathering and often lack datable material. Where valleys are incised through karst areas, caves and sediments can be used to reconstruct the landscape evolution because they can record the elevation of palaeo‐water tables and contain preserved datable material. In Normandy (N. France), the Seine River is entrenched into an extensive karstic chalk plateau. Previous estimates of valley incision were hampered by the lack of preserved datable fluvial terraces. A stack of abandoned phreatic cave passages preserved in the sides of the Seine valley can be used to reconstruct the landscape evolution of the region. Combining geomorphological observations, palaeomagnetic and U/Th dating of speleothem and sediments in eight caves along the Lower Seine valley, we have constructed a new age model for cave development and valley incision. Six identified cave levels up to ∼100 m a.s.l. were formed during the last ~1 Ma, coeval with the incision of the Seine River. Passage morphologies indicate that the caves formed in a shallow phreatic/epiphreatic setting, modified by sediment influxes. The valley's maximum age is constrained by the occurrence of late Pliocene marine sand. Palaeomagnetic dating of cave infills indicates that the highest‐level caves were being infilled prior to 1.1 Ma. The evidence from the studied caves, complemented by fluvial terrace sequences, indicates that rapid river incision occurred during marine isotope stage (MIS) 28 to 20 (0.8–1 Ma), with maximal rates of ~0.30 m ka−1, dropping to ~0.08 m ka−1 between MIS 20–11 (0.8–0.4 Ma) and 0.05 m ka−1 from MIS 5 to the present time

A 160,000-year-old history of tectonically controlled methane seepage in the Arctic

The geological factors controlling gas release from Arctic deep-water gas reservoirs through seabed methane seeps are poorly constrained. This is partly due to limited data on the precise chronology of past methane emission episodes. Here, we use uranium-thorium dating of seep carbonates sampled from the seabed and from cores drilled at the Vestnesa Ridge, off West Svalbard (79°N, ~1200 m water depth). The carbonate ages reveal three emission episodes during the Penultimate Glacial Maximum (~160,000 to 133,000 years ago), during an interstadial in the last glacial (~50,000 to 40,000 years ago), and in the aftermath of the Last Glacial Maximum (~20,000 to 5,000 years ago), respectively. This chronology suggests that glacial tectonics induced by ice sheet fluctuations on Svalbard mainly controlled methane release from Vestnesa Ridge. Data corroborate past methane release in response to Northern Hemisphere cryosphere variations and suggest that Arctic deep-water gas reservoirs are sensitive to temperature variations over Quaternary time scales

Proposal for the Global Boundary Stratotype Section and Point (GSSP) for the Priabonian Stage (Eocene) at the Alano section (Italy)

The base of the Priabonian Stage is one of two stage boundaries in the Paleogene that remains to be formalized. The Alano section (NE Italy) was elected by consensus as a suitable candidate for the base of the Priabonian during the Priabonian Working Group meeting held in Alano di Piave in June 2012. Further detailed research on the section is now followed by a formal proposal, which identifies the base of a prominent crystal tuff layer, the Tiziano bed, at meter 63.57 of the Alano section, as a suitable candidate for the Priabonian Stage. The choice of the Tiziano bed is appropriate from the historical point of view and several bio-magnetostratigraphic events are available to approximate this chronostratigraphic boundary and guarantee a high degree of correlatability over wide geographic areas. Events which approximate the base of the Priabonian Stage in the Alano section are the successive extinction of large acarininids and Morozovelloides (planktonic foraminifera), the Base of common and continuous Cribrocentrum erbae and the Top of Chiasmolithus grandis (nannofossils), as well as the Base of Subchron C17n.2n and the Base of Chron C17n (magnetostratigraphy). Cyclostratigraphic analysis of the Bartonian-Priabonian transition of the Alano section as well as radioisotopic data of the Tiziano tuff layer provide an absolute age (37.710 – 37.762 Ma, respectively) of this bed and, consequently, of the base of the Priabonian Stage

Synchronizing terrestrial and marine records of environmental change across the Eocene–Oligocene transition

Synchronizing terrestrial and marine records of environmental change across the Eocene–Oligocene transitio

Biogeochemistry and timing of methane-derived carbonate formation at Leirdjupet fault complex, SW Barents sea

The origin of modern seafloor methane emissions in the Barents Sea is tightly connected to the glacio-tectonic and oceanographic transformations following the last ice age. Those regional events induced geological structure re-activation and destabilization of gas hydrate reservoirs over large areas of the European continental margins, sustaining widespread fluid plumbing systems. Despite the increasing number of new active seep discoveries, their accurate geochronology and paleo-dynamic is still poorly resolved, thus hindering precise identification of triggering factors and mechanisms controlling past and future seafloor emissions. Here, we report the distribution, petrographic (thin section, electron backscatter diffraction), isotopic (δ13C, δ18O) and lipid biomarker composition of methane-derived carbonates collected from Leirdjupet Fault Complex, SW Barents Sea, at 300 m depth during an ROV survey in 2021. Carbonates are located inside a 120 x 220 m elongated pockmark and form 13C values between −28.6‰ to −10.1‰ and δ18O between 4.6‰ and 5.3‰, enabling us to track carbonate mineral precipitation over the last ∼8 ka. Lipid biomarkers and their compound-specific δ13C analysis in the bulk carbonate revealed the presence of anaerobic methanotrophic archaea of the ANME-2 clade associated with sulfate-reducing bacteria of the Seep-SRB1 clade, as well as traces of petroleum. Our results indicate that methane and petroleum seepage in this area followed a similar evolution as in other southernmost Barents Sea sites controlled by the asynchronous deglaciation of the Barents Sea shelf, and that methane-derived carbonate precipitation is still an active process at many Arctic locations

Protracted post-glacial hydrocarbon seepage in the Barents Sea revealed by U–Th dating of seep carbonates

The hydrocarbon seepage chronology during deglaciation across the formerly glaciated Barents Sea was established using uranium-thorium (U–Th) dating of seep carbonates. Seep carbonates were sampled with remotely operated vehicles (ROV) from the seafloor at three active hydrocarbon seeps (water depth 156–383 m), located in the north-west (Storfjordrenna), north-central (Storbanken High), and south-west (Loppa High) Barents Sea. Overall, the U–Th dates range from 13.5 to 1.2 thousand years (ka) before present, indicating episodic seep carbonate formation since the late Pleistocene throughout the Holocene. The new U–Th dates indicate protracted post-glacial gas seepage, congruent with previously published seep carbonate ages from the south-west Barents Sea. Gas hydrate dissociation and associated seep carbonate formation occurred at Storfjordrenna between ≈6 and 1.2 ka, and around 13.5 and 6 ka at Storbanken. Early and late Holocene seep carbonate ages from Loppa High support post-glacial seismic activity as potential seepage trigger mechanis