67 research outputs found
MOS based nanocapacitor using C-AFM
Nanocapacitors are integral devices of nanoscale MOS based integrated circuits and have not yet been realised. We report in this article our results to date on the realisation of such a nanocapacitor through the use of Atomic Force Microscopy (AFM) anodic oxidation to isolate nano-sized squares of poly-silicon, titanium and aluminium on Si/SiO2. The focus of this work is on the Conductive AFM performed topographical and electrical characterization
Merging solution processing and printing for sustainable fabrication of Cu(In,Ga)Se2 photovoltaics
The targeted global decarbonization demands the urgent replacement of conventional fossil fuel with low carbon technologies. For instance, solar energy is abundant, inexhaustible, non-polluting, and low-priced; however, to produce energy on a large scale with reliable, cost-efficient, and environmentally friendly methods remains a challenge. The outstanding optical properties of Cu(In,Ga)Se2 thin film photovoltaics and their intrinsic compatibility with industrial-scale production are paving the way towards this technology. However, most of the activity in the field relies on the use of non-environmentally friendly methodologies to achieve solution-processed flexible and lightweight photovoltaics with significant efficiencies. Importantly, there is a search for more sustainable alternatives that are compatible with roll-to-roll industry to improve the cost-effectiveness and sustainability of photovoltaics without compromising the photovoltaic performance.
Herein, we review cost-efficient and sustainable fabrication methodologies that complement the current high-
energy-demanding vacuum-based fabrication of Cu(In,Ga)Se2 photovoltaics. The existent non-vacuum deposition methods of Cu(In,Ga)Se2 photoabsorbers are presented and precursors and solvents used in ink formulations are discussed in terms of sustainability. The approaches resulting in most efficient photovoltaic cells are highlighted. Finally, all-solution-processed Cu(In,Ga)Se2 photovoltaics are reviewed, along with the non-vacuum deposition methods of the individual layers, contributing to an even higher throughput and low-cost production. This review highlights the relevance and potential of sustainable non-vacuum methodologies, as well as the need of further investigation in this field to ultimately give access to high-end CIGS PVs with low-cost fabrication.We thank the members of the Nanochemistry Research Group (http://nanochemgroup.org) at INL for insightful discussions and support. This study was conducted with financial support from the Portuguese funding institution FCT – Fundaç ̃ao para Ciˆencia e Tecnologia (PTDC/CTM-ENE/5387/2014, PTDC/NAN-MAT/28745/2017, UID/FIS/04650/2020, UID/QUI/0686/2020, PTDC/FIS-MAC/28157/2017
and SFRH/BD/121780/2016) and Basque Government Industry Department (ELKARTEK and HAZITEK)
Novel Polymorph of GaSe
2D GaSe is a semiconductor belonging to the group of post-transition metal chalcogenides with great potential for advanced optoelectronic applications. The weak interlayer interaction in multilayer 2D materials allows the formation of several polymorphs. Here, the first structural observation of a new GaSe polymorph is reported, characterized by a distinct atomic configuration with a centrosymmetric monolayer (D-3d point group). The atomic structure of this new GaSe polymorph is determined by aberration-corrected scanning transmission electron microscopy. Density-functional theory calculations verify the structural stability of this polymorph. Furthermore, the band structure and Raman intensities are calculated, predicting slight differences to the currently known polymorphs. In addition, the occurrence of layer rotations, interlayer relative orientations, as well as translation shear faults is discussed. The experimental confirmation of the new GaSe polymorph indicates the importance of investigating changes in the crystal structure, which can further impact the properties of this family of compoundsThis article has received support from the project Nanotechnology Based Functional Solutions (NORTE-01-0145-FEDER-000019), supported by Norte Portugal Regional Operational Programme (NORTE2020), under the PORTUGAL 2020 Partnership Agreement, through the European Regional Development Fund (ERDF). Additional support by National Funds through the Portuguese Foundation for Science and Technology (FCT) in the framework of the project "LA2D" -PTDC/FIS-NAN/3668/2014 is acknowledged. This work was supported by FCT, through IDMEC, under LAETA, project UIDB/50022/2020. A. M.-S. thanks the Marie-Curie-COFUND program Nano TRAIN for Growth II (Grant Agreement 713640) and the Ramon y Cajal programme (grant RYC2018-024024-I, MINECO, Spain). This work was carried out in part through the use of the INL Advanced Electron Microscopy, Imaging, and Spectroscopy Facility. The computations were performed on the Tirant III cluster of the Servei d'Informatica of the University of Valencia (project vlc82) and on Mare Nostrum cluster of the Barcelona Supercomputing Center (project FI-2020-2-033 and FI-2020-3-0021)
Formación de la unión de Cu 3BiS 3 investigada por microscopía de fuerza de sonda Kelvin y mediciones de fotovoltaje de superficie
Recently, the compound semiconductor Cu3BiS3 has been demonstrated to have a band gap of ~1.4 eV, well suited for photovoltaic energy harvesting. The preparation of polycrystalline thin films was successfully realized and now the junction formation to the n-type window needs to be developed. We present an investigation of the Cu3BiS3 absorber layer and the junction formation with CdS, ZnS and In2S3 buffer layers. Kelvin probe force microscopy shows the granular structure of the buffer layers with small grains of 20–100 nm, and a considerably smaller work-function distribution for In2S3 compared to that of CdS and ZnS. For In2S3 and CdS buffer layers the KPFM experiments indicate negatively charged Cu3BiS3 grain boundaries resulting from the deposition of the buffer layer. Macroscopic measurements of the surface photovoltage at variable excitation wavelength indicate the influence of defect states below the band gap on charge separation and a surface-defect passivation by the In2S3 buffer layer. Our findings indicate that Cu3BiS3 may become an interesting absorber material for thin-film solar cells; however, for photovoltaic application the band bending at the charge-selective contact has to be increased
Reliable wet-chemical cleaning of natively oxidized high-efficiency Cu(In,Ga)Se2 thin-film solar cell absorbers
Currently, Cu-containing chalcopyrite-based solar cells provide the highest
conversion efficiencies among all thin-film photovoltaic (PV) technologies.
