Infrared spectra of van de Waals complexes of importance in planetary atmospheres

It has been suggested that (CO2)2 and Ar-CO2 are important constituents of the planetary atmospheres of Venus and Mars. Recent results on the laboratory spectroscopy of CO2 containing van der Waals complexes which may be of use in the modeling of the spectra of planetary atmospheres are presented. Sub-Doppler infrared spectra were obtained for (CO2)2, (CO2)3, and rare-gas-CO2 complexes in the vicinity of the CO2 Fermi diad at 2.7 micrometers using a color-center-laser optothermal spectrometer. From the spectroscopic constants the geometries of the complexes have been determined and van der Waals vibrational frequencies have been estimated. The equilibrium configurations are C2h, C3h, and C2v, for (CO2)2, (CO2)3, and the rare-gas-CO2 complexes, respectively. Most of the homogeneous linewidths for the revibrational transitions range from 0.5 to 22 MHz, indicating that predissociation is as much as four orders of magnitude faster than radiative processes for vibrational relaxation in these complexes

The first definitive Middle Jurassic atoposaurid (Crocodylomorpha, Neosuchia), and a discussion on the genus Theriosuchus

Atoposaurids were a clade of semiaquatic crocodyliforms known from the Late Jurassic to the latest Cretaceous. Tentative remains from Europe, Morocco, and Madagascar may extend their range into the Middle Jurassic. Here we report the first unambiguous Middle Jurassic (late Bajocian–Bathonian) atoposaurid: an anterior dentary from the Isle of Skye, Scotland, UK. A comprehensive review of atoposaurid specimens demonstrates that this dentary can be referred to Theriosuchus based on several derived characters, and differs from the five previously recognized species within this genus. Despite several diagnostic features, we conservatively refer it to Theriosuchus sp., pending the discovery of more complete material. As the oldest known definitively diagnostic atoposaurid, this discovery indicates that the oldest members of this group were small-bodied, had heterodont dentition, and were most likely widespread components of European faunas. Our review of mandibular and dental features in atoposaurids not only allows us to present a revised diagnosis of Theriosuchus, but also reveals a great amount of variability within this genus, and indicates that there are currently five valid species that can be differentiated by unique combinations of dental characteristics. This variability can be included in future broad-scale cladistics analyses of atoposaurids and closely related crocodyliforms, which promise to help untangle the complicated taxonomy and evolutionary history of Atoposauridae

Internal meanings: Computed tomography scanning of Koma figurines from Ghana

This is the final version of the article. Available from the publisher via the DOI in this record.Since the 1980s art historians and archaeologists have been aware of the terracotta figurines from Koma Land in northern Ghana (Kröger 1988; Anquandah 1987, 1998). The pioneering excavation and publications by James Anquandah (Anquandah and van Ham 1985; Anquandah 1987, 1998) established their provenance, and unprovenanced figurines from illegal excavations have subsequently increased known numbers. The dominant focus in publication of the Koma Land corpus has been upon what the figurines depict externally (e.g., Anquandah 1987, 1998; Kankpeyeng and Nkumbaan 2008, 2009; Insoll and Kankpeyeng 2014; Insoll in press a). Following the successful trial use of lower resolution Computed Tomography black scanning which produced black-and-white images of five figurines in May 2010 (Insoll, Kankpeyeng, and Nkumbaan 2012:31–32), a further sample of eight terracotta figurines was CT scanned and color images produced in 2013. These are the focus here. All the figurines were from archaeological excavations at Yikpabongo in Koma Land, and the CT scanning indicated that all eight had deliberately made cavities running from their surface into the body of the figurine. This suggests that the importance of some of the figurines was potentially greater than their external appearance and that part of their significance might have been derived from their internal meanings as well. This paper reports on the renewed research in Koma Land that led to the retrieval of the figurines, and on the scanned figu rines themselves. Why the cavities were made is unknown, but various possibilities are explored. This is considered with reference to the Koma figurines and through wider comparison with other archaeological terracotta figurines from West Africa that have evidence for cavities

Micrometer-sized Water Ice Particles for Planetary Science Experiments: Influence of Surface Structure on Collisional Properties

Models and observations suggest that ice-particle aggregation at and beyond the snowline dominates the earliest stages of planet formation, which therefore is subject to many laboratory studies. However, the pressure–temperature gradients in protoplanetary disks mean that the ices are constantly processed, undergoing phase changes between different solid phases and the gas phase. Open questions remain as to whether the properties of the icy particles themselves dictate collision outcomes and therefore how effectively collision experiments reproduce conditions in protoplanetary environments. Previous experiments often yielded apparently contradictory results on collision outcomes, only agreeing in a temperature dependence setting in above ≈210 K. By exploiting the unique capabilities of the NIMROD neutron scattering instrument, we characterized the bulk and surface structure of icy particles used in collision experiments, and studied how these structures alter as a function of temperature at a constant pressure of around 30 mbar. Our icy grains, formed under liquid nitrogen, undergo changes in the crystalline ice-phase, sublimation, sintering and surface pre-melting as they are heated from 103 to 247 K. An increase in the thickness of the diffuse surface layer from ≈10 to ≈30 Å (≈2.5 to 12 bilayers) proves increased molecular mobility at temperatures above ≈210 K. Because none of the other changes tie-in with the temperature trends in collisional outcomes, we conclude that the surface pre-melting phenomenon plays a key role in collision experiments at these temperatures. Consequently, the pressure–temperature environment, may have a larger influence on collision outcomes than previously thought

Now the wars are over: The past, present and future of Scottish battlefields

Battlefield archaeology has provided a new way of appreciating historic battlefields. This paper provides a summary of the long history of warfare and conflict in Scotland which has given rise to a large number of battlefield sites. Recent moves to highlight the archaeological importance of these sites, in the form of Historic Scotland’s Battlefields Inventory are discussed, along with some of the problems associated with the preservation and management of these important cultural sites

Control strategies for integration of electric motor assist and functional electrical stimulation in paraplegic cycling: Utility for exercise testing and mobile cycling

AIM: The aim of this study was to investigate feedback control strategies for integration of electric motor assist and functional electrical stimulation (FES) for paraplegic cycling, with particular focus on development of a testbed for exercise testing in FES cycling, in which both cycling cadence and workrate are simultaneously well controlled and contemporary physiological measures of exercise performance derived. A second aim was to investigate the possible benefits of the approach for mobile, recreational cycling. METHODS: A recumbent tricycle with an auxiliary electric motor is used, which is adapted for paraplegic users, and instrumented for stimulation control. We propose a novel integrated control strategy which simultaneously provides feedback control of leg power output (via automatic adjustment of stimulation intensity) and cycling cadence (via electric motor control). Both loops are designed using system identification and analytical (model-based) feedback design methods. Ventilatory and pulmonary gas exchange response profiles are derived using a portable system for real-time breath-by-breath acquisition. RESULTS:We provide indicative results from one paraplegic subject in which a series of feedback-control tests illustrate accurate control of cycling cadence, leg power control, and external disturbance rejection. We also provide physiological response profiles from a submaximal exercise step test and a maximal incremental exercise test, as facilitated by the control strategy. CONCLUSION: The integrated control strategy is effective in facilitating exercise testing under conditions of well-controlled cadence and power output. Our control approach significantly extends the achievable workrate range and enhances exercise-test sensitivity for FES cycling, thus allowing a more stringent characterization of physiological response profiles and estimation of key parameters of aerobic function.We further conclude that the control approach can significantly improve the overall performance of mobile recreational cycling

Applying unsupervised learning to resolve evolutionary histories and explore the galaxy-halo connection in IllustrisTNG