They have reached efficiency values above 20%, the same performance level as
multi-crystalline silicon-wafer technology that dominates the commercial PV
market. Chalcopyrite thin-film heterostructures consist of a layer stack with
a variety of interfaces between different materials. It is the
chalcopyrite/buffer region (forming the p-n junction), which is of crucial
importance and therefore frequently investigated using surface and interface
science tools, such as photoelectron spectroscopy and scanning probe
microscopy. To ensure comparability and validity of the results, a general
preparation guide for “realistic” surfaces of polycrystalline chalcopyrite
thin films is highly desirable. We present results on wet-chemical cleaning
procedures of polycrystalline Cu(In1-xGax)Se2 thin films with an average x =
[Ga]/([In] + [Ga]) = 0.29, which were exposed to ambient conditions for
different times. The hence natively oxidized sample surfaces were etched in
KCN- or NH3-based aqueous solutions. By x-ray photoelectron spectroscopy, we
find that the KCN treatment results in a chemical surface structure which is –
apart from a slight change in surface composition – identical to a pristine
as-received sample surface. Additionally, we discover a different oxidation
behavior of In and Ga, in agreement with thermodynamic reference data, and we
find indications for the segregation and removal of copper selenide surface
phases from the polycrystalline material
Electroluminescence of copper-nitride nanocrystals
Nanocrystals can behave as quantum boxes with confined electronic states
governing their optoelectronic properties. The formation of nanometer-size
crystals of copper nitride (Cu3N) grown by nitrogen sputtering of a Cu(110)
surface is reported. Scanning tunneling spectroscopy shows that the
nanocrystals exhibit a series of well-defined sharp electronic resonances,
which correspond to confined free-electron-like states. We observe that
electrons from a scanning tunneling microscope tip induce the emission of
light with a larger efficiency than on the bare metal surface. The spectral
analysis of the emitted photons reveals various radiative inelastic pathways
enabled by the confined states, which explain the enhanced light emission.
Thus, the Cu3N nanocrystals can be employed as nanometer-size light sources
Current Status of Bottom-Up Fabrication Approaches for Cu(In,Ga)Se2 Micro-Concentrator Solar Cells
Effect of gallium doping on structural and transport properties of the topological insulator Bi2Se3 grown by molecular beam epitaxy
Topological insulators possess a non-conductive bulk and present surface
states, henceforth, they are electrically conductive along their boundaries.
Bismuth selenide () is one of the most promising topological
insulators. However, a major drawback is its n-type nature arising from its
natural doping, which makes the transport in the bulk dominant. This effect can
be overcome by shifting the chemical potential into the bandgap, turning the
transport of the surface states to be more pronounced than the bulk
counterpart. In this work, was grown by molecular beam epitaxy and
doped with 0.8, 2, 7, and 14 at. % of Ga, with the aim of shifting the chemical
potential into the bandgap. The structural, morphological, and electronic
properties of the Ga doped are studied. Raman and X-ray diffraction
measurements confirmed the incorporation of the dopants into the crystal
structure. Transport and magnetoresistance measurements in the temperature
range of 1.5 to 300 K show that Ga-doped is n-type with a bulk
charge carrier concentration of . Remarkably, magnetotransport
of the weak antilocalization effect (WAL) measurements confirm the existence of
surface states up to a doping percentage of 2 at. % of Ga and coherence length
values between 50-800 nm, which envisages the possibility of topological
superconductivity in this material.Comment: 17 pages, 8 figures, Supplementary Information include
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