We examine the effectiveness of identifying distinct evolutionary histories in IllustrisTNG-100 galaxies using unsupervised machine learning with Gaussian Mixture Models. We focus on how clustering compressed metallicity histories and star formation histories produces subpopulations of galaxies with distinct evolutionary properties (for both halo mass assembly and merger histories). By contrast, clustering with photometric colours fail to resolve such histories. We identify several populations of interest that reflect a variety of evolutionary scenarios supported by the literature. Notably, we identify a population of galaxies inhabiting the upper-red sequence, M* > 1010M⊙ that has a significantly higher ex-situ merger mass fraction present at fixed masses, and a star formation history that has yet to fully quench, in contrast to an overlapping, satellite-dominated population along the red sequence, which is distinctly quiescent. Extending the clustering to study four clusters instead of three further divides quiescent galaxies, while star forming ones are mostly contained in a single cluster, demonstrating a variety of supported pathways to quenching. In addition to these populations, we identify a handful of populations from our other clusters that are readily applicable to observational surveys, including a population related to post starburst (PSB) galaxies, allowing for possible extensions of this work in an observational context, and to corroborate results within the IllustrisTNG ecosystem.PostprintPeer reviewe

Accuracy and computational efficiency of 2D urban surface flood modelling based on cellular automata

There is an emerging abundance freely available of high resolution (one meter or less) LIDAR data due to the advent of remote sensing, which enables wider applications of detailed flood risk modelling and analysis. Digital terrain surface data often comes in raster form, i.e., a square regular grid, and often requires conversion into a specific computational mesh for two-dimensional (2D) flood modelling that adopts triangular irregular meshes. 2D modelling of flood water movement through urban areas requires resolution of complex flow paths around buildings, which requires both high accuracy and computational efficiency. Water distribution and Wastewater systems in the UK contain over 700,000 km of water distribution and sewer pipes, which represents a large risk exposure from flooding caused by sewer surcharging or distribution pipe breaks. This makes it important for utilities to understand and predict where clean or dirty water flows will be directed when they leave the system. In order to establish risk assessment many thousands of simulations may be required calling for the most computational efficient models possible. Cellular Automata (CA) represents a method of running simulations based on a regular square grid, thus saving set-up time of configuring the terrain data into an irregular triangular mesh. It also offers a more uniform memory pattern for very fast modern, highly parallel hardware, such as general purpose graphical processing units (GPGPU). In this paper the performance of the CADDIES, a CA platform and associate flood modelling software caFloodPro, using a square regular grid and Von Neumann neighbourhood, is compared to industry standard software using triangular irregular meshes for similar resolutions. A minimum time step is used to control the computational complexity of the algorithm, which then creates a trade-off between the processing speeds of simulations and the accuracy resulting from the limitations used within the local rule to cope with relatively large time steps. This study shows that using CA based methods on regular square grids offers process speed increases in terms of 5-20 times over that of the industry standard software using irregular triangular meshes, while maintaining 98-99% flooding extent accuracy.This is the final version of the article. Available from Elsevier via the DOI in this record.There is an emerging abundance freely available of high resolution (one meter or less) LIDAR data due to the advent of remote sensing, which enables wider applications of detailed flood risk modelling and analysis. Digital terrain surface data often comes in raster form, i.e., a square regular grid, and often requires conversion into a specific computational mesh for two-dimensional (2D) flood modelling that adopts triangular irregular meshes. 2D modelling of flood water movement through urban areas requires resolution of complex flow paths around buildings, which requires both high accuracy and computational efficiency. Water distribution and Wastewater systems in the UK contain over 700,000 km of water distribution and sewer pipes, which represents a large risk exposure from flooding caused by sewer surcharging or distribution pipe breaks. This makes it important for utilities to understand and predict where clean or dirty water flows will be directed when they leave the system. In order to establish risk assessment many thousands of simulations may be required calling for the most computational efficient models possible. Cellular Automata (CA) represents a method of running simulations based on a regular square grid, thus saving set-up time of configuring the terrain data into an irregular triangular mesh. It also offers a more uniform memory pattern for very fast modern, highly parallel hardware, such as general purpose graphical processing units (GPGPU). In this paper the performance of the CADDIES, a CA platform and associate flood modelling software caFloodPro, using a square regular grid and Von Neumann neighbourhood, is compared to industry standard software using triangular irregular meshes for similar resolutions. A minimum time step is used to control the computational complexity of the algorithm, which then creates a trade-off between the processing speeds of simulations and the accuracy resulting from the limitations used within the local rule to cope with relatively large time steps. This study shows that using CA based methods on regular square grids offers process speed increases in terms of 5-20 times over that of the industry standard software using irregular triangular meshes, while maintaining 98-99% flooding extent accuracy